scholarly journals Efficient Solution Processed CH3NH3PbI3 Perovskite Solar Cells with PolyTPD Hole Transport Layer

2019 ◽  
Vol 74 (8) ◽  
pp. 665-672 ◽  
Author(s):  
Julian Höcker ◽  
David Kiermasch ◽  
Philipp Rieder ◽  
Kristofer Tvingstedt ◽  
Andreas Baumann ◽  
...  
Keyword(s):  
Solar Cells ◽  
Surface Coverage ◽  
Energy Levels ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer ◽  
Solvent Engineering ◽  
Highest Occupied Molecular Orbital

AbstractThe organic and hydrophobic polymer poly[N, N′-bis(4-butilphenyl)-N, N′-bis(phenyl)-benzidine] (polyTPD) represents a promising hole transport layer (HTL) for perovskite photovoltaics due to its suitable energy levels, whereby its highest occupied molecular orbital level matches well with the valence band level of methylammonium lead triiodide (CH3NH3PbI3, MAPbI3) perovskite. However, processing a perovskite layer from the solution on the surface of this organic material, is found to be difficult due to the surface properties of the latter. In this study, we evaluate efficient p-i-n type MAPbI3 perovskite solar cells employing differently processed polyTPD layers. We found that the surface coverage of the MAPbI3 perovskite layer strongly depends on the preparation method of the underlying polyTPD layer. By varying the solvents for the polyTPD precursor, its concentration, and by applying an optimised two-step perovskite deposition technique we increased both the surface coverage of the perovskite layer as well as the power conversion efficiency (PCE) of the corresponding solar cell devices. Our simple solvent-engineering approach demonstrates that no further interface modifications are needed for a successful preparation of efficient planar photovoltaic devices with PCEs in the range of 15 %–16 %.

scholarly journals CuI/Spiro-OMeTAD Double-Layer Hole Transport Layer to Improve Photovoltaic Performance of Perovskite Solar Cells

Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 978
Author(s):  
Chaoqun Lu ◽  
Weijia Zhang ◽  
Zhaoyi Jiang ◽  
Yulong Zhang ◽  
Cong Ni
Keyword(s):  
Solar Cells ◽  
Double Layer ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Perovskite Layer

The hole transport layer (HTL) is one of the main factors affecting the efficiency and stability of perovskite solar cells (PSCs). However, obtaining HTLs with the desired properties through current preparation techniques remains a challenge. In the present study, we propose a new method which can be used to achieve a double-layer HTL, by inserting a CuI layer between the perovskite layer and Spiro-OMeTAD layer via a solution spin coating process. The CuI layer deposited on the surface of the perovskite film directly covers the rough perovskite surface, covering the surface defects of the perovskite, while a layer of CuI film avoids the defects caused by Spiro-OMetad pinholes. The double-layer HTLs improve roughness and reduce charge recombination of the Spiro-OMeTAD layer, thereby resulting in superior hole extraction capabilities and faster hole mobility. The CuI/Spiro-OMeTAD double-layer HTLs-based devices were prepared in N2 gloveboxes and obtained an optimized PCE (photoelectric conversion efficiency) of 17.44%. Furthermore, their stability was improved due to the barrier effect of the inorganic CuI layer on the entry of air and moisture into the perovskite layer. The results demonstrate that another deposited CuI film is a promising method for realizing high-performance and air-stable PSCs.

scholarly journals Facile NiOx Sol-Gel Synthesis Depending on Chain Length of Various Solvents without Catalyst for Efficient Hole Charge Transfer in Perovskite Solar Cells

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1227 ◽  
Author(s):  
Byung Kim ◽  
Woongsik Jang ◽  
Dong Wang
Keyword(s):  
Solar Cells ◽  
Chain Length ◽  
Short Circuit ◽  
Sol Gel ◽  
Perovskite Solar Cells ◽  
Open Circuit ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer

Nickel oxide (NiOx)–based perovskite solar cells (PSCs) have recently gained considerable interest, and exhibit above 20% photovoltaic efficiency. However, the reported syntheses of NiOx sol-gel used toxic chemicals for the catalysts during synthesis, which resulted in a high-temperature annealing requirement to remove the organic catalysts (ligands). Herein, we report a facile “NiOx sol-gel depending on the chain length of various solvents” method that eschews toxic catalysts, to confirm the effect of different types of organic solvents on NiOx synthesis. The optimized conditions of the method resulted in better morphology and an increase in the crystallinity of the perovskite layer. Furthermore, the use of the optimized organic solvent improved the absorbance of the photoactive layer in the PSC device. To compare the electrical properties, a PSC was prepared with a p-i-n structure, and the optimized divalent alcohol-based NiOx as the hole transport layer. This improved the charge transport compared with that for the typical 1,2-ethanediol (ethylene glycol) used in earlier studies. Finally, the optimized solvent-based NiOx enhanced device performance by increasing the short-circuit current density (Jsc), open-circuit voltage (Voc), and fill factor (FF), compared with those of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)–based devices.

scholarly journals Enhanced Efficiencies of Perovskite Solar Cells by Incorporating Silver Nanowires into the Hole Transport Layer

Micromachines ◽  
2019 ◽  
Vol 10 (10) ◽  
pp. 682 ◽  
Author(s):  
Chien-Jui Cheng ◽  
Rathinam Balamurugan ◽  
Bo-Tau Liu
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Silver Nanowires ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer ◽  
Iodide Ions ◽  
Poly Styrene Sulfonate

In this study, we incorporated silver nanowires (AgNWs) into poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) as a hole transport layer (HTL) for inverted perovskite solar cells (PVSCs). The effect of AgNW incorporation on the perovskite crystallization, charge transfer, and power conversion efficiency (PCE) of PVSCs were analyzed and discussed. Compared with neat PEDOT:PSS HTL, incorporation of few AgNWs into PEDOT:PSS can significantly enhance the PCE by 25%. However, the AgNW incorporation may result in performance overestimation due to the lateral charge transfer. The corrosion of AgNWs with a perovskite layer was discussed. Too much AgNW incorporation may lead to defects on the interface between the HTL and the perovskite layer. An extra PEDOT:PSS layer over the pristine PEDOT:PSS-AgNW layer can prevent AgNWs from corrosion by iodide ions.

scholarly journals Improved efficiency and reduced hysteresis in ultra-stable fully printable mesoscopic perovskite solar cells through incorporation of CuSCN into the perovskite layer

2019 ◽  
Vol 7 (14) ◽  
pp. 8073-8077 ◽  
Author(s):  
Iwan Zimmermann ◽  
Paul Gratia ◽  
David Martineau ◽  
Giulia Grancini ◽  
Jean-Nicolas Audinot ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer ◽  
Term Stability ◽  
Long Term Stability ◽  
Carbon Based

Improved charge extraction in carbon-based fully printable hole transport layer-free mesoscopic perovskite solar cells with excellent long-term stability.

scholarly journals Investigation of the S-Shaped Current–Voltage Curve in High Open-Circuit Voltage Ruddlesden–Popper Perovskite Solar Cells

2021 ◽  
Vol 9 ◽  
Author(s):  
Hong Zhong ◽  
Renlai Zhou ◽  
Xiaoqing Wu ◽  
Xiaoyun Lin ◽  
Ya Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Open Circuit Voltage ◽  
Phase Distribution ◽  
Perovskite Solar Cells ◽  
Open Circuit ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer ◽  
Current Voltage

We report our investigation on the S-shaped current–voltage characteristics in a hot-casting–processed (BA)2 (MA)3Pb4I13 Ruddlesden–Popper (RP) perovskite solar cell. The two-dimensional perovskite solar cells are fabricated with NiOx as the hole transport layer (HTL), which leads to significantly high open-circuit voltage (Voc). The champion device shows a Voc of 1.21 V and a short current density (Jsc) of 17.14 mA/cm2, leading to an overall power conversion efficiency (PCE) of 13.7%. Although the PCE is much higher than the control device fabricated on PEDOT:PSS, a significant S-shaped current–voltage behavior is observed in these NiOx-based devices. It is found that the S-shaped current–voltage behavior is related to the lower dimensional phase distribution and crystallinity at the bottom interface of the RP perovskite layer, and the S-shaped distortion is less severe after the device ageing test.

scholarly journals Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells

Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3895
Author(s):  
Tian Yuan ◽  
Jin Li ◽  
Shimin Wang
Keyword(s):  
Graphene Oxide ◽  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer ◽  
Hybrid Perovskite ◽  
Polystyrene Sulfonic Acid ◽  
The Cost

It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl) (P3HT) are very expensive. Here, 3,4-ethylenedioxythiophene (EDOT) monomers are in-situ polymerized on the surface of graphene oxide (GO) as PEDOT-GO film. Compared to frequently used polystyrene sulfonic acid (PSS), GO avoids the corrosion of the perovskite and the use of H2O solvent. The composite PEDOT-GO film is between carbon pair electrode and perovskite layer as hole transport layer (HTL). The highest power conversion efficiency (PCE) is 14.09%.

scholarly journals Polymer/Inorganic Hole Transport Layer for Low-Temperature-Processed Perovskite Solar Cells

Energies ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 2059 ◽  
Author(s):  
Neda Irannejad ◽  
Narges Yaghoobi Nia ◽  
Siavash Adhami ◽  
Enrico Lamanna ◽  
Behzad Rezaei ◽  
...  
Keyword(s):  
Solar Cells ◽  
Thermal Stress ◽  
Low Temperature ◽  
Cell Structure ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Ambient Conditions ◽  
Perovskite Layer

In the search for improvements in perovskite solar cells (PSCs), several different aspects are currently being addressed, including an increase in the stability and a reduction in the hysteresis. Both are mainly achieved by improving the cell structure, employing new materials or novel cell arrangements. We introduce a hysteresis-free low-temperature planar PSC, composed of a poly(3-hexylthiophene) (P3HT)/CuSCN bilayer as a hole transport layer (HTL) and a mixed cation perovskite absorber. Proper adjustment of the precursor concentration and thickness of the HTL led to a homogeneous and dense HTL on the perovskite layer. This strategy not only eliminated the hysteresis of the photocurrent, but also permitted power conversion efficiencies exceeding 15.3%. The P3HT/CuSCN bilayer strategy markedly improved the life span and stability of the non-encapsulated PSCs under atmospheric conditions and accelerated thermal stress. The device retained more than 80% of its initial efficiency after 100 h (60% after 500 h) of continuous thermal stress under ambient conditions. The performance and durability of the PSCs employing a polymer/inorganic bilayer as the HTL are improved mainly due to restraining perovskite ions, metals, and halides migration, emphasizing the pivotal role that can be played by the interface in the perovskite-additive hole transport materials (HTM) stack.

Enhancing Performance of Perovskite Solar Cells by TiCl4 Treatment on the Surface Roughness of the Titanium Dioxide Layer

2021 ◽  
Vol 21 (7) ◽  
pp. 3806-3812
Author(s):  
Truyen Hai Dang ◽  
Sangmo Kim ◽  
Maro Kim ◽  
Chung Wung Bark
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Metal Electrode ◽  
Hole Transport ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Hole Transport Layer ◽  
Perovskite Layer ◽  
And Performance

Perovskite solar cells have been attracting extensive attention because of their superior photovoltaic performances and lower costs as compared to those of prevailing photovoltaic technologies. There are four main interfaces in perovskite solar cells: flourine-doped tin oxide/electron transport layer, electron transport layer/perovskite layer, perovskite layer/hole transport layer, and hole transport layer/metal electrode. Among them, the interface between the perovskite layer (general formula RPbX3) and electron transport layer significantly affects the power conversion efficiency. In this study, a layer of TiO2, which is the most popular metal oxides used for perovskite solar cells applications, was deposited as the electron transport layer. To enhance the perovskite solar cells performance, surface treatment was performed with TiCl4 (80 mM). To investigate the effect of TiCl4 treatment, ultraviolet-visible spectroscopy was performed on the perovskite film. Atomic force microscopy, X-ray diffraction, scanning electron microscopy and performance of perovskite solar cells have been also evaluated in this paper. The results indicated that the TiCl4 treatment significantly improved the perovskite solar cells performance.

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