Energetic properties of peat saturated with petroleum products

2020 ◽  
Vol 13 (2) ◽  
pp. 105-109
Author(s):  
E. S. Dremicheva

This paper presents a method of sorption using peat for elimination of emergency spills of crude oil and petroleum products and the possibility of energy use of oil-saturated peat. The results of assessment of the sorbent capacity of peat are presented, with waste motor oil and diesel fuel chosen as petroleum products. Natural peat has been found to possess sorption properties in relation to petroleum products. The sorbent capacity of peat can be observed from the first minutes of contact with motor oil and diesel fuel, and significantly depends on their viscosity. For the evaluation of thermal properties of peat saturated with petroleum products, experimental studies have been conducted on determination of moisture and ash content of as-fired fuel. It is shown that adsorbed oil increases the moisture and ash content of peat in comparison with the initial sample. Therefore, when intended for energy use, peat saturated with petroleum products is to be subjected to additional drying. Simulation of net calorific value has been performed based on the calorific values of peat and petroleum products with different ratios of petroleum product content in peat and for a saturated peat sample. The obtained results are compared with those of experiments conducted in a calorimetric bomb and recalculated for net calorific value. A satisfactory discrepancy is obtained, which amounts to about 12%. Options have been considered providing for combustion of saturated peat as fuel (burnt per se and combined with a solid fuel) and processing it to produce liquid, gaseous and solid fuels. Peat can be used to solve environmental problems of elimination of emergency spills of crude oil and petroleum products and as an additional resource in solving the problem of finding affordable energy.

Author(s):  

The prospects of using hydrogen as a motor fuel are noted. The problems that arise when converting a diesel engine to run on hydrogen are considered. The features of the organization of the working process of enginesrunning on hydrogen are analyzed. A method of supplying a hydrogenair mixture to a diesel engine is investigated. To supply hydrogen to the engine cylinders, it is proposed to use the Leader4M installation developed by TechnoHill Club LLC (Moscow). Experimental studies of a stationary diesel engine of the D245.12 S type with the supply of hydrogen at the inlet obtained at this installation are carried out. At the maximum power mode, the supply of hydrogen from this installation to the inlet of the diesel engine under study was 0.9 % by weight (taking into account the difference in the calorific value of oil diesel fuel and hydrogen). Such a supply of hydrogen in the specified mode made it possible to increase the fuel efficiency of the diesel engine and reduce the smoke content of exhaust gases, carbon monoxide and unburned hydrocarbon emissions. Keywords internal combustion engines; diesel engine; diesel fuel; hydrogen; hydrogenair mixture; fuel efficiency; exhaust gas toxicity indicators


1996 ◽  
Vol 79 (2) ◽  
pp. 508-519 ◽  
Author(s):  
William M Draper ◽  
Joginder S Dhaliwal ◽  
S Kusum Perera ◽  
Frank J Baumann

Abstract The American Petroleum Institute method for determination of diesel-range total petroleum hydrocarbon (TPH) by gas-liquid chromatography with flame ionization detection was modified to allow simultaneous determination of motor oil. Motor oil elutes as a broad hump of unresolved alkanes and can be distinguished readily from diesel fuel and other fuel oils by its profile. The boiling point ranges for No. 2 diesel fuel and motor oil are C10– C21 and C21–C38, respectively, and these ranges define TPHs in diesel fuel (TPH-D) and motor oil (TPH- M). By this convention, less than 6% of No. 2 diesel is characterized as TPH-M, and less than 9% of motor oil is quantitated as TPH-D. Inlet discrimination was observed when motor oil was injected with a splitless injector. Accurate motor oil quantitation with splitless sample introduction requires calibration with the product or triacontane, which has a similar response factor. Detector response to motor oil (and other petroleum products) and a homologous series of n-alkanes was nearly constant when on-column injection was used. Instrument detection limit for motor oil was about 0.5 μg (split- less injection, total area under the curve), and the widest linear range (up to 100 μg) was obtained by subtracting the solvent chromatogram. Procedures for isolation of motor oil from oil-in-water (O/W) and water-in-oil (W/0) emulsions are described. Method detection limits for diesel fuel and motor oil in purified water were 0.041 and 1.5 mg/L, respectively.


2018 ◽  
Vol 40 (2) ◽  
pp. 33-40
Author(s):  
O.I. Sigal ◽  
L.I. Vorobiov ◽  
N.Y. Pavliuk ◽  
R.V. Serhiienko

The results of experimental studies of humidity, ash content, calorific value for сomponents of municipal solid waste in Cherkassy city are presented. The results of the research are used to develop an integrated waste management and recycling system in the Cherkassy city.  The waste management strategy has been adopted in Ukraine. It determines the main directions of reforming the system of sanitary cleaning of cities in order to minimize environmental pollution in accordance with EU standards. In the process of preparation of the regional implementation plan for the Strategy in Cherkassy, a study of the morphology, energy and environmental characteristics of the components of solid domestic waste (SDW) was made. This article presents the results of experimental studies of humidity, calorific value and ash content for 8 components of waste: paper, cardboard, composite materials, textiles, hygiene products, plastic, other combustible materials, wood shavings are presented. Humidity is also determined in organic residues and in fine fractions. The investigations were carried out at the experimental stand of the Institute of Technical Thermophysics of the National Academy of Sciences of Ukraine. Due to the absence in Ukraine of standards for the study of energy characteristics of solid waste, the measurements were carried out in accordance with standards for solid organic fuels, which slightly differ from the EU methods for the study of solid waste. In order to develop regional integrated waste management plans within the framework of the strategy implementation, based on the qualitative analysis of MSW components, it is necessary to develop standards for determining the energy characteristics of SDW in line with European normative documents. The study of the energy characteristics of solid waste showed a significant heterogeneity in the components of solid waste, which significantly complicated the determination of characteristics and led to a considerable scatter of results and an increase in measurement uncertainty. This happened due to low weight and the need for thorough homogenization of the sample, which was experimentally investigated in accordance with the method of preparation of an analytical sample. The article analyzes need for adaptation of the European methods of detailed morphology of solid domestic waste in Ukraine, which is necessary for separate waste collection. The results of the research are used to develop an integrated waste management and recycling system in the city of Cherkassy.


Fuel ◽  
2021 ◽  
pp. 122527
Author(s):  
Ellisson H. de Paulo ◽  
Francine D. dos Santos ◽  
Gabriely S. Folli ◽  
Layla P. Santos ◽  
Márcia H.C. Nascimento ◽  
...  

2009 ◽  
Vol 23 (9) ◽  
pp. 4515-4521 ◽  
Author(s):  
Estrella Rogel ◽  
Cesar Ovalles ◽  
Michael E. Moir ◽  
John F. Schabron

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 973
Author(s):  
Marta Bożym ◽  
Arkadiusz Gendek ◽  
Grzegorz Siemiątkowski ◽  
Monika Aniszewska ◽  
Jan Malaťák

This paper presents the results of the analysis of the chemical composition and content of heavy metal contamination in forest logging residues, in order to assess the possibility for their further utilisation. The samples were divided into 9 groups, which included coniferous tree cones, wood, and other multi-species logging residues. The elementary composition, ash content, and calorific value were determined as energy use indicators for the samples. Additionally, the content of heavy and alkali metals, which may affect combustion processes and pollutant emissions, was tested. The high content of heavy metals may also disqualify these residues for other uses. The research shows that the test residues are suitable for energy use due to their high calorific value and low content of heavy metals. However, an increased ash content in some samples and the presence of alkali metals, causing high-temperature corrosion of boilers, may disqualify them as a potential fuel in the combustion process. The forest residues may be used in other thermal processes such as pyrolysis or gasification. A low content of heavy metals and a high content of organic matter permit the use of these residues for the production of adsorbents or composite materials.


Author(s):  
Giovanni Lengkey

The purpose of this study is calculating the total energy needed during the rice drying process by using a vertical dryer VRD60 type in Bigo Selatan Village, Kaidipang Subdistrict, North Bolaang Mongondow District, and determining the efficiency of energy use during the rice drying process.  The tools used were: AGRINDO dryer VRD60 type, Danoplus infrared thermometer THE-223, Sima brand weighing scale with the capacity of 500 kg, and CROWN digital grain moisture meter. Materials used were: 5,202 kg (5.2 tons) of Sultan rice variety, diesel fuel, and rice husks. The study was conducted with experimental and survey methods. Data was analyzed descriptively. The results showed  that the total energy used by the dryer is 1,531,560 kcal consist of 6,300 kcal labor (humans) energy, 683,760 kcal  of diesel fuel and 841,500 kcal of energy from husk usage. The biggest energy is obtained from the husk used as much as 255 kg with a calorific value of 841,500 kcal and the biggest use is to evaporate water from materials that is 450,293.1 kcal. The energy efficiency of drying from a vertical dryer VRD60 type is found to be 38.29%.


2021 ◽  
Vol 627 (5) ◽  
pp. 28-31
Author(s):  
D .S. Kopitsyn ◽  
◽  
P. A. Gushchin ◽  
A. A. Panchenko ◽  
F. V. Timofeev ◽  
...  

In this work, we studied the processes of evaporation of gasoline and diesel fuel during their storage. We assessed of the temperature dependence of the content of hydrocarbon vapors in the gas phase over petroleum products. It was found that the experimental data are best described by the empirical equation based on the Antoine equation. An algorithm is proposed for calculating the natural loss of gasoline and diesel fuel, as well as approaches to its reduction.


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