The Role of Metal Ion Solubility in Leaching of Nuclear Waste Glasses

1981 ◽  
Vol 11 ◽  
Author(s):  
B. Grambow

The leachability of solid nuclear waste forms has been studied by many investigators to evaluate the short-term kinetics of elemental release or to determine the effects of leachant composition or other system parameters. Some general observations from these studies have included: incongruent leaching; formation of reaction layers that contain rare-earth, alkaline-earth, or transition metal elements; and apparent saturation of some elements in solution while others continue to be leached. Before these observations can be used to predict long-term performance of waste glasses under repository conditions, the mechanisms controlling the release of elements from the solid must be understood.

1992 ◽  
Vol 294 ◽  
Author(s):  
Rodney C. Ewing

ABSTRACTNatural materials may be used to advantage in the evaluation of the long-term performance of nuclear waste forms. Three case studies are presented: (I) radiation effects in ceramic waste forms; (II) corrosion products of U02 under oxic conditions; (III) corrosion rate of nuclear waste glasses. For each case, a natural phase which is structurally and chemically analogous to the waste form is identified and used to evaluate the long-term behavior of a nuclear waste form. Short-term experimental results are compared to the observations made of analogous natural phases. The three case studies illustrate that results may range between providing fundamental data needed for the long-term evaluation of a waste form to only providing qualitative data of limited use. Although in the most rigorous view the long-term behaviour of a phase cannot be predicted, the correspondence between short-term experimental results and observations made of natural phases provides confidence in the “predicted” behavior of the waste form. The strength of this approach rests with the degree to which a mechanistic understanding of the phenomenon is attained.


2021 ◽  
Vol 14 (12) ◽  
pp. 567
Author(s):  
Arindam Das

M&A performance is a multifaceted, compound construct with no overarching factor that captures all different dimensions. This paper examines the concept of acquisition performance and proposes a model that links firm-level factors and transaction parameters with firms’ short-term and long-term performance, extending to financial-, market- and innovation measures. Building on past empirical studies on the influence of various factors on M&A performance, a multi-dimensional structural equation model has been developed and it has been tested with a dataset on acquisitions in the Indian technology sector over a period of ten years. The results suggest that: (a) smaller acquirers with higher book value and leveraged firms demonstrate better long-term performance; (b) contrary to established understanding, short-term market returns are not influenced by deal parameters; (c) majority stake purchases show relatively lesser gains—suggesting the possible presence of post-acquisition integration issues and, (d) acquirers with high intangible assets continue to do well on innovation performance post-acquisition. By indicating situations and conditions under which an acquisition would potentially lead to a performance gain for the acquirer, these results provide significant insight to practitioners pursuing M&As for growth opportunities.


2019 ◽  
Vol 11 (5) ◽  
pp. 1491 ◽  
Author(s):  
Keling Wang ◽  
Yaqiong Miao ◽  
Ching-Hui Su ◽  
Ming-Hsiang Chen ◽  
Zhongjun Wu ◽  
...  

We examined whether corporate charitable giving (CCG) in China benefits corporate performance (CP) in terms of sales growth (SG), return on asset (ROA), return on equity (ROE), and Tobin’s Q (TQ), and revealed several findings. First, testing shows variation in the impact of CCG on CP. Whereas the ratio of corporate charitable giving (RCCG) to total sales revenue does not significantly enhance SG, ROA, and ROE, it is positively related to TQ. Second, the positive relationship between RCCG and TQ originates from non-state-owned firms (NSOFs) rather than state-owned firms (SOFs). Third, Chinese firms may use CCG as traditional philanthropy to enhance long-term performance instead of strategically using it to generate short-term performance. Lastly, an inverted U-shaped relationship exists between RCCG and TQ, especially for NSOFs.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Chien-Wei Huang ◽  
Tsung-Han Yang ◽  
Guan-Bo Lin

Potholes, one of the major types of distress on pavement surfaces, damage vehicles and are a safety hazard for the travelling public. In order to mitigate the effect of potholes, cold-mix asphalt (CMA) patching materials are commonly used for urgent repair of pavement surfaces before resurfacing can be undertaken. Therefore, the short-term (initial stability) and long-term (in-service durability) performance evaluation of CMA patching materials is necessary. This study conducted several curing conditions in the laboratory to investigate short-term, long-term, and moisture effects on pavement surfaces. Moreover, this study compared the Marshall stability of samples prepared under various compaction conditions. Marshall stability, Cantabro abrasion, and UK wheel tracking tests were conducted to evaluate the performance of CMA patching materials. The results indicated that the Marshall stability of dense-gradation (DG) CMA patching materials was higher than that of open-graded (OG) CMA patching materials and the Marshall stability of OG CMA patching materials was highly influenced by the coarse aggregate proportion. The DG and OG CMA patching materials exhibited comparable abrasion resistance, and the Cantabro abrasion ratio was highly correlated to the estimated asphalt film thickness for the OG CMA patching materials. A moisture indicator (MI) was proposed, and the effect of moisture damage on Marshall stability and Cantabro abrasion ratio was related to the proposed MI. The rutting resistance of the DG CMA patching materials was higher than that of the OG CMA patching materials, which is consistent with the Marshall stability result.


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