Retention Kinetics of Heavy Metals in Soils: Modeling Approaches

2000 ◽  
pp. 171-190
2021 ◽  
Vol 285 ◽  
pp. 06007
Author(s):  
Andrey Sorokin ◽  
Sergey Belopukhov ◽  
Vladimir Gukalov ◽  
Vitaly Savich ◽  
Ravil Baibekov ◽  
...  

The study proves the expediency of assessing the state of heavy metals in soils by the fractional composition of soil compounds, processes and modes. An informational and energy analysis of the state of heavy metals in soils was carried out. The need for an assessment of the kinetics of their desorption from soils was substantiated. The CH3 COONH4 solution displaced 0.3 mg/l Mn from the sod-podzolic soil within 10 minutes, 0.8 mg/l Mn – within 1 hour, 3.3 mg/l Mn – within 1 day, and 12.9 mg/l – within one week; 0.18 mg/L Pb was desorbed within 10 minutes, up to 0.59 mg/l Pb was desorbed within one day. The depositing capacity of soils is an important parameter. Heavy metals in soils are bound into positively and negatively charged systems at рКН of 2-10. In the sod-podzolic soil, the content of NiLn+ was 13.3 mg/l and NiLn-- 1.9 mg/l. According to the informational assessment, heavy metals in soils are characterized by the relationship with other soil properties and change along the soil profile, which was determined from the equations of pair correlation and multiple regression. According to the energy assessment, heavy metals in soils are characterized by thermal effects of their sorption and desorption and have positively and negatively charged complex compounds and air ions


2013 ◽  
Vol 12 (3) ◽  
pp. 239-247

The removal of heavy metals from wastewaters is a matter of paramount importance due to the fact that their high toxicity causes major environmental pollution problems. One of the most efficient, applicable and low cost methods for the removal of toxic metals from aqueous solutions is that of their adsorption on an inorganic adsorbent. In order to achieve high efficiency, it is important to understand the influence of the solution parameters on the extent of the adsorption, as well as the kinetics of the adsorption. In the present work, the adsorption of Cu(II) species onto TiO2 surface was studied. It was found that the adsorption is a rapid process and it is not affected by the value of ionic strength. In addition, it was found that by increasing the pH, the adsorbed amount of Cu2+ ions and the value of the adsorption constant increase, whereas the value of the lateral interaction energy decreases.


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