scholarly journals Determination of metal content and an assessment of the potential use of waste cashew nut ash (CNSA) as a source for potash production

BioResources ◽  
2010 ◽  
Vol 6 (1) ◽  
pp. 529-536
Author(s):  
Mary B. Ogundiran ◽  
Joshua O. Babayemi ◽  
Chima G. Nzeribe

The potential use of waste cashew nut shell (CNS) ash as a source for potash production was investigated in this study. Managing waste ash generated from cashew nut processing is a major challenge, as land filling and open dumping of the waste ashes have been the main options in management of the ash in Nigeria. Economically viable ways of using waste ash rather than having to dispose of it have to be investigated. The CNS was air-dried for 4 weeks and combusted to ashes; the resulting ash was extracted with water for its potash content. Some parameters of the CNS, including moisture, dry matter, and ash content, were determined. Potash yield obtained was 33.4% of 150 g CNS ash used; analysis of the potash gave it a percentage purity of 78%, while purity on recrystalization increased to 86%. Potash yield from CNS ash was comparable to those reported for wood ash, plantain peels, and other agro-wastes. Also, the results showed that the CNS shared similar lignocellulosic properties and characteristics with hardwood biomass.

2021 ◽  
Vol 20 (2) ◽  
pp. 13-22
Author(s):  
A.C. Igboamalu ◽  
U.J. Chukwu ◽  
K. Okorosaye-Orubite

Cashew nut shell liquid (CNSL) extract obtained using soxhlet extraction method with acetone as solvent has been used in the synthesis of Co (II) and Zn (II) metal complexes. The CNSL gave a molecular peak ion of 298g/mol-1 on a GC-MS, an indication that cardanol was more prominent than anacardic acid in the obtained extract. Physicochemical parameters such as saponification value (50.30 mgKOH/g), moisture content (5.10), iodine value (241.00 mgKOH/g), ash content (1.30) and pH (6.31) were equally obtained. The metal complexes of Co (II) and Zn (II) prepared with unmodified (UMCNSL) and aniline modified CNSL (AMCNSL) were characterized using UV-visible, FTIR, melting point and electrical conductivity. Some characteristic FTIR bands were observed for AMCNSL, UMCNCL, AMCNSL-ZnCl2.H2O (1612cm-1) and AMCNSL-CoCl2.6H2O (1612cm-1). The presence of C=N were confirmed in the metal complex of AMCNSL-ZnCl.H2O and AMCNSL-CoCl.6H2O but were not present in the UMCNSL-ZnCl.H2O and UMCNSL-CoCl.6H2O.


2020 ◽  
Vol 45 (1) ◽  
pp. 325-334
Author(s):  
R. Y. Aderinboye ◽  
A. A. Busari ◽  
O. N. Olaoye ◽  
O. O. Adelusi ◽  
K. O Adebayo ◽  
...  

Effect of cashew nut shell liquid (CNSL) in diets for West African dwarf (WAD) goats on protein digestibility and utilization was evaluated in vitro and in vivo. Four diets consisting of Panicum maximum supplemented with concentrate pellets containing 0, 5, 10 and 15mL/kg of CNSL were used. Panicum and pellets were combined in ratio 70: 30 of required dry matter (DM). For in vitro experiment, 500 mg (n=8 per diet) of diet samples (DM basis) were incubated at 39°C for 48 h following the procedure of Menke and Steingass (1988). Dry matter and crude protein digestibility, ammonia nitrogen (NH3-N) and bacteria count were determined after 24 and 48 h incubation by recovering feed residues and rumen liquor. For in vivo experiment, twenty-four WAD goats were divided into four groups of six animals each. Each group was fed one of the four diets at 5% body weight (DM basis). Dry matter and crude protein intake, weight gain, protein efficiency ratio, rumen NH3-N, bacteria count and crudeprotein digestibility were measured during 98 days of feeding and digestibility trial. Experiments were arranged in a completely randomized design and data analyzed using one way analysis of variance procedure of SAS (1999). Results showed that 5 – 15 mL/kg CNSL in supplemental pellets reduced (P < 0.05) protein digestibility in vitro but increased (P < 0.05) total-tract protein digestibility in vivo. In vitro rumen NH3-N decreased (P < 0.05) with 5 – 15ml CNSL inclusion after 24 and 48 h. At 30 and 60 days post-feeding, 10 – 15 mL CNSL reduced (P < 0.05) rumen NH3-N in goats Protein efficiency ratio was higher (P < 0.05) with CNSL and goats fed 15 mL CNSL had the highest (P < 0.05) protein efficiency ratio. Rume bacteria population in vitro and in vivo decreased (P < 0.05) with 5 – 15 mL CNSL in supplemental pellets. In conclusion, the reduced in vitro protein digestibility with reduced NH3-Nproduction and bacteria population in vitro and in vivo suggests an inhibitory effect of CNSL on rumen proteolysis. Cashew nut shell liquid in supplemental pellet for WAD goats up to 15 mL/kg therefore inhibited dietary protein breakdown in the rumen with consequent improvement in protein digestibility and utilization at the lower tract.


2015 ◽  
Vol 804 ◽  
pp. 283-286
Author(s):  
Sangwoei Sawekwiharee ◽  
Thanaporn Boonchoo ◽  
Anchana Kuttiyawong ◽  
Naphat Chathirat

We study the heating energy of briquettes from cashew nut shell (CNS), cultivated in south Thailand. CNS briquettes (CNSB) were produced by mixing CNS powder with the cassava starch ratio 5:1w/w. A chemical component analysis of the CNSB was performed, and the heat utilization efficiency was compared with firewood charcoal. CNSB were found to have a fixed carbon content of 49.2%, ash content of 4.2% (750°C°C at 6 hours), and moisture content of 6.6% (105°C for 24 hours). It was observed that CNSB consists of energy consumption at 0.440-0.456 KW/kg and high compressive strength of 60.2 kg/cm2.The value of heat utilization efficiency obtained inside the fuel briquette of 18.01%, attributed to the burn rate average at 11.90 g/min. CNSB could be used to replace firewood and reduce cost for heating manufacturing processes.


TAPPI Journal ◽  
2012 ◽  
Vol 11 (10) ◽  
pp. 9-17
Author(s):  
ALESSANDRA GERLI ◽  
LEENDERT C. EIGENBROOD

A novel method was developed for the determination of linting propensity of paper based on printing with an IGT printability tester and image analysis of the printed strips. On average, the total fraction of the surface removed as lint during printing is 0.01%-0.1%. This value is lower than those reported in most laboratory printing tests, and more representative of commercial offset printing applications. Newsprint paper produced on a roll/blade former machine was evaluated for linting propensity using the novel method and also printed on a commercial coldset offset press. Laboratory and commercial printing results matched well, showing that linting was higher for the bottom side of paper than for the top side, and that linting could be reduced on both sides by application of a dry-strength additive. In a second case study, varying wet-end conditions were used on a hybrid former machine to produce four paper reels, with the goal of matching the low linting propensity of the paper produced on a machine with gap former configuration. We found that the retention program, by improving fiber fines retention, substantially reduced the linting propensity of the paper produced on the hybrid former machine. The papers were also printed on a commercial coldset offset press. An excellent correlation was found between the total lint area removed from the bottom side of the paper samples during laboratory printing and lint collected on halftone areas of the first upper printing unit after 45000 copies. Finally, the method was applied to determine the linting propensity of highly filled supercalendered paper produced on a hybrid former machine. In this case, the linting propensity of the bottom side of paper correlated with its ash content.


2020 ◽  
Vol 13 (2) ◽  
pp. 105-109
Author(s):  
E. S. Dremicheva

This paper presents a method of sorption using peat for elimination of emergency spills of crude oil and petroleum products and the possibility of energy use of oil-saturated peat. The results of assessment of the sorbent capacity of peat are presented, with waste motor oil and diesel fuel chosen as petroleum products. Natural peat has been found to possess sorption properties in relation to petroleum products. The sorbent capacity of peat can be observed from the first minutes of contact with motor oil and diesel fuel, and significantly depends on their viscosity. For the evaluation of thermal properties of peat saturated with petroleum products, experimental studies have been conducted on determination of moisture and ash content of as-fired fuel. It is shown that adsorbed oil increases the moisture and ash content of peat in comparison with the initial sample. Therefore, when intended for energy use, peat saturated with petroleum products is to be subjected to additional drying. Simulation of net calorific value has been performed based on the calorific values of peat and petroleum products with different ratios of petroleum product content in peat and for a saturated peat sample. The obtained results are compared with those of experiments conducted in a calorimetric bomb and recalculated for net calorific value. A satisfactory discrepancy is obtained, which amounts to about 12%. Options have been considered providing for combustion of saturated peat as fuel (burnt per se and combined with a solid fuel) and processing it to produce liquid, gaseous and solid fuels. Peat can be used to solve environmental problems of elimination of emergency spills of crude oil and petroleum products and as an additional resource in solving the problem of finding affordable energy.


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