Sorption of Gaseous Pollutants on Ion Exchangers

2021 ◽  
pp. 315-351
Author(s):  
Hiroyuki Yoshida
TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 167-178 ◽  
Author(s):  
Xin Tong ◽  
Jiao Li ◽  
Jun Ma ◽  
Xiaoquan Chen ◽  
Wenhao Shen

Studies were undertaken to evaluate gaseous pollutants in workplace air within pulp and paper mills and to consider the effectiveness of photo-catalytic treatment of this air. Ambient air at 30 sampling sites in five pulp and paper mills of southern China were sampled and analyzed. The results revealed that formaldehyde and various benzene-based molecules were the main gaseous pollutants at these five mills. A photo-catalytic reactor system with titanium dioxide (TiO2) was developed and evaluated for degradation of formaldehyde, benzene and their mixtures. The experimental results demonstrated that both formaldehyde and benzene in their pure forms could be completely photo-catalytic degraded, though the degradation of benzene was much more difficult than that for formaldehyde. Study of the photo-catalytic degradation kinetics revealed that the degradation rate of formaldehyde increased with initial concentration fitting a first-order kinetics reaction. In contrast, the degradation rate of benzene had no relationship with initial concentration and degradation did not conform to first-order kinetics. The photo-catalytic degradation of formaldehyde-benzene mixtures indicated that formaldehyde behaved differently than when treated in its pure form. The degradation time was two times longer and the kinetics did not reflect a first-order reaction. The degradation of benzene was similar in both pure form and when mixed with formaldehyde.


2002 ◽  
Vol 1 (4) ◽  
pp. 577-588
Author(s):  
Eveline Popovici ◽  
Igor Cretescu ◽  
Elena Botezatu ◽  
Gabriela Soreanu ◽  
Alina Mihaela Hanu ◽  
...  

2013 ◽  
Vol 12 (1) ◽  
pp. 137-145 ◽  
Author(s):  
Iuliana Rogoveanu Radosavlevici ◽  
Dan Niculae Robescu
Keyword(s):  

1995 ◽  
Vol 32 (7) ◽  
pp. 199-206 ◽  
Author(s):  
Martin Oldenburg ◽  
Ivan Sekoulov

In this study the use of zeolites as ion-exchangers for equalization of ammonia peak loadings in aerated biological activated filters was investigated. For this use zeolites were mixed with a filter medium and the nitrifying filter was loaded with ammonia peaks for two hours at different flow rates. It could be demonstrated that during the phase of higher inflow concentrations the zeolite was collecting ammonia. When the influent concentration decreased ammonia was desorbed from the zeolite and could be nitrified by the bacteria growing on the filter medium. It was shown that additional zeolites can equalize variations of ammonia, especially in filter units which are working at a high nitrification rate and which are very sensitive to varying influent conditions. During the operation time of the filter no separation of the zeolite by higher hydraulic loading or by backwashing could be recognized. So the upgrading of nitrifying filters with zeolite represents an additional security for effluents containing oscillating ammonia concentrations.


1981 ◽  
Vol 46 (7) ◽  
pp. 1577-1587 ◽  
Author(s):  
Karel Jeřábek

Catalytic activity of ion exchangers prepared by partial sulphonation of styrene-divinylbenzene copolymers in reesterifications of ethyl acetate by methanol and propanol, hydrolysis of ethyl acetate and in synthesis of bisphenol A has been compared with data on polymer structure of these catalysts and with distribution of the crosslinking agent, divinylbenzene, calculated from literature data on kinetics of copolymerisation of styrene with divinylbenzene. It was found that the polymer structure of ion exchangers influences catalytic activity predominantly by changing the local concentration of acid active sites. The results obtained indicated that the effect of transport phenomena on the rate of catalytic reactions does not depend on the degree of swelling of the ion exchangers in reaction medium but it is mainly dependent on the relative affinity of reaction components to the acid groups or to the polymer skeleton.


1994 ◽  
Vol 59 (6) ◽  
pp. 1311-1318 ◽  
Author(s):  
Ladislav Svoboda ◽  
Petr Vořechovský

The properties of cellulose chelating ion exchangers Ostsorb have been studied in the sorption of cadmium and lead from aqueous solutions. The Cd(II) and Pb(II) ions are trapped by the Ostsorb OXIN and Ostsorb DETA ion exchangers most effectively in neutral and alkaline media but at these conditions formation of stable hydrolytic products of both metals competes with the exchange equilibria. From this point of view, Ostsorb DTTA appears to be a more suitable sorbent since it traps the Pb(II) and Cd(II) ions in acidic media already. Chloride ions interfere with the sorption of the two metals by Ostsorb DTTA whereas the ionic strength adjusted by the addition of sodium perchlorate does not affect the exchange capacity of this ion exchanger.


2020 ◽  
Vol 4 (1) ◽  
pp. 17
Author(s):  
Saisantosh Vamshi Harsha Madiraju ◽  
Ashok Kumar

Transportation sources are a major contributor to air pollution in urban areas. The role of air quality modeling is vital in the formulation of air pollution control and management strategies. Many models have appeared in the literature to estimate near-field ground level concentrations from mobile sources moving on a highway. However, current models do not account explicitly for the effect of wind shear (magnitude) near the ground while computing the ground level concentrations near highways from mobile sources. This study presents an analytical model based on the solution of the convective-diffusion equation by incorporating the wind shear near the ground for gaseous pollutants. The model input includes emission rate, wind speed, wind direction, turbulence, and terrain features. The dispersion coefficients are based on the near field parameterization. The sensitivity of the model to compute ground level concentrations for different inputs is presented for three different downwind distances. In general, the model shows Type III sensitivity (i.e., the errors in the input will show a corresponding change in the computed ground level concentrations) for most of the input variables. However, the model equations should be re-examined for three input variables (wind velocity at the reference height and two variables related to the vertical spread of the plume) to make sure that that the model is valid for computing ground level concentrations.


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