The effect of molybdenum trioxide inter-layer between indium tin oxide (ITO) and organic semiconductor on the energy level alignment

2009 ◽  
Vol 1212 ◽  
Author(s):  
Irfan Irfan ◽  
Huanjun Ding ◽  
Yongli Gao ◽  
Do Yang Kim ◽  
Jegadesan Subbiah ◽  
...  

AbstractWe investigated 0 to 300 Å thick stepped molybdenum trioxide (MoO3) inter-layer between in-situ oxygen plasma treated conducting indium tin oxide (ITO) and chloro-aluminum pthalocyanine (AlPc-Cl) layer-by-layer evaporated up to 228 Å, with ultra-violet photoemission spectroscopy (UPS) and inverse photoemission spectroscopy (IPES). The MoO3 inter-layers were observed to increase the surface workfunction. The workfunction increase was observed to saturate at 20 Å of MoO3 coverage. The increased surface workfunction causes hole accumulation and band bending in the subsequently deposited AlPc-Cl. A possible explanation of reduction in series resistance by the insertion of the MoO3 insulating layer is discussed based on these observations and energy level alignment.

2012 ◽  
Vol 111 (11) ◽  
pp. 114511 ◽  
Author(s):  
Junghwan Kim ◽  
Geunjin Kim ◽  
Youna Choi ◽  
Jongjin Lee ◽  
Sung Heum Park ◽  
...  

2018 ◽  
Vol 706 ◽  
pp. 317-322 ◽  
Author(s):  
Junkyeong Jeong ◽  
Jiyeon Lee ◽  
Hyunchan Lee ◽  
Gyeongho Hyun ◽  
Soohyung Park ◽  
...  

2010 ◽  
Vol 96 (7) ◽  
pp. 073304 ◽  
Author(s):  
Irfan ◽  
Huanjun Ding ◽  
Yongli Gao ◽  
Do Young Kim ◽  
Jegadesan Subbiah ◽  
...  

MRS Advances ◽  
2017 ◽  
Vol 2 (42) ◽  
pp. 2261-2266
Author(s):  
Kohei Shimizu ◽  
Hirohiko Fukagawa ◽  
Katsuyuki Morii ◽  
Hiroumi Kinjo ◽  
Tomoya Sato ◽  
...  

ABSTRACTA polyethyleneimine (PEI) interlayer has been applied on indium tin oxide (ITO) to improve electron injection in organic devices including inverted organic light-emitting diodes (OLEDs). To understand the improvement effect by PEI insertion, the energy level alignment at bis(10-hydroxybenzo[h]quinolinato)beryllium (Bebq2)/PEI/ITO interfaces was investigated by UV photoemission spectroscopy (UPS). The deposition of a PEI layer was found to reduce the absolute work function of ITO by 1.4 eV. The vacuum level shifts at Bebq2/ITO and Bebq2/PEI interfaces were also determined as 0.3 eV and 0.1 eV in the direction to reduce the electron injection barrier, respectively. Thus the work function reduction by PEI and downward vacuum level shift at the Bebq2/PEI interface can contribute to the improvement effect. Kelvin probe measurement revealed the weak orientation polarization in Bebq2 film with the bottom side positively polarized. This polarization polarity is also advantageous for electron injection in inverted devices.


2012 ◽  
Vol 101 (23) ◽  
pp. 233305 ◽  
Author(s):  
Younjoo Lee ◽  
Hyunbok Lee ◽  
Soohyung Park ◽  
Yeonjin Yi

2007 ◽  
Vol 102 (7) ◽  
pp. 073719 ◽  
Author(s):  
Karsten Fehse ◽  
Selina Olthof ◽  
Karsten Walzer ◽  
Karl Leo ◽  
Robert L. Johnson ◽  
...  

2004 ◽  
Vol 95 (11) ◽  
pp. 6273-6276 ◽  
Author(s):  
Jianqiao Hu ◽  
Jisheng Pan ◽  
Furong Zhu ◽  
Hao Gong

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