Effects of thermal aging on mechanical properties of laminated lead and natural rubber bearing

2014 ◽  
Vol 6 (2) ◽  
pp. 127-140 ◽  
Author(s):  
Dookie Kim ◽  
Ju Oh ◽  
Jeongyun Do ◽  
Jinyoung Park
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Thermal Aging ◽  
Rubber Bearing

The Effect of Thermal Aging on Mechanical Properties and Morphological Properties of Thermoplastic Vulcanizates Based on Natural Rubber and Polystyrene

2020 ◽  
Vol 990 ◽  
pp. 262-266
Author(s):  
Prathumrat Nu-Yang ◽  
Atiwat Wiriya-Amornchai ◽  
Jaehoon Yoon ◽  
Chainat Saechau ◽  
Poom Rattanamusik
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Natural Rubber ◽  
Thermal Aging ◽  
Morphological Properties ◽  
Vulcanized Rubber ◽  
Thermoplastic Vulcanizates ◽  
Internal Mixer ◽  
Processing Properties

Thermoplastic vulcanizates or TPVs is a type of materials exhibiting excellent properties between thermoplastic and elastomer by combining the characteristics of vulcanized rubber with the processing properties of thermoplastics. This research aims to study the effect of thermal aging on the morphology and mechanical properties of thermoplastic vulcanizates (TPVs) based on a mixture of natural rubber (NR) and polystyrene (PS). TPVs samples were prepared using the internal mixer at a mass ratio of NR/PS 70/30, 50/50, 30/70 and 0/100. Tensile properties and impact strength showed that when the amount of NR increased tends of impact strength and elongation at break increased but tends of tensile strength decreased. On the other hand, tends of tensile strength for thermal aging at 70°C for 3 days increased when the amount of PS increase. The blending ratio of NR / PS at 70/30 is the best. It gave a worthy increase from 19.94 MPa to be 25.56 MPa (28.18%).

Effects of Thermal Aging on The Mechanical Properties of Natural Rubber

2003 ◽  
Vol 76 (4) ◽  
pp. 785-802 ◽  
Author(s):  
Joseph T. South ◽  
Scott W. Case ◽  
Kenneth L. Reifsnider
Keyword(s):  
Mechanical Properties ◽  
Thermal Degradation ◽  
Natural Rubber ◽  
Thermal Aging ◽  
Master Curve ◽  
Dynamic Mechanical Properties ◽  
Rubber Compound ◽  
Dynamic Mechanical ◽  
Rubber Vulcanizate

Abstract The focus of this research was to investigate the effect of thermal degradation upon the mechanical properties of a natural rubber compound. We examined both the quasi-static and dynamic mechanical properties of a natural rubber vulcanizate which had been subjected to isothermal, anaerobic aging. The thermal aging was conducted between the temperatures of 80 °C and 120 °C for times ranging from 3 to 24 days. The effect of thermal degradation was measured using the changes in the crosslink distribution of the vulcanizates as functions of time at temperature. A master curve relationship between the crosslink distribution of the vulcanizates due to thermal degradation and the static and dynamic mechanical properties has been developed. It was found that the both the quasi-static and dynamic mechanical properties correlated with the percentage of poly and monosulfidic crosslinks, where in general higher levels of polysulfidic crosslink gave rise to the highest mechanical properties.

Thermal aging on mechanical properties and crosslinked network of natural rubber/zinc Dimethacrylate composites

2011 ◽  
Vol 124 (3) ◽  
pp. 2240-2249 ◽  
Author(s):  
Chuanhui Xu ◽  
Yukun Chen ◽  
Jing Huang ◽  
Xingrong Zeng ◽  
Jianping Ding
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Thermal Aging

EFFECT OF ZINC DITHIOCARBAMATES AND THIAZOLE-BASED ACCELERATORS ON THE VULCANIZATION OF NATURAL RUBBER

2012 ◽  
Vol 85 (1) ◽  
pp. 120-131 ◽  
Author(s):  
Md. Najib Alam ◽  
Swapan Kumar Mandal ◽  
Subhas Chandra Debnath
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
Reaction Mechanism ◽  
Natural Rubber ◽  
High Performance ◽  
Binary Systems ◽  
Synergistic Activity ◽  
Tetramethylthiuram Disulfide

Abstract Several zinc dithiocarbamates (ZDCs) as accelerator derived from safe amine has been exclusively studied in the presence of thiazole-based accelerators to introduce safe dithiocarbamate in the vulcanization of natural rubber. Comparison has been made between conventional unsafe zinc dimethyldithiocarbamate (ZDMC) with safe novel ZDC combined with thizole-based accelerators in the light of mechanical properties. The study reveals that thiuram disulfide and 2-mercaptobenzothiazole (MBT) are always formed from the reaction either between ZDC and dibenzothiazyledisulfide (MBTS) or between ZDC and N-cyclohexyl-2-benzothiazole sulfenamide (CBS). It has been conclusively proved that MBT generated from MBTS or CBS reacts with ZDC and produces tetramethylthiuram disulfide. The observed synergistic activity has been discussed based on the cure and physical data and explained through the results based on high-performance liquid chromatography and a reaction mechanism. Synergistic activity is observed in all binary systems studied. The highest tensile strength is observed in the zinc (N-benzyl piperazino) dithiocarbamate-accelerated system at 3:6 mM ratios. In respect of tensile strength and modulus value, unsafe ZDMC can be successfully replaced by safe ZDCs in combination with thiazole group containing accelerator.

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