Epitaxial Growth of SiC in a Vertical Multi-Wafer CVD System: Already Suited as Production Process?

1999 ◽  
Vol 572 ◽  
Author(s):  
Roland Rupp ◽  
Christian Hecht ◽  
Arno Wiedenhofer ◽  
Dietrich Stephani

ABSTRACTResults about a new CVD system suited for epitaxial growth on six 2 inch SiC-wafers at a time are presented. Excellent gas flow stability is achieved for this new reactor type as shown by in- situ observations of the gas flow dynamics in the reactor chamber. These experimental results agree favorably with numerical process simulation results.The epitaxial layers grown in the multi-wafer system so far show a by an order of magnitude higher background impurity level (≤1015 cm−3) as reported previously for layers grown in single-wafer systems by the authors and other groups (≤ 1014 cm−3). On the other hand, the doping homogeneity achieved until today is very encouraging. The variation on a 2 inch wafer is less than ± 20% at about 1*1016 cm−3. The wafer to wafer variation of the average doping value both within a run and from run to run is within 15 %. The reproducibility and uniformity of the layer thickness is even better (total thickness variation ≤5% on a 2 inch wafer). The surface of the epitaxial layers is very smooth with a typical growth step height of 0.5 nm (4H, 8° off orientation). First measurements on Schottky diodes build on these layers show low leakage current values indicating low point defect density in the epitaxial layers.

2005 ◽  
Vol 483-485 ◽  
pp. 429-432 ◽  
Author(s):  
Francesco La Via ◽  
Fabrizio Roccaforte ◽  
Salvatore di Franco ◽  
Alfonso Ruggiero ◽  
L. Neri ◽  
...  

The effects of the Si/H2 ratio on the growth of the epitaxial layer and on the epitaxial defects was studied in detail. A large increase of the growth rate has been observed with the increase of the silicon flux in the CVD reactor. Close to a Si/H2 ratio of 0.05 % silicon nucleation in the gas phase occurs producing a great amount of silicon particles that precipitate on the wafers. The epitaxial layers grown with a Si/H2 ratio of 0.03% show a low defect density and a low leakage current of the Schottky diodes realized on these wafers. For these diodes the DLTS spectra show thepresence of several peaks at 0.14, 0.75, 1.36 and 1.43 eV. For epitaxial layers grown with higher values of the Si/H2 ratio and then with an higher growth rate, the leakage current of the Schottky diodes increases considerably.


2008 ◽  
Vol 600-603 ◽  
pp. 317-320 ◽  
Author(s):  
Robert E. Stahlbush ◽  
Brenda L. VanMil ◽  
Kendrick X. Liu ◽  
Kok Keong Lew ◽  
Rachael L. Myers-Ward ◽  
...  

The evolution of basal plane dislocations (BPDs) in 4H-SiC epitaxy during its growth is investigated by using two types of interrupted growth in conjunction with ultraviolet photoluminescence (UVPL) imaging of the dislocations. For the first, each epitaxial growth was stopped after 10-20 μm and a UVPL map was collected. For the second, changing the gas flow interrupted the growth and the BPDs were imaged at the end. The first sequence made it possible to track the formation of half-loop arrays and show that they arise from BPDs that glide perpendicular to the offcut direction. For both types, each interruption causes between 30 – 50% of the BPDs to be converted to threading edge dislocations (TEDs). This result suggests that using interrupted growth may be an alternate method to producing epitaxial layers with low BPD concentration.


2008 ◽  
Vol 600-603 ◽  
pp. 991-994 ◽  
Author(s):  
Pierre Brosselard ◽  
Nicolas Camara ◽  
Jawad ul Hassan ◽  
Xavier Jordá ◽  
Peder Bergman ◽  
...  

An innovative process has been developed by Linköping University to prepare the 4HSiC substrate surface before epitaxial growth. The processed PiN diodes have been characterized in forward and reverse mode at different temperature. The larger diodes (2.56 mm2) have a very low leakage current around 20 nA @ 500V for temperatures up to 300°C. A performant yield (68%) was obtained on these larger diodes have a breakdown voltage superior to 500V. Electroluminescence characteristics have been done on these devices and they show that there is no generation of Stacking Faults during the bipolar conduction.


2009 ◽  
Vol 56 (4) ◽  
pp. 1827-1834 ◽  
Author(s):  
L. A. Kosyachenko ◽  
V. M. Sklyarchuk ◽  
O. F. Sklyarchuk ◽  
O. L. Maslyanchuk ◽  
V. A. Gnatyuk ◽  
...  

MRS Advances ◽  
2016 ◽  
Vol 1 (54) ◽  
pp. 3631-3636 ◽  
Author(s):  
Johji Nishio ◽  
Hirokuni Asamizu ◽  
Mitsuhiro Kushibe ◽  
Hidenori Kitai ◽  
Kazutoshi Kojima

ABSTRACT Reduction in background carrier concentration has been investigated for 4H-SiC C-face epitaxial growth in order to be applied for ultra-high voltage power devices. Optimizing epitaxial growth parameters made it possible to achieve 7.6x1013 cm-3 as the background carrier concentration within a whole area of specular 3-inch wafers. In addition to the background carrier concentration reduction, epitaxial film thickness variation, surface defect density and the carrier lifetime have been confirmed to fulfill the requirements for the devices.


2014 ◽  
Vol 778-780 ◽  
pp. 214-217 ◽  
Author(s):  
Kentaro Tamura ◽  
Chiaki Kudou ◽  
Keiko Masumoto ◽  
Johji Nishio ◽  
Kazutoshi Kojima

We have grown epitaxial layers on 2° off-cut 4H-SiC(0001) Si-face substrates. The epitaxial layer surfaces on 2° off-cut substrates are more prone to generate step-bunching than on 4° off-cut substrates, which are observed by confocal microscopy with differential interference contrast. We have speculated that the step-bunching is generated at the beginning of an epitaxial growth. Triangular defect density of epitaxial layers on 2° off-cut substrates is as low as 0.7 cm–2 for the size corresponding to 150 mm. We have firstly reported distribution of 2° off-cut epitaxial layers for the 150-mm size using two 76.2-mm wafers: σ/mean = 3.3% for thickness, σ/mean = 7.3% for carrier concentration.


2019 ◽  
Vol 954 ◽  
pp. 114-120
Author(s):  
Ying Xi Niu ◽  
Xiao Yan Tang ◽  
Li Xin Tian ◽  
Liu Zheng ◽  
Wen Ting Zhang ◽  
...  

70-um thick homoepitaxial layers with very low defect density were grown on 6-inch 4° off-axis wafers using hot-wall chemical vapor deposition (CVD). Process optimization resulted in reduction of the density of triangular defects from 1.01 cm-2 to 0.14 cm-2. The treatment of wafer (CMP or selection) was essential. The in-situ etch process was optimized prior to the epitaxial growth. Junction Barrier Schottky diodes fabricated on the epitaxial films presented a typical I–V characteristic and a block voltage of 6500 V.


2006 ◽  
Vol 527-529 ◽  
pp. 163-166 ◽  
Author(s):  
Francesco La Via ◽  
G. Galvagno ◽  
A. Firrincieli ◽  
Fabrizio Roccaforte ◽  
Salvatore di Franco ◽  
...  

The growth rate of 4H-SiC epi layers has been increased by a factor 3 (up to 18μm/h) with respect to the standard process with the introduction of HCl in the deposition chamber. The epitaxial layers grown with the addition of HCl have been characterized by electrical, optical and structural characterization methods. An optimized process without the addition of HCl is reported for comparison. The Schottky diodes, manufactured on the epitaxial layer grown with the addition of HCl at 1600 °C, have electrical characteristics comparable with the standard epitaxial process with the advantage of an epitaxial growth rate three times higher.


2009 ◽  
Vol 615-617 ◽  
pp. 55-60 ◽  
Author(s):  
Francesco La Via ◽  
Gaetano Izzo ◽  
Massimo Camarda ◽  
Giuseppe Abbondanza ◽  
Danilo Crippa

The growth rate of 4H-SiC epi layers has been increased up to 100 µm/h by chlorine addition. The epitaxial layers grown with this process have been characterized by electrical, optical and structural characterization methods. Very thick (> 100 µm) epitaxial layer has been grown and the Schottky diodes realized on these layers have good yield (> 87%) with a low defect density (10/cm2). This process gives the opportunity to realize very high power devices with breakdown voltages in the range of 10 kV or X-Ray and particle detectors with a low cost epitaxy process.


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