Reconstruction of depositional environments in time, organic matter enrichment and thermal maturity of the lower Palaeozoic mudstones in the Lithuanian part of the Baltic Basin

2021 ◽  
Author(s):  
◽  
Anna Katarzyna Cichon-Pupienis
2018 ◽  
Vol 6 (3) ◽  
pp. SH117-SH132 ◽  
Author(s):  
Krzysztof Sowiżdżał ◽  
Tomasz Słoczyński ◽  
Marek Stadtműller ◽  
Weronika Kaczmarczyk

We have developed a Lower Palaeozoic petroleum systems analysis in the selected zones of the Polish section of the Baltic Basin (onshore and offshore), which we carried out to assess the potential of shale rock formations as unconventional reservoirs. The areas of the Baltic Basin, which we analyzed represent a diversity of shale formations burial depths and thus different advancement of sediments compaction and organic matter transformation. Methods of dynamic petroleum systems modeling were applied with a 3D modeling workflow (PetroMod suite software). We considered an extensive array of data, including results of geochemical and petrophysical laboratory measurements, geophysical borehole data and, in selected locations — 3D seismic data. Five potentially perspective shale rock intervals (Silurian [2], Ordovician [2], and Upper Cambrian [1]) are identified and interpreted in terms of their geochemical and petrophysical properties. We calibrated the petroleum system models in terms of proper reproduction of diagenetic processes (pore pressure and porosity), thermal conditions (vitrinite reflectance, temperature), and kerogen kinetic model (organic matter transformation ratio, types of hydrocarbons generated). The results of the petroleum system simulations reveal that for the predominant part of the analyzed area, the achieved level of kerogen thermal maturity determines the generation of liquid hydrocarbons, which results in the present-day saturation of shale formations mainly with crude oil. We concluded that the highest generation yields as well as present-day hydrocarbons in place are observed for Ordovician Sasino Formation (onshore and offshore), Silurian/Llandovery Jantar member (onshore), and Upper Cambrian (alum shales) formation. Furthermore, a significant variation in the mass/volumes of accumulated hydrocarbons is observed within each of the shale formations being considered.


2017 ◽  
Vol 5 (2) ◽  
pp. SF225-SF242 ◽  
Author(s):  
Xun Sun ◽  
Quansheng Liang ◽  
Chengfu Jiang ◽  
Daniel Enriquez ◽  
Tongwei Zhang ◽  
...  

Source-rock samples from the Upper Triassic Yanchang Formation in the Ordos Basin of China were geochemically characterized to determine variations in depositional environments, organic-matter (OM) source, and thermal maturity. Total organic carbon (TOC) content varies from 4 wt% to 10 wt% in the Chang 7, Chang 8, and Chang 9 members — the three OM-rich shale intervals. The Chang 7 has the highest TOC and hydrogen index values, and it is considered the best source rock in the formation. Geochemical evidence indicates that the main sources of OM in the Yanchang Formation are freshwater lacustrine phytoplanktons, aquatic macrophytes, aquatic organisms, and land plants deposited under a weakly reducing to suboxic depositional environment. The elevated [Formula: see text] sterane concentration and depleted [Formula: see text] values of OM in the middle of the Chang 7 may indicate the presence of freshwater cyanobacteria blooms that corresponds to a period of maximum lake expansion. The OM deposited in deeper parts of the lake is dominated by oil-prone type I or type II kerogen or a mixture of both. The OM deposited in shallower settings is characterized by increased terrestrial input with a mixture of types II and III kerogen. These source rocks are in the oil window, with maturity increasing with burial depth. The measured solid-bitumen reflectance and calculated vitrinite reflectance from the temperature at maximum release of hydrocarbons occurs during Rock-Eval pyrolysis ([Formula: see text]) and the methylphenanthrene index (MPI-1) chemical maturity parameters range from 0.8 to [Formula: see text]. Because the thermal labilities of OM are associated with the kerogen type, the required thermal stress for oil generation from types I and II mixed kerogen has a higher and narrower range of temperature for hydrocarbon generation than that of OM dominated by type II kerogen or types II and III mixed kerogen deposited in the prodelta and delta front.


Clay Minerals ◽  
2009 ◽  
Vol 44 (3) ◽  
pp. 361-387 ◽  
Author(s):  
J. Środoń ◽  
N. Clauer ◽  
W. Huff ◽  
T. Dudek ◽  
M. Banaś

AbstractMixed-layer illite-smectite samples from the Ordovician and Silurian K-bentonites of the Baltic Basin and the Baltic Shield (Norway, Sweden, Denmark, Poland and Estonia) were dated by K-Ar on several grain fractions and were studied by X-ray diffraction (XRD), both on oriented and random preparations, in order to reveal the conditions of smectite illitization in the area. Authigenic K-feldspar was also dated. The geographic pattern of the degree of illitization (% smectite in illite-smectite measured by XRD) is consistent with other indicators of palaeotemperatures (acritarchs, conodont alteration index, vitrinite reflectance, apatite fission track ages). It reveals the highest maximum palaeotemperatures (up to at least 200ºC) along the Norwegian and the German-Polish branches of the Caledonides and the lowest palaeotemperatures (120ºC) in the central part of the studied area. The distribution of K-Ar ages is not well correlated with this pattern, revealing a zone of older ages (Lower Devonian-Lower Carboniferous) between Denmark and Estonia, and areas of younger ages (Upper Devonian to Carboniferous/Permian boundary) to the north and south of this zone. The zone of older ages is interpreted as the result of illitization induced by a thermal event in front of the Caledonian orogenic belt (migration of hot metamorphic fluids?). The areas of younger ages are considered as representing deep burial illitization under a thick Silurian-Carboniferous sedimentary cover, perhaps augmented by a tectonic load. The K-Ar dates invalidate the hypothesis of a long-lasting low-temperature illitization as the mechanism of formation of the Estonian Palaeozoic illite-smectite. The ammonium content of illite-smectite from the Baltic K-bentonites reflects the proximity of organic-rich source rocks that underwent thermal alteration at the time of illite crystallization.


2020 ◽  
Vol 4 (1) ◽  
pp. 1-13
Author(s):  
Aboglila S

Drill cutting samples (n = 92) from the Devonian Awaynat Wanin Formation and Silurian Tanezzuft Formation, sampled from three wells F1, G1 and H1, locate in the northern edge of the Murzuq basin (approximately 700 kilometers south of Tripoli). The studied samples were analyzed in the objective of their organic geochemical assessment such as the type of organic matter, depositional conditions and thermal maturity level. A bulk geochemical parameters and precise biomarkers were estimated, using chromatography-mass spectrometry (GC-MS) to reveal a diversity of their geochemical characterizations. The rock formations are having varied organic matter contents, ranged from fair to excellent. The total organic carbon (TOC) reached about 9.1 wt%, ranging from 0.6 to 2.93 wt% (Awaynat Wanin), 0.5 to 2.54 wt% (Tanezzuft) and 0.52 to 9.1 wt% (Hot Shale). The cutting samples are ranged oil-prone organic matter (OM) of hydrogen index (HI) ranged between 98 –396 mg HC/g TOC, related kerogen types are type II and II/III, with oxygen index (OI): 6 - 190 with one sample have value of 366 mg CO2/g. Thermal maturity of these source rocks is different, ranging from immature to mature and oil window in the most of Tanezzuft Formation and Hot Shale samples, as reflected from the production index data (PI: 0.08 - 034). Tmax and vitrinite reflectance Ro% data (Tmax: 435 – 454 & Ro%: 0.46 - 1.38) for the Awaynat Wanin. Biomarker ratios of specific hydrocarbons extracted from represented samples (n = 9), were moreover used to study thermal maturity level and depositional environments. Pristine/Phytane (Pr/Ph) ratios of 1.65 - 2.23 indicated anoxic to suboxic conditions of depositional marine shale and lacustrine source rock.


2021 ◽  
Vol 54 (1C) ◽  
pp. 87-100
Author(s):  
Arwa Al-Dolaimy

Eight cuttings samples were obtained from Sargelu and Kurrachine formations in different wells at different depths to detect steranes and triterpanes biomarkers as an indicator of the depositional environments and thermal maturity of organic matter. This was accomplished using GC-MS technology. The diasterane/sterane ratio showed low ratios in analyzed samples (BJS2, JKS3, BJK1, JKK4, JKK7) as in most marine carbonate sources, while algal-bacterial organic matter contribution for the samples analyzed based on the predominance of C23 tricyclic relative to the C19 tricyclic terpene and the C23 tricyclic greater than C24 tricyclic terpane. The Gammacerane index indicated that normal salinity conditions during depositions. The biomarkers related to maturation such as diasterane/sterane, Ts/(Ts+Tm), and C29Ts/C29 hopane show that the organic matter in Ain Zalah well (Sargelu Formation) is within early mature (oil window).


2019 ◽  
Vol 7 (4) ◽  
pp. SK45-SK52 ◽  
Author(s):  
Colin MacRitchie ◽  
Mohamed K. Zobaa

Horizontal drilling and multistage fracturing designs have recently made the Wolfcamp shale horizons a highly sought-after and low-cost oil opportunity at a time of market volatility. One current challenge is that the Wolfcamp shale horizons are unpredictable, especially in acreages with limited well control and seismic data. Sedimentary organic matter (palynofacies) analysis can delineate thermal maturity windows, determine kerogen types, and reflect depositional environments to aid in realizing hydrocarbon potential. We palynologically processed 16 samples at roughly 3 m intervals from the upper Wolfcamp section of the Collier-1201 well in Reeves County, Texas. We examined the prepared microscope slides in transmitted light to quantify (point count) and describe the organic facies in each sample. Additionally, we integrated organic geochemical data to corroborate palynofacies analysis. We classified most of the observed organic matter particles as highly degraded phytoclasts with unidentifiable terrestrial palynomorphs. The palynofacies and organic geochemical data indicate a mixed type-II/III kerogen (oil- and gas-prone materials) characterized by substantial terrigenous input. All samples displayed a high degree of thermal maturity from immense overburden as the Delaware Basin subsided and the overlying beds compacted. The lithologic and organic facies of the studied interval reflect fluctuating proximal marine conditions.


Author(s):  
Henrik I. Petersen ◽  
Jan Andsbjerg ◽  
Jørgen A. Bojesen-Koefoed ◽  
Hans P. Nytoft ◽  
Per Rosenberg

NOTE: This monograph was published in a former series of GEUS Bulletin. Please use the original series name when citing this monograph. For example: Petersen, H. I., Andsbjerg, J., Bojesen-Koefoed, J. A., Nytoft, H. P., & Rosenberg, P. (1998). Petroleum potential and depositional environments of Middle Jurassic coals and non-marine deposits, Danish Central Graben, with special reference to the Søgne Basin. Geology of Denmark Survey Bulletin, 36, 1-80. https://doi.org/10.34194/dgub.v36.5022 _______________ New data from five wells in the Søgne Basin, Danish Central Graben of the North Sea - West Lulu-1, West Lulu-3, Lulu-1, Amalie-1 and Cleo-1 - together with previously released data from the West Lulu-2 well, show that the cumulative thickness of the Bryne Formation coal seams decreases towards the palaeo-shoreline from 5.05 m to 0.60 m, and that the seams have varying extents. Their overall organic petrographic and geochemical composition reflects the palaeoenvironmental conditions in the precursor mires, in particular the rate of rise in the water table, principally related to the relative rise in sea level, and the degree of marine influence. Laterally towards the palaeo-shoreline, all coal seams have increased proportions of C27 steranes and higher C35-homohopane indices suggesting stronger marine influence on the coastal reaches of the ancient mires. In each well it is also observed that coal seams formed during accelerated relative sea-level rise (T-seams) are characterised by higher contents of sterane C27 and higher C35-homohopane indices than seams formed during slower rates of base-level rise (R-seams). The most landward and freshwater-influenced parts of the seams have higher proportions of sterane C29 and the highest Pr/Ph ratios. The coals, with respect to thermal maturity, are well within the oil window, except in the Amalie-1 well where they are more mature. The largest average hydrogen indices and thermally extracted and generated bitumen yields are obtained from the T-seams. However, generally an increase in the hydrogen index is recorded in a seaward direction for all seams. Multivariate regression analysis demonstrates that collotelinite, telinite, the vitrinite maceral group, vitrinite-rich microlithotypes and the TOC content have a significant positive influence on the remaining generative potential represented by S2. Pyrolysis-gas chromatography reveals that during maturation the coals will generate from 72.4 to 82.0% oil-like components and only 18.0 to 27.6% gas. However, this does not necessarily imply that all of these oil-like components can be expelled to form a crude oil accumulation. Distribution of C27–29 regular steranes shows good correlation between extracts of Bryne Formation coals and oils/condensates present in Bryne Formation sandstones. The sum of evidence indicates that the coals in the Søgne Basin have generated and are still capable of generating liquid and gaseous petroleum, but with respect to petroleum generation potential, they are not as good as the documented oil-prone Middle Jurassic coals from North-East Greenland and Tertiary coals from Asia. Mudstones intercalated with the Bryne Formation coals have a similar or lower generative potential as the coals. In areas outside the Søgne Basin, the coastal plain deposits of the Central Graben Group contain predominantly terrestrial-derived kerogen type III or IIb. The thermal maturity of the organic matter ranges from close to or within the peak oil generation range in the oil window (Alma-1x, Anne-3a and M-8 well) to the late oil window (Elly-3 and Falk-1 wells) or close to the end of the oil window (Skjold Flank-1 well). Only a limited generative potential remains in Elly-3, but the kerogen may initially have possessed a good petroleum potential. In the Falk-1 well, a good generative capacity still remains. The kerogen in Skjold Flank-1 may possess the capability to generate condensate and gas, whereas the organic matter in the Alma-1x, Anne-3a and M-8 wells generally exhibits a poor petroleum generative potential.  


Sign in / Sign up

Export Citation Format

Share Document