Photoconductivity of Highly Disordered Carbon Fibers

1990 ◽  
Vol 209 ◽  
Author(s):  
Kazuyoshii Kuriyama ◽  
Mildred.S. Dresselhauss

ABSTRACTA highly disordered carbon material, activated carbon fibers, is investigated through bulk conductivity and photoconductivity measurements. This material has a high density of defect states introduced by an aqtivation process that leads to a huge specific surface area of up to 2000m2/g. The conductivity increases by a factor of 4–10 with increasing temperaturefrom 30K to 290K. In contrast, the photoconductivity decreases by a factor of three with increasing temperature. The relaxation time of the photoconductivity is rather long(on the order 10−1 sec), indicating that the recombination process proceeds through localized states. flopping processes are used to interpret the transport properties of this material.

1991 ◽  
Vol 6 (5) ◽  
pp. 1040-1047 ◽  
Author(s):  
K. Kuriyama ◽  
M.S. Dresselhaus

The conductivity and photoconductivity are measured on a high-surface-area disordered carbon material, i.e., activated carbon fibers, to investigate their electronic properties. This material is a highly disordered carbon derived from a phenolic precursor, having a huge specific surface area of 1000–2000 m2/g. Our preliminary thermopower measurements show that the dominant carriers are holes at room temperature. The x-ray diffraction pattern reveals that the microstructure is amorphous-like with Lc ≃ 10 Å. The intrinsic electrical conductivity, on the order of 20 S/cm at room temperature, increases by a factor of several with increasing temperature in the range 30–290 K. In contrast, the photoconductivity in vacuum decreases with increasing temperature. The magnitude of the photoconductive signal was reduced by a factor of ten when the sample was exposed to air. The recombination kinetics changes from a monomolecular process at room temperature to a bimolecular process at low temperatures, indicative of an increase in the photocarrier density at low temperatures. The high density of localized states, which limits the motion of carriers and results in a slow recombination process, is responsible for the observed photoconductivity.


1999 ◽  
Vol 11 (12) ◽  
pp. 3476-3483 ◽  
Author(s):  
Christian L. Mangun ◽  
Kelly R. Benak ◽  
Michael A. Daley ◽  
James Economy

1998 ◽  
Vol 5 (3-4) ◽  
pp. 261-266 ◽  
Author(s):  
M. Endo ◽  
T. Furuta ◽  
F. Minoura ◽  
C. Kim ◽  
K. Oshida ◽  
...  

2012 ◽  
Vol 184-185 ◽  
pp. 1110-1113 ◽  
Author(s):  
Li Fen He ◽  
Qi Xia Liu ◽  
Tao Ji ◽  
Qiang Gao

Various jute-based activated carbon fibers were prepared by using jute fibers as raw materials and phosphoric acid as activating agent. The effects of three main factors such as concentration of activating agent, activation temperature and activation time on the yield and adsorptive properties of active carbon fibers were investigated via orthogonal experiments. The surface physical morphology of jute-based activated carbon fiber was also observed by using Scanning Electron Microscope. Results showed that the optimum conditions were phosphoric acid concentration of 4 mol/L, activation temperature of 600 °C and activation time of 1h. The yield, iodine number and amount of methylene blue adsorption of the active carbon fiber prepared under optimum conditions were 37.99 %, 1208.87 mg/g and 374.65 mg/g, respectively.


Carbon ◽  
2004 ◽  
Vol 42 (10) ◽  
pp. 2113-2115 ◽  
Author(s):  
Soo-Jin Park ◽  
Sung-Yeol Jin

Carbon ◽  
2002 ◽  
Vol 40 (13) ◽  
pp. 2291-2300 ◽  
Author(s):  
Haiqin Rong ◽  
Zhenyu Ryu ◽  
Jingtang Zheng ◽  
Yuanli Zhang

2007 ◽  
Vol 611 (1-2) ◽  
pp. 225-231 ◽  
Author(s):  
Chun-Ling Liu ◽  
Wen-Sheng Dong ◽  
Gao-Ping Cao ◽  
Jing-Ren Song ◽  
Lang Liu ◽  
...  

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