Phosphorescence Lifetimes of [Cr(NCS)6]-3 in Frozen Alcohol Solvents
AbstractFor [Cr(NCS)6]-3 in normal alcohols at 77 K the lifetimes of phosphorescence from the excited doublet state are reported. The lifetimes decrease in the order ethanol > methanol > n-propanol > n-butanol > n-pentanol > n-hexanol > n-heptanol, and the rate constant increases exponentially when the 0'-0 band energy of the 2Eg → 4A2g transition decreases.
2014 ◽
Vol 118
(28)
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pp. 7869-7877
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1993 ◽
Vol 70
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pp. 326-331
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2018 ◽
Vol 6
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pp. 45
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2018 ◽
1970 ◽
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pp. 97-105
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1984 ◽
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pp. 97-109
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pp. 487-493
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pp. 3024-3028