The chemistry and mineralogy of the olivine nodules of Calton Hill, Derbyshire

1963 ◽  
Vol 33 (261) ◽  
pp. 483-497 ◽  
Author(s):  
S. el D. Hamad
Keyword(s):  
Host Rock ◽  
Chromium Content ◽  
Basaltic Magma ◽  
Optical Data ◽  
Chromian Spinel ◽  
Chemical Analyses ◽  
High Chromium ◽  
Cell Parameters ◽  
Tie Line

SummaryChemical analyses, optical data, and cell parameters are given for olivine (Fo90·3 and Fo91·4), orthopyroxene (Ca1·5Mg89·0Fe9·5 and Ca9·8Mg88·6Fe10·6), clinopyroxene (Ca39·6Mg55·8Fe4·6), and chromian spinel from olivine nodules from the Carboniferous basalt of Calton Hill, Derbyshire. Chemical and modal analyses of the nodules and of their host rock are also presented. The distribution of Mg and Fe in the coexisting pyroxenes is fairly similar to that observed by Ross, Foster, and Myers (1954) but differs slightly in that the extension of the pyroxene tie-line intersects the Ca-Mg side of the Ca-Mg-Fe triangle. The clinopyroxene is a normal augite rather than the hydrous augite previously reported (Tomkeieff, 1928). The high chromium content of the spinel and clinopyroxene contrasts with the low value for this element in the host rock, suggesting that these minerals are not differentiates of the basaltic magma: the nodules are considered to represent fragments from a deep-seated peridotite.

Conjugate cummingtonite and hornblende at Sgeir nan Sgarbh, South Harris, Outer Hebrides

1973 ◽  
Vol 39 (304) ◽  
pp. 464-466 ◽  
Author(s):  
A. Livingstone ◽  
M. T. Frost ◽  
P. Suddaby
Keyword(s):  
Optical Data ◽  
Chemical Analyses ◽  
Cell Parameters ◽  
Outer Hebrides

SummaryChemical analyses, cell parameters, and optical data are presented for conjugate cummingtonite and hornblende, which occur in a paragneiss. A metasomatic origin for the development of hornblende from cummingtonite, during retrogressive metamorphism, is proposed.

Ortho- and Clino-Pyroxenes from the Charnockite Series of Amaravathi, Andhra Pradesh, South India

1973 ◽  
Vol 39 (301) ◽  
pp. 74-77 ◽  
Author(s):  
A. Ramaswamy ◽  
M. S. Murty
Keyword(s):  
High Pressure ◽  
Chemical Equilibrium ◽  
Andhra Pradesh ◽  
South India ◽  
Optical Data ◽  
Chemical Analyses ◽  
Structural Formulae ◽  
Tie Line

SummaryThe chemical analyses, structural formulae, and optical data of seven orthopyroxenes and six clinopyroxenes, all from the charnockite series of Amaravathi, are presented. The orthopyroxenes are in the hypersthene-ferrohypersthene range while the clinopyroxenes are in the sahlite range. The aluminous nature of the pyroxene is believed to be the result of high pressure. The clinopyroxenes have the granulite trend on the Wo-En-Fs plot. The tie-line projections and the KD values for the pyroxene pairs indicate conditions of chemical equilibrium around 670 °C for the charnockite series of Amaravathi.

The chemistry and cell parameters of omphacites and related pyroxenes

1969 ◽  
Vol 37 (285) ◽  
pp. 61-74 ◽  
Author(s):  
A. D. Edgar ◽  
A. Mottana ◽  
N. D. Macrae
Keyword(s):  
Powder Diffraction ◽  
Electron Microprobe ◽  
Graphical Representation ◽  
Chemical Compositions ◽  
Chemical Analyses ◽  
X Ray ◽  
Cell Parameters ◽  
Cell Dimensions ◽  
Approximate Estimation

SummaryIn an attempt to correlate the chemical compositions and cell sizes of omphacites and related pyroxenes, the cell dimensions of fifty-five analysed pyroxenes have been determined, or taken from the literature. Twenty-two of the chemical analyses are new, nineteen of them being done by electron microprobe. Approximately two-thirds of the total number of analyses may be considered first class, the remainder are of doubtful or unknown quality. Cell parameters, determined by X-ray powder diffraction methods, have errors of 0·1 % for the majority of samples, although for some samples taken from the literature errors are unknown.The majority of methods of recalculating omphacite analyses into their end-member molecules are unsuitable for correlation of cell constants with chemistry, mainly due to the impossibility of graphical representation of more than three end-member molecules, and to the non-stoichiometry of these molecules. Using a modification of Tröger's (1962) method of recalculating chloromelanite analyses the present analyses have been recalculated into the diopside-jadeite-acmite and diopside-jadeite-hedenbergite molecules and compared with their determined cell parameters. Because of the gradations in all parameters between these end-member molecules, determination of compositions based on the cell parameters (a, b, c, vol, or β) can only be made within wide limits. However, using a method of projection of compositions from the acmite and hedenbergite apices to the diopside-jadeite join the ratios of diopside to jadeite can be determined for most samples to within ±5 mol%. As there are the most important constituents of most omphacites, this method permits an approximate estimation of omphacite compositions. From a knowledge of the cell sizes of the omphacite a rough indication of the conditions of formation of its host rock may also be obtained.

D'ansite-(Mn), Na21Mn2+(SO4)10Cl3 and d'ansite-(Fe), Na21Fe2+(SO4)10Cl3, two new minerals from volcanic fumaroles

2012 ◽  
Vol 76 (7) ◽  
pp. 2773-2783 ◽  
Author(s):  
F. Demartin ◽  
I. Campostrini ◽  
C. Castellano ◽  
C. M. Gramaccioli ◽  
M. Russo
Keyword(s):  
Single Crystal ◽  
Empirical Formula ◽  
Energy Dispersive Spectrometry ◽  
Chemical Analyses ◽  
Crystal Data ◽  
Unit Cell Parameters ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Cell Parameters ◽  
Fossa Crater

AbstractThe new minerals d'ansite-(Mn), Na21Mn2+(SO4)10Cl3, and d'ansite-(Fe), Na21Fe2+(SO4)10Cl3, occur as encrustations in fumaroles at Vesuvius, Naples, Italy and La Fossa crater, Vulcano, Aeolian Islands, Italy, respectively. Both minerals are cubic and crystallize in space group I3d. D'ansite-(Mn) forms colourless translucent tristetrahedral crystals up to 0.2 mm on edge; d'ansite-(Fe) forms aggregates of colourless to white complex isometric crystals of about the same size. Chemical analyses obtained by energy-dispersive spectrometry on an electron microprobe gave the following mean compositions: d'ansite-(Mn), Na2O 39.37, MnO 3.46, MgO 0.13, SO3 49.99, Cl 6.36, O=Cl–1.44, total 97.87 wt.%, corresponding to an empirical formula, on the basis of 43 anions, of Na20.61 (Mn2+0.79Mg0.05)Σ0.84S10.13O40.09Cl2.91; and d'ansite-(Fe), Na2O 39.12, FeO 4.18, MgO 0.12, SO3 49.91, Cl 6.81, O=Cl –1.54, total 98.60 wt.%, corresponding to an empirical formula of Na20.42(Fe2+0.94Mg0.05)Σ0.99S10.08O39.89Cl3.11. The six strongest reflections in the X-ray powder diffraction pattern of d'ansite-(Fe) [listed as dobs(Å) (I) (hkl)] are as follows: 2.807(100)(044), 2.570(37)(235), 1.714(29)(129), 3.384(27)(233), 3.113(26)(134), 2.108(15)(237). The unit-cell parameters obtained from single-crystal data are 15.9291(9) and 15.882(3) Å for d'ansite-(Mn) and d'ansite-(Fe), respectively. The structure of both minerals was refined, using single-crystal diffraction data, to final R parameters of 0.0309 and 0.0336 on reflections with I > 2σ(I). The structure contains three independent Na sites, one of which is partially occupied by Mn2+ or Fe2+, two independent sulfate anions and one chlorine site.

Zeolitová mineralizace s gmelinitem-K z Jedlky u Benešova nad Ploučnicí (Česká republika)

2021 ◽  
Vol 29 (2) ◽  
pp. 213-229
Author(s):  
Petr Pauliš ◽  
Libor Hrůzek ◽  
Oldřich Janeček ◽  
Zdeněk Dolníček ◽  
Volker Betz ◽  
...  
Keyword(s):  
Czech Republic ◽  
Empirical Formula ◽  
Unit Cell ◽  
Mineral Species ◽  
Chemical Analyses ◽  
Unit Cell Parameters ◽  
X Ray ◽  
Cell Parameters ◽  
Quantitative Chemical

A new locality of zeolite minerals occurs on the NE edge of the Jedlka village, at the SE slope of the Hlídka hill, 2 km to W of Benešov nad Ploučnicí (northern Bohemia, Czech Republic). The mineralization is developed in Cenozoic analcime-nepheline tephrite. Ten zeolite mineral species (gmelinite-K, analcime, harmotome, chabazite-Ca, lévyne-Ca, mezolite, natrolite, offretite, phillipsite-K, thomsonite-Ca) were found in small amygdule cavities of tephrite. The most interesting is gmelinite-K, a rare zeolite worldwide, which forms clear, white or slightly yellowish, hexagonal lenticular crystals up to 7 mm, always intergrown with the chabazite-Ca. The unit-cell parameters of gmelinite-K, refined from the powder X-ray data, are a = 13.795 (19), c = 9.811(6) Å and V = 1616.8(3) Å3; its quantitative chemical analyses correspond to the empirical formula (K2.32Ca1.86Sr0.53Na0.20Ba0.19)Σ5.10(Al8.14Si16.01O48)·22H2O.

Caracteres petrographiques de l'ophite de Vebre (Ariege)

1965 ◽  
Vol S7-VII (1) ◽  
pp. 168-171
Author(s):  
Ch Riotte ◽  
Jean Thiebaut
Keyword(s):  
Basaltic Magma ◽  
Petrographic Analysis ◽  
Chemical Analyses ◽  
Rock Types ◽  
The Right ◽  
Potassium Enrichment ◽  
Later Phase

Abstract Petrographic analysis of the ophite outcrop on the right bank of the Ariege river, below Vebre, France, shows that the rock is rich in epidote and exhibits pegmatoid differentiation. Three rock types are distinguished--common ophite with variable amounts of epidote; ophite with phlogopite; and pegmatoid rocks with orthoclase. The results of four chemical analyses indicate that the Vebre ophites were affected by pneumatolysis during crystallization from a saturated basaltic magma. The pneumatolysis caused the crystallization of hornblende and, in a later phase of potassium enrichment, the superimposition of orthoclase in the pegmatoid plagioclases and the phlogopite in the hornblende crystals of the ophite.

New data on glaucocerinite

1985 ◽  
Vol 49 (353) ◽  
pp. 583-590 ◽  
Author(s):  
Gunnar Raade ◽  
C. J. Elliott ◽  
V. K. Din
Keyword(s):  
Chemical Analysis ◽  
Diffraction Pattern ◽  
Powder Diffraction ◽  
Western Australia ◽  
Type Structure ◽  
Type Material ◽  
Optical Data ◽  
Hexagonal Cell ◽  
X Ray ◽  
Cell Parameters

AbstractThe strongest lines in the X-ray powder diffraction pattern of type material of glaucocerinite from Laurion (Greece), indexed on a hexagonal pseudocell, are 10.9 (100) (003), 5.45 (90) (006), 3.63 (80) (009), 2.62 (60) (012), 2.46 (60) (015), 2.231 (50) (018), and 1.981 Å (50) (0.1.11). The pseudocell parameters area3.0700(8),c32.65(1) Å. Chemical analysis of topotype material yields the formula [(Zn,Cu)5Al3(OH)16] [(SO4)1.5·9H2O] based on a pyroaurite-like structure. The pseudocell parameters for this sample area3.057(3),c32.52(5) Å. Optical data are 2Vα⋍ 60°,α1.540,β1.554,γ1.562;D(meas.) = 2.4±0.1 g/cm3,D(calc.) = 2.33 g/cm3. So-called ‘woodwardite’ from Caernarvonshire, Wales, is identified as the Cuanalogue of glaucocerinite. An ‘11 Å mineral’ occurring together with carrboydite in Western Australia is shown to be the Ni-analogue of glaucocerinite. Alleged cotype glaucocerinite from Laurion is related to woodwardite and has the formula [(Zn,Cu)2Al(OH)6][(SO4)0.5· 3H2O]. This is a cation-ordered pyroaurite-type structure with hexagonal cell parametersa5.306(2),c26.77(2) Å. The strongest X-ray powder lines occur at 8.9 (100) (003), 4.47 (90) (006), 2.55 (60) (113), and 2.28 Å (50) (116).

Mechanism of High Temperature Embrittlement and Loss of Corrosion Resistance in AISI Type 446 Stainless Steel

CORROSION ◽  
1971 ◽  
Vol 27 (12) ◽  
pp. 531-544 ◽  
Author(s):  
J. J. DEMO
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Material Properties ◽  
Chromium Content ◽  
Raw Material ◽  
Construction Work ◽  
Ferritic Alloys ◽  
High Chromium ◽  
Aisi Type ◽  
Resistance To Stress

Abstract The ferritic alloys, particularly AISI Type 446 steel with its high chromium content, have desirable properties of corrosion resistance, low raw material cost, and resistance to stress corrosion cracking (SCC); yet they are not widely used in construction work because of the damaging effects of high temperature exposures (such as welding) on their corrosion resistance and ductility. This work describes the causes for their loss of corrosion resistance and ductility, and defines changes in composition and heat treatment that would improve their material properties.

Effective Extraction of Vanadium and Chromium from High Chromium Content Vanadium Slag by Sodium Roasting and Water Leaching

2016 ◽  
Vol 863 ◽  
pp. 144-148 ◽  
Author(s):  
Ming Li ◽  
Liang Xiao ◽  
Jing Jing Liu ◽  
Zhi Xin Shi ◽  
Zi Bi Fu ◽  
...  
Keyword(s):  
Chromium Content ◽  
Leaching Rate ◽  
Vanadium Slag ◽  
Water Leaching ◽  
Sodium Salts ◽  
High Chromium ◽  
Effective Factor ◽  
Roasting Process ◽  
Roasting Temperature ◽  
Roasting Time

The extraction of vanadium and chromium from high chromium content vanadium slag by salt roasting and water leaching process has been investigated, which uses mixed sodium salts (Na2CO3 and NaOH) as additive agent in roasting process. The mineralogical morphology was prospected by TG-DSC, XRD, SEM and EDS. The oxidation of slag and transversion of V/Cr-containing phase and sodium salts have been discussed. It has been demonstrated that the presence of NaOH contributes to decompose spinel and olivine phases, which is beneficial to reduce the roasting temperature and elevate V, Cr leaching ratio. The roasting parameters have been studied as a function of roasting temperature, roasting time and ratio of alkali, in which the roasting temperature is the most effective factor on the leaching rate of vanadium and chromium. Under the optimum condition, the leaching rates of V and Cr reached 95.8% and 97.6%, respectively.

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