A new synthesis and characterization of magnesium-aluminium hydroxides

SummaryA new synthesis of Mg-Al double hydroxides is described, that gives products relatively low (0.8–1.0%) in CO2. The general formula [Mg1−xAlx (OH)2][(OH)x(H2O)0.81−x] with 0.23 ≤ x ≤ 0.33 is proposed. Cell parameters and thermal data are given. The c-axial length decreases with Al-content; this is attributed to increased electrostatic attraction between layers.

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Synthesis and characterization of terephthalate-intercalated NiAl layered double hydroxides with high Al content

Dalton Transactions ◽

10.1039/c2dt31502e ◽

2013 ◽

Vol 42 (6) ◽

pp. 2084-2093 ◽

Cited By ~ 34

Author(s):

Santiago Arias ◽

Jean Guillaume Eon ◽

Rosane A. S. San Gil ◽

Yordy E. Licea ◽

Luz Amparo Palacio ◽

...

Keyword(s):

Layered Double Hydroxides ◽

Synthesis And Characterization ◽

Al Content ◽

High Al Content ◽

Double Hydroxides

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Synthesis and characterization of Layered Double Hydroxides aimed at encapsulation of sodium diclofenac: Theoretical and experimental study

Journal of Molecular Liquids ◽

10.1016/j.molliq.2021.116677 ◽

2021 ◽

pp. 116677

Author(s):

Samra Amamra ◽

Hayet Elkolli ◽

Yacine Benguerba ◽

Alessandro Erto ◽

Marco Balsamo ◽

...

Keyword(s):

Experimental Study ◽

Layered Double Hydroxides ◽

Synthesis And Characterization ◽

Sodium Diclofenac ◽

Double Hydroxides

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Synthesis and characterization of layered bismuth vanadates

Journal of Materials Research ◽

10.1557/jmr.1990.2718 ◽

1990 ◽

Vol 5 (11) ◽

pp. 2718-2722 ◽

Cited By ~ 56

Author(s):

K. B. R. Varma ◽

G. N. Subbanna ◽

T. N. Guru ◽

C. N. R. Rao

Keyword(s):

Curie Temperature ◽

General Formula ◽

Layered Structure ◽

Synthesis And Characterization ◽

Structure And Properties ◽

Bismuth Vanadates

Bi2VO5.5 (Bi4O11), which is the vanadium analog of the first member of the Aurivillius family of oxides of the general formula Bi2An−1BnO3n+3, has been prepared and characterized. The vanadate has the expected layered structure and is ferroelectric with a Curie temperature of 720 K. While we have not been able to synthesize the vanadium analog of the n = 2 member of the Aurivillius family, we have examined the structure and properties of a vanadate of the composition Bi2V3O9.

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Synthesis and characterization of a superoxo complex of the dicobalt cofacial diporphyrin [(.mu.-O2)Co2(DPB)(1,5-diphenylimidazole)2][PF6], the structure of the parent dicobalt diporphyrin Co2(DPB), and a new synthesis of the free-base cofacial diporphyrin H4(DPB)

Journal of the American Chemical Society ◽

10.1021/ja00051a020 ◽

1992 ◽

Vol 114 (25) ◽

pp. 9869-9877 ◽

Cited By ~ 68

Author(s):

James P. Collman ◽

James E. Hutchison ◽

Michel Angel Lopez ◽

Alain Tabard ◽

Roger Guilard ◽

...

Keyword(s):

Synthesis And Characterization ◽

Free Base ◽

New Synthesis

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Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications

Inorganics ◽

10.3390/inorganics6030097 ◽

2018 ◽

Vol 6 (3) ◽

pp. 97 ◽

Cited By ~ 8

Author(s):

Marie Gaschard ◽

Farzaneh Nehzat ◽

Thomas Cheminel ◽

Bruno Therrien

Keyword(s):

Molecular Structure ◽

Single Crystal ◽

General Formula ◽

Structure Analysis ◽

White Light ◽

Light Irradiation ◽

Synthesis And Characterization ◽

X Ray

The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed by the single-crystal X-ray structure analysis of [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2][CF3SO3]4 · 4 acetone (A2 · 4 acetone), thus showing the anthracene moieties to be available for reaction with oxygen. While the formation of the endoperoxide form of Lanthr was observed in solution upon white light irradiation, the same reaction does not occur when Lanthr is part of the metalla-assemblies.

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Synthesis and characterization of new complexes of Co+2 , Ni+2 , Cu+2 and Zn+2 with (Sodium acetate thio ) ethylene ligands

Baghdad Science Journal ◽

10.21123/bsj.10.3.650-657 ◽

2013 ◽

Vol 10 (3) ◽

pp. 650-657

Author(s):

Baghdad Science Journal

Keyword(s):

Content Analysis ◽

General Formula ◽

Metal Content ◽

Sodium Acetate ◽

Magnetic Measurement ◽

Synthesis And Characterization ◽

Square Planar ◽

Square Planar Complexes ◽

Uv Visible

This research involves the preparation of new ligands 1,1,2,2- tetrakis (sodium acetate thio)ethylene(L1) and 1,1,2- tris(sodiumacetatethio) ethylene(L2), through the reaction of disodium thioglycolate) with tetra chloro ethylene or tri chloro ethylene in (1:4) or (1:3) moler ratio . Homodinucliar complexes of general formlu [M2(L1)] and [M2(L2)ClH2O] , when M= Co(II), Ni(II), Cu (II) and Zn(II) also mono nuclear complexes of general formula [M(L2)] . The prepared complexes were characterized using spectral method (UV/Visible/ IR) , metal content analysis , magnetic and atomic measurements . The spectral and magnetic measurement indicats that some complexes have tetrahedral or square planar complexes environtment .

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