scholarly journals Formation of Hydrides in the Surface Layer of Aluminum in NonEquilibrium Conditions of Electrolyte Plasma

2019 ◽  
Vol 20 (2) ◽  
pp. 181-184
Author(s):  
L. Fedorenkova
Keyword(s):  
Diffusion Layer ◽  
Hydrogen Atoms ◽  
Equilibrium Conditions ◽  
Heating And Cooling ◽  
Polymorphic Modifications ◽  
High Heating ◽  
Aluminum Hydrides ◽  
Micromechanical Characteristics ◽  
Nonequilibrium Conditions ◽  
Non Equilibrium

In this paper, the formation of a diffusion layer on aluminum, which includes aluminum hydrides, in non-equilibrium conditions of electrolyte plasma with high local temperatures, high heating and cooling rates were studied. As a result of the research it was obtained that in the diffusion layer formed complex nanosized inclusions of polymorphic modifications (AlН3)n and AlB3H12. The diffusion in the non-equilibrium conditions of the electrolyte plasma is carried out in hydrogen environment, where the hydrogen atoms have the greatest energy and is one of the main forces that activate the diffusion process and influence the structure, composition and micromechanical characteristics of the diffusion layer.

scholarly journals A time-domain phase diagram of metastable states in a charge ordered quantum material

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jan Ravnik ◽  
Michele Diego ◽  
Yaroslav Gerasimenko ◽  
Yevhenii Vaskivskyi ◽  
Igor Vaskivskyi ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Time Domain ◽  
Metastable States ◽  
Scanning Tunneling ◽  
Photon Density ◽  
Tunneling Microscopy ◽  
Equilibrium Conditions ◽  
Time Resolved ◽  
A Charge ◽  
Non Equilibrium

AbstractMetastable self-organized electronic states in quantum materials are of fundamental importance, displaying emergent dynamical properties that may be used in new generations of sensors and memory devices. Such states are typically formed through phase transitions under non-equilibrium conditions and the final state is reached through processes that span a large range of timescales. Conventionally, phase diagrams of materials are thought of as static, without temporal evolution. However, many functional properties of materials arise as a result of complex temporal changes in the material occurring on different timescales. Hitherto, such properties were not considered within the context of a temporally-evolving phase diagram, even though, under non-equilibrium conditions, different phases typically evolve on different timescales. Here, by using time-resolved optical techniques and femtosecond-pulse-excited scanning tunneling microscopy (STM), we track the evolution of the metastable states in a material that has been of wide recent interest, the quasi-two-dimensional dichalcogenide 1T-TaS2. We map out its temporal phase diagram using the photon density and temperature as control parameters on timescales ranging from 10−12 to 103 s. The introduction of a time-domain axis in the phase diagram enables us to follow the evolution of metastable emergent states created by different phase transition mechanisms on different timescales, thus enabling comparison with theoretical predictions of the phase diagram, and opening the way to understanding of the complex ordering processes in metastable materials.

Emergence of a Promiscuous Peroxidase Under Non‐Equilibrium Conditions

2021 ◽  
Author(s):  
Sumit Pal ◽  
Antara Reja ◽  
Subhajit Bal ◽  
Baishakhi Tikader ◽  
Dibyendu Das
Keyword(s):  
Equilibrium Conditions ◽  
Non Equilibrium

scholarly journals Quantification of fast molecular adhesion by fluorescence footprinting

2021 ◽  
Author(s):  
Adam B. Yasunaga ◽  
Isaac T.S. Li
Keyword(s):  
Shear Stress ◽  
Dynamic Range ◽  
Force Distribution ◽  
Equilibrium Conditions ◽  
Ligand Dissociation ◽  
Molecular Adhesion ◽  
Molecular Force ◽  
Adhesion Complex ◽  
Non Equilibrium

AbstractRolling adhesion is a unique process in which the adhesion events are short-lived and operate under highly non-equilibrium conditions. These characteristics pose a challenge in molecular force quantification, where in situ measurement of such forces cannot be achieved with most molecular force sensors that probe near equilibrium. In this report, we demonstrated a quantitative adhesion footprint assay combining DNA-based non-equilibrium force probes and modelling to measure the molecular force involved in fast rolling adhesion. We were able to directly profile the ensemble molecular force distribution during rolling adhesion with a dynamic range between 0 – 18 pN. Our results showed that the shear stress driving bead rolling motility directly controls the molecular tension on the probe-conjugated adhesion complex. Furthermore, the shear stress can steer the dissociation bias of components within the molecular force probe complex, favouring either DNA probe dissociation or receptor-ligand dissociation.

scholarly journals Hydrogen non-equilibrium ionisation effects in coronal mass ejections

2020 ◽  
Vol 637 ◽  
pp. A49
Author(s):  
P. Pagano ◽  
A. Bemporad ◽  
D. H. Mackay
Keyword(s):  
Magnetic Flux ◽  
Visible Light ◽  
Coronal Mass Ejections ◽  
Flux Rope ◽  
Neutral Hydrogen ◽  
Hydrogen Atoms ◽  
Mhd Simulation ◽  
Magnetic Flux Rope ◽  
New Generation ◽  
Non Equilibrium

Context. A new generation of coronagraphs used to study solar wind and coronal mass ejections (CMEs) are being developed and launched. These coronagraphs will heavily rely on multi-channel observations where visible light (VL) and UV-EUV (ultraviolet-extreme ultraviolet) observations provide new plasma diagnostics. One of these instruments, Metis on board ESA-Solar Orbiter, will simultaneously observe VL and the UV Lyman-α line. The number of neutral hydrogen atoms (a small fraction of coronal protons) is a key parameter for deriving plasma properties, such as the temperature from the observed Lyman-α line intensity. However, these measurements are significantly affected if non-equilibrium ionisation effects occur, which can be relevant during CMEs. Aims. The aim of this work is to determine if non-equilibrium ionisation effects are relevant in CMEs and, in particular, when and in which regions of the CME plasma ionisation equilibrium can be assumed for data analysis. Methods. We used a magneto-hydrodynamic (MHD) simulation of a magnetic flux rope ejection to generate a CME. From this, we then reconstructed the ionisation state of hydrogen atoms in the CME by evaluating both the advection of neutral and ionised hydrogen atoms and the ionisation and recombination rates in the MHD simulation. Results. We find that the equilibrium ionisation assumption mostly holds in the core of the CME, which is represented by a magnetic flux rope. In contrast, non-equilibrium ionisation effects are significant at the CME front, where we find about 100 times more neutral hydrogen atoms than prescribed by ionisation equilibrium conditions. We find this to be the case even if this neutral hydrogen excess might be difficult to identify due to projection effects. Conclusions. This work provides key information for the development of a new generation of diagnostic techniques that aim to combine visible light and Lyman-α line emissions. The results show that non-equilibrium ionisation effects need to be considered when we analyse CME fronts. Incorrectly assuming equilibrium ionisation in these regions would lead to a systematic underestimate of plasma temperatures.

Kinetic study of CO2 plasmas under non-equilibrium conditions. II. Input of vibrational energy

2018 ◽  
Vol 27 (11) ◽  
pp. 115009 ◽  
Author(s):  
M Grofulović ◽  
T Silva ◽  
B L M Klarenaar ◽  
A S Morillo-Candas ◽  
O Guaitella ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Vibrational Energy ◽  
Equilibrium Conditions ◽  
Non Equilibrium
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