Are Gel-Derived Glasses Different from Ordinary Glasses?

1986 ◽  
Vol 73 ◽  
Author(s):  
M. C. Weinberg

ABSTRACTA review is presented of some of the previously reported differences and similarities between comparable gel glasses (and gels) and ordinary glasses. In this regard, considerations are made with respect to such factors as structure, physical and thermal properties, and phase transformation behavior. A variety of silicate lass compositions are used for illustrative purposes. The discussion is roughly ivided into two sections; low and high temperature behavior. At low temperatures one anticipates that differences between gel and conventional glasses will exist, but such dissimilarities are not expected to persist to high temperatures. However, experimental evidence is presented which indicates the perpetuation of such differences to very high temperatures. A partial resolution for this anomalous behavior is offered.

1999 ◽  
Vol 14 (3) ◽  
pp. 715-728 ◽  
Author(s):  
P. Zhao ◽  
D. G. Morris ◽  
M. A. Morris Munoz

High-temperature forging experiments have been carried out by axial compression testing on a Fe–41Al–2Cr alloy in order to determine the deformation systems operating under such high-speed, high-temperature conditions, and to examine the textures produced by such deformation and during subsequent annealing to recrystallize. Deformation is deduced to take place by the operation of 〈111〉 {110} and 〈111〉{112} slip systems at low temperatures and by 〈100〉{001} and 〈100〉{011} slip systems at high temperatures, with the formation of the expected strong 〈111〉 textures. The examination of the weak 〈100〉 texture component is critical to distinguishing the operating slip system. Both texture and dislocation analyses are consistent with the operation of these deformation systems. Recrystallization takes place extremely quickly at high temperatures (above 800 °C), that is within seconds after deformation and also dynamically during deformation itself. Recrystallization changes the texture such that 〈100〉 textures superimpose on the deformation texture. The flow stress peak observed during forging is found at a very high temperature. Possible origins of the peak are examined in terms of the operating slip systems.


1982 ◽  
Vol 75 (1) ◽  
pp. 53-55
Author(s):  
George Knill ◽  
George Fawceti

Everyone knows that wood bums at a very high temperature. This burning is a chemical process that combines oxygen and carbon. The process occurs at very low temperatures as well as at very high ones. At high temperatures the process is spectacular-fire. At low temperatures (room temperature) you won’t even notice it, although it is still going on. Wood is always burning.


2015 ◽  
Vol 833 ◽  
pp. 63-66
Author(s):  
Cui Ping Wang ◽  
Yu Ding Liu ◽  
Shui Yuan Yang ◽  
Xing Jun Liu

The microstructure and phase transformation behavior of Ni-Mn-Fe high-temperature shape memory alloys including Ni40+xFe10Mn50-x (x = 0, 10) were investigated. The results show that both two alloys exhibit single fcc γ phase annealed at 900°C for 1 day. When these quenched alloys are again annealed at 500°C for 20 days, they almost exhibit main tetragonal θ martensite. The microstructural evolutions are consistent with the results of phase transformation measurements. It is clearly found that there is an irreversible phase transformation around 480°C ~ 570°C, which is associated with the formation of tetragonal θ martensite from γ phase. Afterwards, the reversible martensitic transformation occurs during heating and cooling with very high transformation temperature.


2014 ◽  
Vol 1693 ◽  
Author(s):  
Dean P. Hamilton ◽  
Michael R. Jennings ◽  
Craig A. Fisher ◽  
Yogesh K. Sharma ◽  
Stephen J. York ◽  
...  

ABSTRACTSilicon carbide power devices are purported to be capable of operating at very high temperatures. Current commercially available SiC MOSFETs from a number of manufacturers have been evaluated to understand and quantify the aging processes and temperature dependencies that occur when operated up to 350°C. High temperature constant positive bias stress tests demonstrated a two times increase in threshold voltage from the original value for some device types, which was maintained indefinitely but could be corrected with a long negative gate bias. The threshold voltages were found to decrease close to zero and the on-state resistances increased quite linearly to approximately five or six times their room temperature values. Long term thermal aging of the dies appears to demonstrate possible degradation of the ohmic contacts. This appears as a rectifying response in the I-V curves at low drain-source bias. The high temperature capability of the latest generations of these devices has been proven independently; provided that threshold voltage management is implemented, the devices are capable of being operated and are free from the effects of thermal aging for at least 70 hours cumulative at 300°C.


1997 ◽  
Vol 172 (1-2) ◽  
pp. 93-102 ◽  
Author(s):  
Y. Tachibana ◽  
S. Shiozawa ◽  
J. Fukakura ◽  
F. Matsumoto ◽  
T. Araki

1892 ◽  
Vol 50 (302-307) ◽  
pp. 254-254

This investigation forms one of a series, former members of which refer to the thermal properties of ethyl oxide and various alcohols. Owing to the high temperature of the critical point of water, the work was confined to comparatively low temperatures.


2015 ◽  
Vol 833 ◽  
pp. 67-70
Author(s):  
Shui Yuan Yang ◽  
Cui Ping Wang ◽  
Yu Su ◽  
Xing Jun Liu

The evolutions of microstructure and phase transformation behavior of Cu-Al-Fe-Nb/Ta high-temperature shape memory alloys under the quenched and aged states were investigated in this study, including Cu-10wt.% Al-6wt.% Fe, Cu-10wt.% Al-4wt.% Fe-2wt.% Nb and Cu-10wt.% Al-4wt.% Fe-2wt.% Ta three types alloys. The obtained results show that after quenching, Cu-10wt.% Al-6wt.% Fe alloy exhibits two-phase microstructure of β′1 martensite + Fe (Al,Cu) phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy also has two-phase microstructure of (β′1 + γ′1 martensites) + Nb (Fe,Al,Cu)2 phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Ta alloy is consisted of three-phase of (β′1 + γ′1 martensites) + Fe (Al,Cu,Ta) + Ta2(Al,Cu,Fe)3 phases. However, α (Cu) phase precipitates after aging for three alloys; and Fe (Al,Cu,Nb) phase is also present in Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy. All the studied alloys exhibit complicated martensitic transformation behaviors resulted from the existence of two types martensites (β′1 and γ′1).


2006 ◽  
Vol 503-504 ◽  
pp. 1013-0 ◽  
Author(s):  
Chao Ying Xie ◽  
Z.G. Fan ◽  
Z.H. Li ◽  
G.Q. Xiang ◽  
X.H. Cheng

Microstructures and transformation behavior of TiNi shape memory alloy after high temperature ECAE process have been investigated. It is found that the initial coarse grains were refined after high temperature ECAE processes and short annealing at 750°C. Transformation temperatures of TiNi alloy sharply decreased after two ECAE processes, rose obviously when annealed at 750°C for 5min, and quickly rose back after annealing at 500°C for 2 hours. Reasons for phase transformation behavior changes have been discussed.


1970 ◽  
Vol 18 (2) ◽  
pp. 105-110
Author(s):  
A.A. Abdalla ◽  
K. Verkerk

The effects were assessed of CCC and GA on tomatoes grown either under a high temperature regime (35 degrees day and 25 degrees C. night) or at normal temperatures (22 degrees and 18 degrees ). CCC (0.4%) was applied to the soil in the pots either 2 days after transplanting or at the start of flowering; G A was applied by dipping the first truss in GA (50 p.p.m.). CCC greatly retarded the growth rate of the stems of the plants under both temperature regimes; this effect persisted for about 17 and 24 days under the high and normal temperature regimes, respectively. With plants grown at high temperatures CCC applied at the start of flowering greatly reduced flower shedding and slightly increased the fruit set and fruit development of hand-pollinated flowers. With plants grown at normal temperatures, however, the effects of CCC were slight. CCC-treated plants were sturdy with dark-green leaves which remained green longer, especially under the high temperature regime. More N accumulated in the tissues of plants grown at high temperatures than at normal temperatures, and the N content of the latter plants was considerably increased by CCC treatment. The root development of the CCC-treated plants was much more extensive than that of the untreated plants. The numbers of seeds in the hand-pollinated fruit were not affected by CCC, but at high temperatures there were considerably less seeds than at low temperatures. GA enhanced fruit set of the high-temperature plants, but the fruits were small and seedless. GA also accelerated fruit ripening by 2 and 3 weeks in the plants grown at high and normal temperatures, respectively.-Agric. Univ., Wageningen. (Abstract retrieved from CAB Abstracts by CABI’s permission)


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