scholarly journals HIGH-DENSITY POLYETHYLENE-BASED COMPOSITES WITH PRESSURE-TREATED WOOD FIBERS

BioResources ◽  
2012 ◽  
Vol 7 (4) ◽  
Author(s):  
Lu Shang ◽  
Guangping Han ◽  
Fangzheng Zhu ◽  
Jiansheng Ding ◽  
Todd Shupe ◽  
...  
Holzforschung ◽  
2016 ◽  
Vol 70 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Manuel R. Pelaez-Samaniego ◽  
Vikram Yadama ◽  
Manuel Garcia-Perez ◽  
Eini Lowell ◽  
Rui Zhu ◽  
...  

AbstractHot water extraction (HWE) partially removes hemicelluloses from wood while leaving the majority of the lignin and cellulose; however, the lignin partially migrates to the inner surfaces of the cell wall where it can be deposited as a layer that is sometimes visible as droplets. This lignin-rich material was isolated via Soxhlet extraction with dichloromethane to investigate its rheological behavior in blends with high-density polyethylene (HDPE), a common material in wood plastic composites (WPCs). Pyrolysis gas-chromatography/mass spectrometry (Py-GC/MS) and electrospray ion mass spectrometry (ESI/MS) confirmed that the isolated material is constituted mainly of low-molecular-weight lignin oligomers. The blends of HDPE/isolated lignin, in varying ratios, were tested by means of dynamic rheology. A “shoulder” was found in plots “shear storage moduli (G′) vs. frequency sweep” and a shift of the terminal zone to lower frequencies was observed. Apparently, this shoulder is caused by the elastic contribution of the interfacial tension between the blend components. The rheology of WPCs produced from HWE wood and HDPE shows a similar shoulder in G′ plots, suggesting that the HDPE/lignin blends are in part responsible for the shape of the G′ curves.


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1459
Author(s):  
Agbelenko Koffi ◽  
Fayçal Mijiyawa ◽  
Demagna Koffi ◽  
Fouad Erchiqui ◽  
Lotfi Toubal

Wood–plastic composites have emerged and represent an alternative to conventional composites reinforced with synthetic carbon fiber or glass fiber–polymer. A wide variety of wood fibers are used in WPCs including birch fiber. Birch is a common hardwood tree that grows in cool areas such as the province of Quebec, Canada. The effect of the filler proportion on the mechanical properties, wettability, and thermal degradation of high-density polyethylene/birch fiber composite was studied. High-density polyethylene, birch fiber and maleic anhydride polyethylene as coupling agent were mixed and pressed to obtain test specimens. Tensile and flexural tests, scanning electron microscopy, dynamic mechanical analysis, differential scanning calorimetry, thermogravimetry analysis and surface energy measurement were carried out. The tensile elastic modulus increased by 210% as the fiber content reached 50% by weight while the flexural modulus increased by 236%. The water droplet contact angle always exceeded 90°, meaning that the material remained hydrophobic. The thermal decomposition mass loss increased proportional with the percentage of fiber, which degraded at a lower temperature than the HDPE did. Both the storage modulus and the loss modulus increased with the proportion of fiber. Based on differential scanning calorimetry, neither the fiber proportion nor the coupling agent proportion affected the material melting temperature.


2017 ◽  
Vol 51 (30) ◽  
pp. 4205-4218 ◽  
Author(s):  
Kadir Karakuş ◽  
Deniz Aydemir ◽  
Ahmet Öztel ◽  
Gokhan Gunduz ◽  
Fatih Mengeloglu

The aim of this study is to investigate the effects of nanoboron nitride on the physical, mechanical, morphological and thermal properties of heat-treated wood high-density polyethylene composites. Three different multicriteria decision-making models such as the technique for order preference by similarity to ideal solutions, multi-attribute utility theory and compromise programming were used to predict the nanocomposites having optimum properties. High-density polyethylene as a matrix, heat-treated wood (30%) as a reinforcement filler and nanoboron nitride (0.5%, 1% and 2%) for improving the thermal stability were used; the composites prepared were grounded in a single-screw extruder, and the test samples were prepared with injection molding. According to the results, both testing and multicriteria decision-making models showed that heat-treated wood polymer nanocomposites with 2% nanoboron nitride have the optimum properties. Multicriteria decision-making methods are thought to be useful tools for materials having the optimal properties. It can be said that this study will be a guide for future material selection studies.


1990 ◽  
Vol 30 (11) ◽  
pp. 693-699 ◽  
Author(s):  
Kit L. Yam ◽  
Binoy K. Gogoi ◽  
Christopher C. Lai ◽  
Susan E. Selke

2020 ◽  
Vol 54 (25) ◽  
pp. 3717-3729 ◽  
Author(s):  
Behzad Kord ◽  
Farnaz Movahedi ◽  
Laleh Adlnasab ◽  
Hassan Masrouri

In this investigation, the effect of ionic liquids (ILs) pretreatment on the interfacial behavior, physical, and thermal properties of compression-molded composite boards produced from wood flour and high-density polyethylene was studied. Firstly, wood flour was pretreated with with two types of synthesized ILs, namely 1-(3-trimethoxysilylpropyl)-3-methylimidazolium chloride (IL-Cl) and 1-(3-trimethoxysilylpropyl)-3-methylimidazolium thiocyanate (IL-SCN). Thereafter, the interfacial strength, weight loss, water absorption, and thickness swelling of the specimens prepared from untreated and ILs-treated were evaluated. Further, the chemical treatment of wood flour with ILs was tracked by Fourier transform infrared spectroscopy. The morphological aspects of the specimens were characterized using Field Emission Scanning Electron Microscope (FESEM). Results demonstrated that the strong interaction between the wood flour and high-density polyethylene occurred in the presence of ILs pretreatment, which corresponded with the minimum amounts of adhesion factor. The tan δ peak was shifted to higher temperature for the modified samples than unmodified ones. It was noted that thermal stability of the composite boards improved as a result of ILs pretreatment. The residual weight in temperature of 600℃ was increased to 21.09% and 17.28% for the composite panels made from IL-SCN- and IL-Cl-treated wood, respectively, as compared to a residual mass of 16.35% for the composite based on untreated wood. Furthermore, physical testing revealed that the specimens produced from ILs-treated wood exhibited superior water resistance and dimensional stability compared to that of untreated ones.


2021 ◽  
Vol 72 (3) ◽  
pp. 219-229
Author(s):  
Kadir Karakuş ◽  
Deniz Aydemir ◽  
Gokhan Gunduz ◽  
Fatih Mengeloğlu

This study investigated the effect of untreated and heat-treated ash and black pine wood flour concentrations on the selected properties of high density polyethylene (HDPE) composites. HDPE and wood flour were used as thermoplastic matrix and filler, respectively. The blends of HDPE and wood fl our were compounded using single screw extruder and test samples were prepared through injection molding. Mechanical properties like tensile strength (TS), tensile modulus (TM), elongation at break (EatB), fl exural strength (FS), fl exural modulus (FM) and impact strength (IS) of manufactured composites were determined. Wood fl our concentrations have significantly increased density, FS, TM and FM and hardness of composites while reducing TS, EatB and IS. Heat-treated ash and black pine fl our reinforced HDPE composites had higher mechanical properties than untreated ones. Composites showed two main decomposition peaks; one coming from ash wood flour (353-370 °C) and black pine wood fl our (373-376 °C), the second one from HDPE degradation (469-490 °C). SEM images showed improved dispersion of heat-treated ash and black pine wood flour. The obtained results showed that both the untreated and heat-treated ash/black pine wood flour have an important potential in the manufacture of HDPE composites.


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