Diffusion Barriers for Copper Metallization: Predicting Phase Stability and Reactivity using Equilibrium Thermodynamics
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AbstractThe guidelines for designing a conductive, amorphous material, capable of thermodynamic equilibrium with copper, are defined using readily available thermodynamic information. The tradeoff between desired properties – equilibrium at the interfaces, amorphous microstructure, and electronic conductivity – are described, along with trends in relevant binary systems that result in these properties. These guidelines defined systems for experimental study, for which preliminary results are presented.
2000 ◽
Vol 50
(1-4)
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pp. 357-368
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2014 ◽
Vol 41
(6)
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pp. 455-456
2013 ◽
Vol 740-742
◽
pp. 801-804
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