Influence of particle size on non-Darcy seepage of water and sediment in fractured rock

Seepage mutation of fractured rock mass is one of the main inducements of dump slide and other disasters. Pore structure is a significant factor affecting the seepage characteristics of fractured rock mass, while particle size gradation has an important effect on the distribution of pore structure. Through the self-developed experimental system, the nonlinear seepage test on the fractured sandstones of the coalseam roof was conducted to investigate the influence of seepage pressure, porosity, and fractal dimension. Besides, the nonlinear seepage model was established by Barree–Conway theory. The results showed that, during the seepage process of fractured sandstone, there were significant nonlinear characteristics, which increased with the increase of the seepage pressure. With the increasing porosity, there was greater average pore size of fractured sandstone, stronger permeability, and weaker nonlinear seepage. The seepage characteristics approximated to that of Darcy model. However, with increasing grading fractal dimension, there were smaller average pore size of fractured sandstone, weaker permeability, and stronger nonlinear seepage. The seepage characteristics approximated to that of Forchheimer model.

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Metals distribution and particle size analysis in water and sediment of the Djetinja river and Dragica spring (Serbia)

Chemical Industry and Chemical Engineering Quarterly ◽

10.2298/ciceq100126036k ◽

2010 ◽

Vol 16 (4) ◽

pp. 363-372 ◽

Cited By ~ 1

Author(s):

Jelena Kiurski ◽

Milica Vucinic-Vasic ◽

Snezana Aksentijevic ◽

Uranija Kozmidis-Luburic ◽

Mirjana Vojinovic-Miloradov

Keyword(s):

Particle Size ◽

River Basin ◽

Size Range ◽

Suspended Solid ◽

Particle Size Analysis ◽

Size Analysis ◽

Sediment Samples ◽

Water And Sediment ◽

Zone Ii ◽

First Time

This paper reports the results on total metal concentration (Al, Fe, Cr, Cu, Ni and Zn) in water and sediment of the Djetinja river basin in the area of western Serbia. Samples were collected in spring season. Based on the comparison of the concentrations of all analyzed metals it is possible to differentiate two zones: zone I (sampling sites 1-4), affected by the discharge of the Dragica spring, and zone II (sites 5-8), affected by the confluence of the Dragica spring with the Djetinja river. The analysis of suspended solid particle size in water as well as in sediment samples were performed in size range 0.02-2000 mm and a positive correlation was found with the concentration of aluminium, zinc, iron and nickel in water samples. The study of particle size and metals distribution through the river basin of the Djetinja was a useful tool for getting information about the distribution degree of the polluting agents, and their possible evolution growth and pollution sources. The research of metals distribution and particle size analysis in water and sediment of the Djetinja river and Dragica spring (Serbia) was conducted for the first time.

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Microstructural characterization of laser-melted/roller-quenched dicalcium silicate

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100104972 ◽

1988 ◽

Vol 46 ◽

pp. 582-583

Author(s):

C. J. Chan ◽

K. R. Venkatachari ◽

W. M. Kriven ◽

J. F. Young

Keyword(s):

Particle Size ◽

Raw Materials ◽

Shape Change ◽

Microstructural Characterization ◽

Particle Size Effect ◽

Dicalcium Silicate ◽

Laser Melting ◽

Uniform Size ◽

Cell Shape Change ◽

Wide Range

Dicalcium silicate (Ca2SiO4) is a major component of Portland cement. It has also been investigated as a potential transformation toughener alternative to zirconia. It has five polymorphs: α, α'H, α'L, β and γ. Of interest is the β-to-γ transformation on cooling at about 490°C. This transformation, accompanied by a 12% volume increase and a 4.6° unit cell shape change, is analogous to the tetragonal-to-monoclinic transformation in zirconia. Due to the processing methods used, previous studies into the particle size effect were limited by a wide range of particle size distribution. In an attempt to obtain a more uniform size, a fast quench rate involving a laser-melting/roller-quenching technique was investigated.The laser-melting/roller-quenching experiment used precompacted bars of stoichiometric γ-Ca2SiO4 powder, which were synthesized from AR grade CaCO3 and SiO2xH2O. The raw materials were mixed by conventional ceramic processing techniques, and sintered at 1450°C. The dusted γ-Ca2SiO4 powder was uniaxially pressed into 0.4 cm x 0.4 cm x 4 cm bars under 34 MPa and cold isostatically pressed under 172 MPa. The γ-Ca2SiO4 bars were melted by a 10 KW-CO2 laser.

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Analytical Electron Microscopy study of two vehicle-aged automotive exhaust catalysts having dissimilar activities

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100153336 ◽

1989 ◽

Vol 47 ◽

pp. 272-273

Author(s):

Sooho Kim ◽

M. J. D’Aniello

Keyword(s):

Electron Microscopy ◽

Particle Size ◽

Noble Metal ◽

Catalyst Deactivation ◽

Analytical Electron Microscopy ◽

Microscopy Study ◽

Metal Particles ◽

Automotive Exhaust ◽

Exhaust Catalysts ◽

Analytical Electron

Automotive catalysts generally lose-agtivity during vehicle operation due to several well-known deactivation mechanisms. To gain a more fundamental understanding of catalyst deactivation, the microscopic details of fresh and vehicle-aged commercial pelleted automotive exhaust catalysts containing Pt, Pd and Rh were studied by employing Analytical Electron Microscopy (AEM). Two different vehicle-aged samples containing similar poison levels but having different catalytic activities (denoted better and poorer) were selected for this study.The general microstructure of the supports and the noble metal particles of the two catalysts looks similar; the noble metal particles were generally found to be spherical and often faceted. However, the average noble metal particle size on the poorer catalyst (21 nm) was larger than that on the better catalyst (16 nm). These sizes represent a significant increase over that found on the fresh catalyst (8 nm). The activity of these catalysts decreases as the observed particle size increases.

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