scholarly journals Thermal Decomposition and Combustion Behavior of Plastics with Flame Retardant

2009 ◽  
Vol 4 (2) ◽  
pp. 264-275
Author(s):  
Tomohiko FURUHATA ◽  
Yasuo YAMAMOTO ◽  
Akira ISHII ◽  
Kenji AMAGAI ◽  
Masataka ARAI
2007 ◽  
Vol 73 (734) ◽  
pp. 2160-2168 ◽  
Author(s):  
Yasuo YAMAMOTO ◽  
Akira ISHII ◽  
Kenji AMAGAI ◽  
Tomohiko FURUHATA ◽  
Masataka ARAI

2014 ◽  
Vol 983 ◽  
pp. 190-193
Author(s):  
Cai Yun Sun ◽  
Yong Li Yang ◽  
Ming Gao

Wood has been treated with amino resins and amino resins modified with phosphoric acid to impart flame retardancy. The thermal degradation of samples has been studied by thermogravimetry (TG) in air. From the resulting data, kinetic parameters for different stages of thermal degradation are obtained following the method of Broido. For the decomposition of wood and flame retardant wood, the activation energy is found to decrease from 122 to 72 kJmol-1.


BioResources ◽  
2014 ◽  
Vol 9 (3) ◽  
Author(s):  
Na Xiao ◽  
Xue Zheng ◽  
Shuping Song ◽  
Junwen Pu

2018 ◽  
Vol 1 (1) ◽  
pp. 1-13 ◽  
Author(s):  
Hao Wu ◽  
Rogelio Ortiz ◽  
Renan De Azevedo Correa ◽  
Mourad Krifa ◽  
Joseph H. Koo

AbstractIncorporation of flame-retardant (FR) additives and nanoclay fillers into thermoplastic polymers effectively suppresses materials flammability and melt dripping behavior. However, it largely affects other properties, such as toughness and ductility. In order to recover the lost toughness and ductility of flame retardant polyamide 6, various loadings of maleic anhydride modified SEBS elastomer were added and processed by twin screw extrusion. TEM images showed exfoliated nanoclay platelets and reveals that the clay platelets well dispersed in the polymer matrix. By balancing the ratio of flame retardants, nanoclay and elastomers, formulation with elongation at break as high as 76% was achieved. Combining conventional intumescent FR and nanoclay, UL-94 V-0 rating and the LOI value as high as 32.2 were achieved. In conclusion, effective self-extinguishing and non-drip polyamide 6 nanocomposite formulations with significant improvement in toughness and ductility were achieved.


2020 ◽  
Vol 31 (8) ◽  
pp. 1836-1846 ◽  
Author(s):  
Weiwei Zhang ◽  
Wenchao Zhang ◽  
Zhaolu Qin ◽  
Xin Zhang ◽  
Fan Yang ◽  
...  

2019 ◽  
Vol 956 ◽  
pp. 181-191
Author(s):  
Jian Lin Xu ◽  
Bing Xue Ma ◽  
Cheng Hu Kang ◽  
Cheng Cheng Xu ◽  
Zhou Chen ◽  
...  

The thermal decomposition kinetics of polybutylene terephthalate (PBT) and flame-retardant PBT (FR-PBT) were investigated by thermogravimetric analysis at various heating rates. The kinetic parameters were determined by using Kissinger, Flynn-Wall-Ozawa and Friedman methods. The y (α) and z (α) master plots were used to identify the thermal decomposition model. The results show that the rate of residual carbon of FR-PBT is higher than that of PBT and the maximum mass loss rate of FR-PBT is lower than that of PBT. The values of activation energy of PBT (208.71 kJ/mol) and FR-PBT (244.78 kJ/mol) calculated by Kissinger method were higher than those of PBT (PBT: 195.54 kJ/mol) and FR-PBT (FR-PBT: 196.00 kJ/mol) calculated by Flynn-Wall-Ozawa method and those of PBT and FR-PBT (PBT: 199.10 kJ/mol, FR-PBT: 206.03 kJ/mol) calculated by Friedman methods. There is a common thing that the values of activation energy of FR-PBT are higher than that of PBT in different methods. The thermal decomposition reaction models of the PBT and FR-PBT can be described by Avarami-Erofeyev model (A1).


RSC Advances ◽  
2017 ◽  
Vol 7 (27) ◽  
pp. 16866-16877 ◽  
Author(s):  
B. Prieur ◽  
M. Meub ◽  
M. Wittemann ◽  
R. Klein ◽  
S. Bellayer ◽  
...  

Lignin is an abundant polyphenol biopolymeric material chemically functionalisable to act as flame retardant in polymers.


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