Three-dimensionally ordered macroporous TiO2 electrodes: Fabrication of inverse TiO2 opals for pore-size-dependent characterization

A procedure is described for the quantitative transfer of fibers and particulates collected on membrane filters to electron microscope (EM) grids. Various Millipore MF filters (Millipore AA, HA, GS, and VM; 0.8, 0.45, 0.22 and 0.05 μm mean pore size) have been used with success. Observed particle losses have not been size dependent and have not exceeded 10%. With fibers (glass or asbestos) as the collected media this observed loss is approximately 3%.

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Diverting the phase transition behaviour of adipic acid via mesoporous silica confinement

RSC Advances ◽

10.1039/c6ra23498d ◽

2016 ◽

Vol 6 (113) ◽

pp. 111787-111796 ◽

Cited By ~ 14

Author(s):

Shang Liu ◽

Guixiang Ma ◽

Shaolei Xie ◽

Yongzhong Jia ◽

Jinhe Sun ◽

...

Keyword(s):

Phase Transition ◽

Mesoporous Silica ◽

Pore Size ◽

Thermal Behaviour ◽

Adipic Acid ◽

Size Dependent ◽

Transition Behaviour

Phase transition regulation was achieved by imbibing adipic acid into mesoporous silica chambers, on the basis of pore size-dependent thermal behaviour.

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Effects of pore size on the mechanical properties of three-dimensionally ordered macroporous nickel

Materials & Design (1980-2015) ◽

10.1016/j.matdes.2012.09.009 ◽

2013 ◽

Vol 45 ◽

pp. 52-55 ◽

Cited By ~ 12

Author(s):

Zhenyu Li ◽

Lili Yang ◽

Yang Li ◽

Yongning Yang ◽

Changhai Zhou ◽

...

Keyword(s):

Mechanical Properties ◽

Pore Size ◽

Ordered Macroporous

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Additive Manufacturing and size-dependent mechanical properties of three-dimensional microarchitected, high-temperature ceramic metamaterials

Journal of Materials Research ◽

10.1557/jmr.2018.11 ◽

2018 ◽

Vol 33 (3) ◽

pp. 360-371 ◽

Cited By ~ 28

Author(s):

Huachen Cui ◽

Ryan Hensleigh ◽

Hongshun Chen ◽

Xiaoyu Zheng

Keyword(s):

Mechanical Properties ◽

High Temperature ◽

Additive Manufacturing ◽

Three Dimensional ◽

Size Dependent ◽

Image Position

Abstract

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Pore Size-Dependent Structure of Confined Water in Mesoporous Silica Films from Water Adsorption/Desorption Using ATR–FTIR Spectroscopy

Langmuir ◽

10.1021/acs.langmuir.9b01435 ◽

2019 ◽

Vol 35 (37) ◽

pp. 11986-11994 ◽

Cited By ~ 7

Author(s):

Bettina Baumgartner ◽

Jakob Hayden ◽

Jérôme Loizillon ◽

Sophia Steinbacher ◽

David Grosso ◽

...

Keyword(s):

Mesoporous Silica ◽

Ftir Spectroscopy ◽

Pore Size ◽

Water Adsorption ◽

Confined Water ◽

Silica Films ◽

Size Dependent ◽

Adsorption Desorption

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Preparation of Three-dimensionally ordered Macroporous SiO2Membranes with Controllable Pore Size

Chemistry Letters ◽

10.1246/cl.2007.464 ◽

2007 ◽

Vol 36 (3) ◽

pp. 464-465 ◽

Cited By ~ 5

Author(s):

Kui Zhao ◽

Yiqun Fan ◽

Nanping Xu

Keyword(s):

Pore Size ◽

Ordered Macroporous

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On the concentration dependence of surface diffusion coefficients in capillary porous materials

Proceedings of the Royal Society of London. Series A: Mathematical and Physical Sciences ◽

10.1098/rspa.1991.0095 ◽

1991 ◽

Vol 434 (1891) ◽

pp. 317-340 ◽

Cited By ~ 6

Keyword(s):

Experimental Data ◽

Carbon Dioxide ◽

Pore Size ◽

Surface Diffusion ◽

Diffusion Coefficients ◽

Physical Adsorption ◽

Structural Heterogeneity ◽

Size Dependent ◽

Chemical Potentials ◽

Uniform Pore Size

The influence of structural heterogeneity, in the form of a non-uniform pore size distribution, on the isotherms and surface diffusion coefficients for monolayer physical adsorption is studied. A pore size dependent langmuirian isotherm is used along with consideration of equality of chemical potentials at the pore mouths at an intersection. The diffusion is modelled by a recently developed random walk formulation. It is found that the surface diffusion coefficients are strongly influenced by the heterogeneity and have a stronger increase with overall coverage than that predicted by the Darken equation. The results are found to match the experimental data of P. C. Carman and F. A. Raal on the diffusion of carbon dioxide in carbon black without the use of a fitting parameter.

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