scholarly journals Research on a method of eliminating the line broadening caused by the wavelength shift based on the first harmonic

2021 ◽  
Author(s):  
Qi-xing Tang ◽  
Yujun Zhang ◽  
Dong Chen ◽  
Ying He
Keyword(s):  
Wavelength Shift ◽  
Line Broadening

LINE BROADENING IN THE FERROELECTRIC K4Fe(CN)6·3H2O

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-31-C6-34
Author(s):  
F. PLACIDO
Keyword(s):  
Line Broadening

Nondestructive Inspection of Thin, Low-Z Samples using Multiplexed Compton Scatter Tomography

1997 ◽  
Vol 503 ◽  
Author(s):  
B. L. Evans ◽  
J. B. Martin ◽  
L. W. Burggraf
Keyword(s):  
Signal To Noise Ratio ◽  
Reconstruction Algorithm ◽  
Filtered Backprojection ◽  
Line Broadening ◽  
Compton Scatter ◽  
X Ray ◽  
Tomography System ◽  
Transmission Computed Tomography ◽  
High Purity Germanium ◽  
Scattered Energy

ABSTRACTThe viability of a Compton scattering tomography system for nondestructively inspecting thin, low Z samples for corrosion is examined. This technique differs from conventional x-ray backscatter NDI because it does not rely on narrow collimation of source and detectors to examine small volumes in the sample. Instead, photons of a single energy are backscattered from the sample and their scattered energy spectra are measured at multiple detector locations, and these spectra are then used to reconstruct an image of the object. This multiplexed Compton scatter tomography technique interrogates multiple volume elements simultaneously. Thin samples less than 1 cm thick and made of low Z materials are best imaged with gamma rays at or below 100 keV energy. At this energy, Compton line broadening becomes an important resolution limitation. An analytical model has been developed to simulate the signals collected in a demonstration system consisting of an array of planar high-purity germanium detectors. A technique for deconvolving the effects of Compton broadening and detector energy resolution from signals with additive noise is also presented. A filtered backprojection image reconstruction algorithm with similarities to that used in conventional transmission computed tomography is developed. A simulation of a 360–degree inspection gives distortion-free results. In a simulation of a single-sided inspection, a 5 mm × 5 mm corrosion flaw with 50% density is readily identified in 1-cm thick aluminum phantom when the signal to noise ratio in the data exceeds 28.

Solvent-Ligand Interactions in Colloidal Nanocrystals

2018 ◽  
Author(s):  
Jonathan De Roo ◽  
Nuri Yazdani ◽  
Emile Drijvers ◽  
Alessandro Lauria ◽  
Jorick Maes ◽  
...  
Keyword(s):  
Direct Method ◽  
Line Broadening ◽  
H Nmr ◽  
Size Dependent ◽  
Line Shape Analysis ◽  
Wide Range ◽  
Nanocrystal Synthesis ◽  
Ligand Interactions ◽  
Indispensable Tool ◽  
Theoretical Evidence

<p>Although solvent-ligand interactions play a major role in nanocrystal synthesis, dispersion formulation and assembly, there is currently no direct method to study this. Here we examine the broadening of <sup>1</sup>H NMR resonances associated with bound ligands, and turn this poorly understood descriptor into a tool to assess solvent-ligand interactions. We show that the line broadening has both a homogeneous and a heterogeneous component. The former is nanocrystal-size dependent and the latter results from solvent-ligand interactions. Our model is supported by experimental and theoretical evidence that correlates broad NMR lines with poor ligand solvation. This correlation is found across a wide range of solvents, extending from water to hexane, for both hydrophobic and hydrophilic ligand types, and for a multitude of oxide, sulfide and selenide nanocrystals. Our findings thus put forward NMR line shape analysis as an indispensable tool to form, investigate and manipulate nanocolloids.</p>

Critical Raman line shape behavior of fluid nitrogen

2004 ◽  
Vol 76 (1) ◽  
pp. 147-155 ◽  
Author(s):  
M. Musso ◽  
F. Matthai ◽  
D. Keutel ◽  
K.-L. Oehme
Keyword(s):  
Raman Line ◽  
Line Shape ◽  
Line Broadening ◽  
Vibrational Resonance ◽  
Critical Isochore ◽  
Molecular Fluids ◽  
Detection Techniques ◽  
Gas Phases ◽  
Line Shapes ◽  
Band Position

Isotropic Raman line shapes of simple molecular fluids exhibit critical line broadening near their respective liquid-gas critical points. In order to observe this phenomenon, it is essential that the band position of a given vibrational mode is density-dependent, and that vibrational depopulation processes negligibly contribute to line broadening. Special attention was given to the fact that the isotropic (i.e., nonrotationally broadened) line shape of liquid N2 is affected by resonant intermolecular vibrational interactions between identical oscillators. By means of the well-chosen isotopic mixture (14N2).975 - (14N15N).025, the temperature and density dependences of shift, width, and asymmetry of the resonantly coupled 14N2 and, depending on the S/N ratio available, of the resonantly uncoupled 14N15N were determined, with up to milli-Kelvin resolution, in the coexisting liquid and gas phases and along the critical isochore, using a highest-resolution double monochromator and modern charge-coupled device detection techniques. Clear evidence was found that vibrational resonance couplings are present in all dense phases studied.

scholarly journals Compact omnidirectional multicore fiber-based vector bending sensor

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Josu Amorebieta ◽  
Angel Ortega-Gomez ◽  
Gaizka Durana ◽  
Rubén Fernández ◽  
Enrique Antonio-Lopez ◽  
...  
Keyword(s):  
Single Mode ◽  
High Accuracy ◽  
Single Mode Fiber ◽  
Wavelength Shift ◽  
Short Segment ◽  
Light Power ◽  
Highly Sensitive ◽  
Bending Sensor ◽  
Asymmetric Multicore ◽  
Multicore Fiber

AbstractWe propose and demonstrate a compact and simple vector bending sensor capable of distinguishing any direction and amplitude with high accuracy. The sensor consists of a short segment of asymmetric multicore fiber (MCF) fusion spliced to a standard single mode fiber. The reflection spectrum of such a structure shifts and shrinks in specific manners depending on the direction in which the MCF is bent. By monitoring simultaneously wavelength shift and light power variations, the amplitude and bend direction of the MCF can be unmistakably measured in any orientation, from 0° to 360°. The bending sensor proposed here is highly sensitive even for small bending angles (below 1°).

scholarly journals Toward Engineering Intrinsic Line Widths and Line Broadening in Perovskite Nanoplatelets

ACS Nano ◽  
2021 ◽  
Vol 15 (4) ◽  
pp. 6499-6506
Author(s):  
Albert Liu ◽  
Gabriel Nagamine ◽  
Luiz G. Bonato ◽  
Diogo B. Almeida ◽  
Luiz F. Zagonel ◽  
...  
Keyword(s):  
Line Broadening ◽  
Line Widths
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