scholarly journals Study of the Adsorption Mechanism and the Structure of Adsorbed Layers of Polyelectrolytes at the Metal Oxide/Solution Interface

2001 ◽  
Vol 19 (5) ◽  
pp. 409-421 ◽  
Author(s):  
S. Chibowski ◽  
M. Wiśniewska
Keyword(s):  
Molecular Weight ◽  
Zeta Potential ◽  
Metal Oxide ◽  
Polymer Adsorption ◽  
Solid Particles ◽  
Polymer Molecular Weight ◽  
Oh Groups ◽  
Solution Interface ◽  
Adsorbed Polymer ◽  
Principal Factors

The influence of the molecular weight of polyacrylic acid (PAA) and polyacrylamide (PAM) as well as of inorganic contaminants on the ZrO2 surface on the adsorption and electrokinetic properties of the metal oxide/polyelectrolyte solution interface were studied for ZrO2 and Fe2O3 solid particles. The calculated concentrations of the various surface groups on ZrO2 and Fe2O3 enabled an investigation of the possible mechanism for the bonding of the studied polyelectrolytes with the surfaces of both oxides. PAA and PAM macromolecules bond with the solid surface mainly via the –OH groups of the oxides, which may interact with the carboxy groups of polyelectrolytes through hydrogen bridging. A comparison of the change in values of the diffuse layer charge with the surface charge enabled the principal factors responsible for the changes in the zeta potential of the oxides, e.g. pH, polymer molecular weight and concentration of the polymer solutions, to be evaluated. From such zeta potential values, it was possible to determine the free energies of adsorption of PAA and PAM on the surfaces of both oxides. The thicknesses of adsorbed polymer layers on Fe2O3 and ZrO2 were calculated on the basis of measurements of their suspension viscosities in the absence and presence of adsorbed polymer. It was shown that the thickness of the adsorption layer increased with increasing polymer molecular weight, pH and concentration of the polymer solution. Because the experimental determination of the number and the length of trains, loops and tails in such polyelectrolytes was not possible, the participation of such segments of polymer structure at the interface was computed using the Scheutjens–Fleer model of polymer adsorption. The polymer adsorption expressed as the number of equivalent monolayers was calculated and compared with the experimental data.

scholarly journals Studies of Some Properties and the Structure of Polyethylene Glycol (PEG) Macromolecules Adsorbed on a TiO2 Surface

2001 ◽  
Vol 19 (5) ◽  
pp. 397-407 ◽  
Author(s):  
S. Chibowski ◽  
M. Paszkiewicz
Keyword(s):  
Molecular Weight ◽  
Polyethylene Glycol ◽  
Zeta Potential ◽  
Surface Charge ◽  
Adsorption Layer ◽  
Bulk Solution ◽  
Ionic Structure ◽  
Solution Interface ◽  
Main Factors ◽  
Presence And Absence

In the studies presented, the influence of the molecular weight of polyethylene glycol (PEG) on the adsorption and electrical properties at the metal oxide/polymer solution interface has been determined. The main factors responsible for the observed changes in the zeta potential and surface charge of titania were determined on the basis of the data obtained. It was demonstrated that changes in the ionic structure of the Stern layer depend on the molecular weight of PEG and its conformation. A possible mechanism for the changes in zeta potential both with pH and molecular weight was proposed on the basis of values of the surface charge difference (Δσ0) and the diffuse layer charge difference (Δσd) as determined in the presence and absence of the polymer. The thickness of the adsorption layer (δ) on the surface of titania was calculated from the zeta potential changes, both in the presence and absence of the polymer. A distinct influence of the PEG molecular weight was noted on the values of the adsorption layer thickness (δ) determined. The structures of the macromolecules in solution and at the solid/solution interface were compared and from the dependencies obtained some changes in the shape and dimensions of the polymer coils on passing from the bulk solution to the interface were proposed.

scholarly journals Adsorption of Polyelectrolytes at the Manganese Oxide(IV)–Polymer Solution Interface: Structure of Adsorbed Layers

2002 ◽  
Vol 20 (5) ◽  
pp. 511-522 ◽  
Author(s):  
S. Chibowski ◽  
M. Wiśniewska ◽  
M. Paszkiewicz
Keyword(s):  
Molecular Weight ◽  
Zeta Potential ◽  
Manganese Oxide ◽  
Polymer Solution ◽  
Adsorption Layer ◽  
Interface Structure ◽  
Ionic Polymers ◽  
Free Energies ◽  
Solution Interface ◽  
Adsorbed Layers

The influence of the molecular weight of polyelectrolytes on their adsorption and on the structure of the adsorbed layers at the manganese oxide(IV)–polymer solution interface was determined. Polyacrylic acid (PAA) and polyacrylamide (PAM) were applied as ionic polymers. An explanation was proposed for the observed changes in surface charge and zeta potential of the solid in the presence of these polymers. The thickness of the adsorption layer of PAA and PAM was determined and the free energies of adsorption of these polymers on the MnO2 surface were calculated from the zeta potential measurements.

Crystallization of Isotactic Poly(propylene) in Solution as Followed by Slow Calorimetry

1995 ◽  
Vol 60 (11) ◽  
pp. 1905-1924 ◽  
Author(s):  
Hong Phuong-Nguyen ◽  
Geneviève Delmas
Keyword(s):  
Molecular Weight ◽  
Crystal Growth ◽  
High Temperature ◽  
Heat Of Fusion ◽  
Complete Dissolution ◽  
Polymer Molecular Weight ◽  
Solvent Quality ◽  
Temperature Ramp ◽  
Poly Propylene

Dissolution, crystallization and second dissolution traces of isotactic poly(propylene) have been obtained in a slow temperature ramp (3 K h-1) with the C80 Setaram calorimeter. Traces of phase-change, in presence of solvent, are comparable to traces without solvent. The change of enthalpy on heating or cooling, ∆Htotal, over the 40-170 °C temperature range, is the sum of two contributions, ∆HDSC and ∆Hnetwork. The change ∆HDSC is the usual heat obtained in a fast temperature ramp and ∆Hnetwork is associated with a physical network whose disordering is slow and subject to superheating due to strain. When dissolution is complete, ∆Htotal is equal to ∆H0, the heat of fusion of perfect crystals. The values of ∆Htota for nascent and recrystallized samples are compared. Dissolution is the tool to evaluate the quality of the crystals. The repartition of ∆Htotal, into the two endotherms, reflects the quality of crystals. The crystals grown more rapidly have a higher fraction of network crystals which are stable at high T in the solvents. A complete dissolution, i.e. a high temperature (170 °C or more) is necessary to obtain good crystals. The effect of concentration, polymer molecular weight and solvent quality on crystal growth is analyzed.

scholarly journals Development of Highly Efficient, Glassy Carbon Foam Supported, Palladium Catalysts for Hydrogenation of Nitrobenzene

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1172
Author(s):  
Ádám Prekob ◽  
Mahitha Udayakumar ◽  
Gábor Karacs ◽  
Ferenc Kristály ◽  
Gábor Muránszky ◽  
...  
Keyword(s):  
Zeta Potential ◽  
Glassy Carbon ◽  
Palladium Nanoparticles ◽  
Palladium Catalysts ◽  
Sucrose Solution ◽  
Supported Catalyst ◽  
Carbon Foam ◽  
Hydroxyl Groups ◽  
Polyurethane Elastomers ◽  
Oh Groups

Glassy carbon foam (GCF) catalyst supports were synthesized from waste polyurethane elastomers by impregnating them in sucrose solution followed by pyrolysis and activation (AC) using N2 and CO2 gas. The palladium nanoparticles were formed from Pd(NO3)2. The formed palladium nanoparticles are highly dispersive because the mean diameters are 8.0 ± 4.3 (Pd/GCF), 7.6 ± 4.2 (Pd/GCF-AC1) and 4.4 ± 1.6 nm (Pd/GCF-AC2). Oxidative post-treatment by CO2 of the supports resulted in the formation of hydroxyl groups on the GCF surfaces, leading to a decrease in zeta potential. The decreased zeta potential increased the wettability of the GCF supports. This, and the interactions between –OH groups and Pd ions, decreased the particle size of palladium. The catalysts were tested in the hydrogenation of nitrobenzene. The non-treated, glassy-carbon-supported catalyst (Pd/GCF) resulted in a 99.2% aniline yield at 293 K and 50 bar hydrogen pressure, but the reaction was slightly slower than other catalysts. The catalysts on the post-treated (activated) supports showed higher catalytic activity and the rate of hydrogenation was higher. The maximum attained aniline selectivities were 99.0% (Pd/GCF-AC1) at 293 K and 98.0% (Pd/GCF-AC2) at 323 K.

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