Dynamic Recovery of Palladium Particles Dispersed in a Polymer-Containing Acetone Solution by Precipitation of 2-(Dimethylamino)ethyl Methacrylate and Styrene Copolymers

2020 ◽  
Vol 53 (7) ◽  
pp. 280-286
Author(s):  
Takafumi Kajiwara ◽  
Wataru Kasaishi ◽  
Shintaro Morisada ◽  
Keisuke Ohto ◽  
Hidetaka Kawakita
Keyword(s):  
Dynamic Recovery ◽  
Acetone Solution ◽  
Ethyl Methacrylate ◽  
Styrene Copolymers ◽  
Palladium Particles

Postmortem and in situ TEM methods to study the mechanism of failure in controlled-morphology high-impact polystrene resin

1996 ◽  
Vol 54 ◽  
pp. 178-179
Author(s):  
R. C. Cieslinski ◽  
M. T. Dineen ◽  
J. L. Hahnfeld
Keyword(s):  
Poisson Ratio ◽  
Acrylonitrile Butadiene Styrene ◽  
High Impact ◽  
In Situ Tem ◽  
Styrene Copolymers ◽  
Controlled Morphology ◽  
Point Bend ◽  
Mechanism Of Failure ◽  
Impact Energies

Advanced Styrenic resins are being developed throughout the industry to bridge the properties gap between traditional HIPS (High Impact Polystyrene) and ABS (Acrylonitrile-Butadiene-Styrene copolymers) resins. These new resins have an unprecedented balance of high gloss and high impact energies. Dow Chemical's contribution to this area is based on a unique combination of rubber morphologies including labyrinth, onion skin, and core-shell rubber particles. This new resin, referred as a controlled morphology resin (CMR), was investigated to determine the toughening mechanism of this unique rubber morphology. This poster will summarize the initial studies of these resins using the double-notch four-point bend test of Su and Yee, tensile stage electron microscopy, and Poisson Ratio analysis of the fracture mechanism.

The Effect of Secondary Metalworking Processes on Susceptibility of Aircraft to Catastrophic Failures and Prevention Methods

2013 ◽  
Vol 58 (4) ◽  
pp. 1207-1212
Author(s):  
E.S. Dzidowski
Keyword(s):  
Dynamic Recovery ◽  
Fatigue Cracks ◽  
Shear Bands ◽  
Adiabatic Shear ◽  
Deformation Mechanisms ◽  
Processing Maps ◽  
Adiabatic Shear Bands ◽  
Flow Localization ◽  
Catastrophic Failures ◽  
Prevention Methods

Abstract The causes of plane crashes, stemming from the subcritical growth of fatigue cracks, are examined. It is found that the crashes occurred mainly because of the negligence of the defects arising in the course of secondary metalworking processes. It is shown that it is possible to prevent such damage, i.e. voids, wedge cracks, grain boundary cracks, adiabatic shear bands and flow localization, through the use of processing maps indicating the ranges in which the above defects arise and the ranges in which safe deformation mechanisms, such as deformation in dynamic recrystallization conditions, superplasticity, globularization and dynamic recovery, occur. Thanks to the use of such maps the processes can be optimized by selecting proper deformation rates and forming temperatures.

TACTIX 740 and TACTIX 741 RESINS

Alloy Digest ◽  
1991 ◽  
Vol 40 (12) ◽  
Keyword(s):  
Physical Properties ◽  
Acetone Solution ◽  
Chemical Company ◽  
High Durability ◽  
Melt Adhesives ◽  
Hot Melt

Abstract TACTIX 740 resin offers high durability for hot melt adhesives. TACTIX 741, an acetone solution of TACTIX 740, is designed for composites prepared by solution prepregging. This datasheet provides information on composition and physical properties. Filing Code: P-32. Producer or source: The Dow Chemical Company, Dow Plastics.

scholarly journals Tuning the Cloud-Point and Flocculation Temperature of Poly(2-(diethylamino)ethyl methacrylate)-Based Nanoparticles via a Postpolymerization Betainization Approach

2021 ◽  
Author(s):  
Matthieu P. J. Miclotte ◽  
Stefan B. Lawrenson ◽  
Spyridon Varlas ◽  
Bilal Rashid ◽  
Emma Chapman ◽  
...  
Keyword(s):  
Cloud Point ◽  
Ethyl Methacrylate

scholarly journals Dynamic Softening Mechanisms and Microstructure Evolution of TB18 Titanium Alloy during Uniaxial Hot Deformation

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 789
Author(s):  
Qiang Fu ◽  
Wuhua Yuan ◽  
Wei Xiang
Keyword(s):  
Titanium Alloy ◽  
Dynamic Recovery ◽  
True Strain ◽  
Hot Workability ◽  
Compression Tests ◽  
Phase Zone ◽  
Β Phase ◽  
Stability And Instability ◽  
Dynamic Softening ◽  
Transus Temperature

In this study, isothermal compression tests of TB18 titanium alloy were conducted using a Gleeble 3800 thermomechanical simulator for temperatures ranging from 650 to 880 °C and strain rates ranging from 0.001 to 10 s−1, with a constant height reduction of 60%, to investigate the dynamic softening mechanisms and hot workability of TB18 alloy. The results showed that the flow stress significantly decreased with an increasing deformation temperature and decreasing strain rate, which was affected by the competition between work hardening and dynamic softening. The hyperbolic sine Arrhenius-type constitutive equation was established, and the deformation activation energy was calculated to be 303.91 kJ·mol−1 in the (α + β) phase zone and 212.813 kJ·mol−1 in the β phase zone. The processing map constructed at a true strain of 0.9 exhibited stability and instability regions under the tested deformation conditions. The microstructure characteristics demonstrated that in the stability region, the dominant restoration and flow-softening mechanisms were the dynamic recovery of β phase and dynamic globularization of α grains below transus temperature, as well as the dynamic recovery and continuous dynamic recrystallization of β grains above transus temperature. In the instability region, the dynamic softening mechanism was flow localization in the form of a shear band and a deformation band caused by adiabatic heating.

Stimuli-responsive polymersomes of poly [2-(dimethylamino) ethyl methacrylate]-b-polystyrene

2021 ◽  
Author(s):  
Valdomiro V. de Souza ◽  
Gustavo P. B. Carretero ◽  
Phelipe A. M. Vitale ◽  
Íris Todeschini ◽  
Paloma O. Kotani ◽  
...  
Keyword(s):  
Stimuli Responsive ◽  
Ethyl Methacrylate

scholarly journals Sustainable Myrcene-Based Elastomers via a Convenient Anionic Polymerization

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 838
Author(s):  
David Hermann Lamparelli ◽  
Magdalena Maria Kleybolte ◽  
Malte Winnacker ◽  
Carmine Capacchione
Keyword(s):  
Anionic Polymerization ◽  
Sodium Hydride ◽  
Reactivity Ratios ◽  
Molecular Weights ◽  
Styrene Copolymers ◽  
Wide Range ◽  
Elastomeric Materials ◽  
Complete Study ◽  
Anionic Copolymerization ◽  
Trialkylaluminum Derivatives

Soluble heterocomplexes consisting of sodium hydride in combination with trialkylaluminum derivatives have been used as anionic initiating systems at 100 °C in toluene for convenient homo-, co- and ter-polymerization of myrcene with styrene and isoprene. In this way it has been possible to obtain elastomeric materials in a wide range of compositions with interesting thermal profiles and different polymeric architectures by simply modulating the alimentation feed and the (monomers)/(initiator systems) ratio. Especially, a complete study of the myrcene-styrene copolymers (PMS) was carried out, highlighting their tapered microstructures with high molecular weights (up to 159.8 KDa) and a single glass transition temperature. For PMS copolymer reactivity ratios, rmyr = 0.12 ± 0.003 and rsty = 3.18 ± 0.65 and rmyr = 0.10 ± 0.004 and rsty = 3.32 ± 0.68 were determined according to the Kelen–Tudos (KT) and extended Kelen–Tudos (exKT) methods, respectively. Finally, this study showed an easy accessible approach for the production of various elastomers by anionic copolymerization of renewable terpenes, such as myrcene, with commodities.

Sign in / Sign up

Export Citation Format

Share Document