scholarly journals Colloidal Cu/ZnO catalysts for the hydrogenation of carbon dioxide to methanol: investigating catalyst preparation and ligand effects

2017 ◽  
Vol 7 (17) ◽  
pp. 3842-3850 ◽  
Author(s):  
Sebastian D. Pike ◽  
Andrés García-Trenco ◽  
Edward R. White ◽  
Alice H. M. Leung ◽  
Jonathan Weiner ◽  
...  

This paper reports on the influences of the catalyst preparation method and ligand effects for a series of highly active Cu/ZnO colloidal catalysts for the hydrogenation of CO2 to methanol.

2019 ◽  
Vol 7 (23) ◽  
pp. 14019-14026 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Sungho Yoon

A novel phenanthroline-functionalized porous organic polymer (phen-POP) has been designed, and prepared for the first time without other reactive functional groups in the polymer skeleton. Post-synthetic metalation of phen-POP with IrCl3 afforded a single-site, highly active and selective catalyst for the hydrogenation of CO2 to formate.


2017 ◽  
Vol 7 (18) ◽  
pp. 4233-4233
Author(s):  
Sebastian D. Pike ◽  
Andrés García-Trenco ◽  
Edward R. White ◽  
Alice H. M. Leung ◽  
Jonathan Weiner ◽  
...  

Correction for ‘Colloidal Cu/ZnO catalysts for the hydrogenation of carbon dioxide to methanol: investigating catalyst preparation and ligand effects’ by Sebastian D. Pike et al., Catal. Sci. Technol., 2017, DOI: 10.1039/c7cy01191a.


2015 ◽  
Vol 6 (1) ◽  
pp. 693-704 ◽  
Author(s):  
Sebastian Wesselbaum ◽  
Verena Moha ◽  
Markus Meuresch ◽  
Sandra Brosinski ◽  
Katharina M. Thenert ◽  
...  

The hydrogenation of CO2 to methanol using a recyclable molecular organometallic catalyst in the absence of an alcohol additive is demonstrated for the first time.


Nanoscale ◽  
2019 ◽  
Vol 11 (20) ◽  
pp. 9969-9979 ◽  
Author(s):  
Qingli Tang ◽  
Wenchao Ji ◽  
Christopher K. Russell ◽  
Yulong Zhang ◽  
Maohong Fan ◽  
...  

The hydrogenation of CO2 to CH3OH is one of the most promising technologies for the utilization of captured CO2 in the future.


2020 ◽  
Vol 49 (9) ◽  
pp. 2994-3000
Author(s):  
Karan Chaudhary ◽  
Manoj Trivedi ◽  
D. T. Masram ◽  
Abhinav Kumar ◽  
Girijesh Kumar ◽  
...  

Catalytic conversion of CO2via hydrogenation using in situ gaseous H2 (granulated tin metal and concentrated HCl) to produce the formate salt (HCO2−) with turnover number (TON) values of 326 to 1.065 × 105 in 12 h to 48 h of reaction at 25 °C to 80 °C has been reported.


Catalysts ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 795 ◽  
Author(s):  
Hua-Ping Ren ◽  
Shao-Peng Tian ◽  
Si-Yi Ding ◽  
Gui-Qiu Huang ◽  
Min Zhu ◽  
...  

Ni-C/SiO2 and Ni-G/SiO2 catalysts were prepared by a complexed-impregnation method using citric acid and glycine as complexing agents, respectively. Ni/SiO2 was also prepared by the conventional incipient impregnation method. All the catalysts were comparatively tested for carbon dioxide reforming of methane (CDR) at P = 1.0 atm, T = 750 °C, CO2/CH4 = 1.0, and GHSV = 60,000 mL·g−1·h−1. The results showed that Ni-C/SiO2 and Ni-G/SiO2 exhibited better CDR performance, especially regarding stability, than Ni/SiO2. The conversions of CH4 and CO2 were kept constant above 82% and 87% after 20 h of reaction over Ni-C/SiO2 and Ni-G/SiO2 while they were decreased from 81% and 88% to 56% and 59%, respectively, over the Ni/SiO2. The characterization results of the catalysts before and after the reaction showed that the particle size and the distribution of Ni, as well as the interactions between Ni and the support were significantly influenced by the preparation method. As a result, an excellent resistance to the coking deposition and the anti-sintering of Ni was obtained over the Ni-C/SiO2 and Ni-G/SiO2, leading to a highly active and stable CDR performance.


2016 ◽  
Vol 89 (1) ◽  
pp. 113-124 ◽  
Author(s):  
Wataru Aoki ◽  
Natdanai Wattanavinin ◽  
Shuhei Kusumoto ◽  
Kyoko Nozaki

2015 ◽  
Vol 51 (66) ◽  
pp. 13098-13101 ◽  
Author(s):  
Xinzheng Yang

A computationally designed aliphatic PNP iron complex as a mimic of the active center of [Fe]-hydrogenase for the hydrogenation of CO2.


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