Facile nitration of aromatic compounds using Bi(NO3)3·5H2O/MgSO4 under mechanochemical conditions

Abstract Bi(NO3)3·5H2O/MgSO4 was developed as an efficient and green reagent for the nitration of aromatic compounds under mechanochemistry (or ball milling) condition. While aromatics with weak activating groups such as phenyl could be nitrated by this reagent with 100% conversion, aromatics with weak deactivating groups such as chloro- or bromo- could also be nitrated but with moderate conversion and regioselectivity with big para/ortho ratios. The in situ generated N2O4 or NO2 due to the decomposition of Bi(NO3)3·5H2O promoted by MgSO4 should be responsible for this mechanochemical nitration.

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Mechanochemical sulfonation of aromatic compounds using NaHSO4·H2O/P2O5

Journal of Chemical Research ◽

10.1177/17475198211032571 ◽

2021 ◽

pp. 174751982110325

Author(s):

Lu-Lu Zuo ◽

Shuai Qin ◽

Pu Zhang ◽

Yu-Jun Qin ◽

Zhi-Xin Guo

Keyword(s):

Ball Milling ◽

Aromatic Compounds ◽

High Speed ◽

Sulfonic Acids ◽

High Speed Ball Milling

A series of aromatic sulfonic acids is synthesized by subjecting arenes and NaHSO4·H2O to high-speed ball milling in the presence of P2O5. It is suggested the aromatic sulfonation occurs via in situ generated H2SO4 to give aromatic sulfonic acids. In some cases, formation of diaryl sulfones was observed.

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Regioselective Functionalization of N-Fused Heteroaromatics via FeCl3-Catalyzed Nucleophilic Addition to Activated N-Heterocycles

Synthesis ◽

10.1055/s-0040-1705985 ◽

2020 ◽

Author(s):

Ikyon Kim ◽

Sung June Kim ◽

Sunhee Lee

Keyword(s):

Aromatic Compounds ◽

Nucleophilic Addition ◽

Chemical Space ◽

Wide Range ◽

Regioselective Functionalization

AbstractBroadening of nitrogen-fused heteroaromatic chemical space such as indolizine and pyrrolo[1,2-a]pyrazine was achieved via FeCl3-catalyzed nucleophilic addition of these N-fused aromatic compounds to a wide range of azolinium systems generated in situ, leading to novel N-fused heteroaromatic scaffolds with dearomatized N-heterocyclic substituents regioselectively. Nucleophilic addition of indolizines and pyrrolo[1,2-a]pyrazines mainly occurred at the C1 position of the isoquinoliniums and at the C4 site of the quinoliniums.

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In‐Situ Synthesis of MoS 2 /BiOBr Material via Mechanical Ball Milling for Boosted Photocatalytic Degradation Pollutants Performance

ChemistrySelect ◽

10.1002/slct.202004316 ◽

2021 ◽

Vol 6 (5) ◽

pp. 928-936

Author(s):

Weiqing Yin ◽

Xujing Cao ◽

Bin Wang ◽

Qi Jiang ◽

Zhigang Chen ◽

...

Keyword(s):

Photocatalytic Degradation ◽

Ball Milling ◽

In Situ Synthesis ◽

Mechanical Ball Milling

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Design of Ionic Liquid 3-Methyl-1-sulfonic Acid Imidazolium Nitrate as Reagent for the Nitration of Aromatic Compounds by in Situ Generation of NO2 in Acidic Media

The Journal of Organic Chemistry ◽

10.1021/jo300137w ◽

2012 ◽

Vol 77 (7) ◽

pp. 3640-3645 ◽

Cited By ~ 103

Author(s):

Mohammad A. Zolfigol ◽

Ardeshir Khazaei ◽

Ahmad R. Moosavi-Zare ◽

Abdolkarim Zare ◽

Hendrik G. Kruger ◽

...

Keyword(s):

Ionic Liquid ◽

Aromatic Compounds ◽

Sulfonic Acid ◽

Acidic Media ◽

In Situ Generation

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ChemInform Abstract: A General Method for the Preparation of Zirconocene Complexes of Substituted Benzynes: in situ Generation, Coupling Reactions, and Use in the Synthesis of Polyfunctionalized Aromatic Compounds.

ChemInform ◽

10.1002/chin.198810300 ◽

1988 ◽

Vol 19 (10) ◽

Author(s):

S. L. BUCHWALD ◽

B. T. WATSON ◽

R. T. LUM ◽

W. A. NUGENT

Keyword(s):

Aromatic Compounds ◽

Coupling Reactions ◽

In Situ Generation ◽

General Method

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Mechanical Properties of Nanocrystalline Materials Produced by In Situ Consolidation Ball Milling

Materials Science Forum ◽

10.4028/www.scientific.net/msf.579.15 ◽

2008 ◽

Vol 579 ◽

pp. 15-28 ◽

Cited By ~ 8

Author(s):

Carl C. Koch ◽

Khaled M. Youssef ◽

Ron O. Scattergood

Keyword(s):

Mechanical Properties ◽

Ball Milling ◽

Nanocrystalline Materials ◽

Preparation Method ◽

High Strength ◽

Al Alloys ◽

Ductile Metals ◽

Cu Alloys ◽

Bulk Nanocrystalline

This paper reviews a method, “in situ consolidation ball milling” that provides artifactfree bulk nanocrystalline samples for several ductile metals such as Zn, Al and Al alloys, and Cu and Cu alloys. The preparation method is described in this paper and examples of the mechanical behavior of nanocrystalline materials made by this technique are given. It is found that in such artifact-free metals, combinations of both high strength and good ductility are possible.

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