Die Kristallstruktur des 1:1-Komplexes von Antimontrichlorid und 2.2′-Bipyridin / The Crystal Structure of the 1:1 Complex of Antimony Trichloride and 2,2′-Bipyridine
1980 ◽
Vol 35
(12)
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pp. 1548-1551
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Keyword(s):
The crystal structure of the complex compound of SbCl3 with a chelating bipyridyl group was determined. Sb(C10H8N2)Cl3 crystallizes in the space group P21/c with a = 818.9(4), b = 695.8(7), c = 2331.3(12) pm, β = 103.59(4)° and Z = 4 molecules per unit cell. The SbCl3 fragment is T-shaped with <Sb-Cl> at 254.7 pm. Taking into account also the N atoms of the chelating 2,2′-bipyridyl group (<Sb-N> = 228.1 pm) and an intermolecular Sb···Cl contact at 334.0 pm the Sb coordination is distorted octahedral.
1992 ◽
Vol 47
(4)
◽
pp. 594-596
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1992 ◽
Vol 47
(1-2)
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pp. 177-181
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Keyword(s):
1996 ◽
Vol 51
(1)
◽
pp. 133-138
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Keyword(s):