Characterization of Photochemically or Electrochemically Reduced Blue Titanium Dioxide
1990 ◽
Vol 45
(6)
◽
pp. 864-870
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Keyword(s):
Blue TiO2 which is formed under UV irradiation under inert gases in the presence of hole scavengers is characterized. The concentration of surface-trapped electrons which cause the blue colour was analytically determined after irradiation in the presence of methanol or other organic compounds. The saturation concentration is controlled by a dynamic equilibrium of photoreduction and reoxidation of the reduced surface sites which leads to H2 formation. The blue colour can also be produced by chemical or electrochemical reduction. Mobility of the surface-trapped electrons in an electrical field gradient is demonstrated. The reduced TiO2 is similar to a hydrogen titanium bronze.
2011 ◽
Vol 3
(8)
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pp. 645-648
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2012 ◽
Vol 1225
◽
pp. 174-181
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2014 ◽
Vol 15
(8)
◽
pp. 593-605
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2006 ◽
Vol 89
(2)
◽
pp. 720-723
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