scholarly journals Plant availability of trace elements in sewage sludge-treated soils: methodology¹

2011 ◽  
Vol 35 (4) ◽  
pp. 1453-1460 ◽  
Author(s):  
Giuliano Marchi ◽  
Luiz Roberto Guimarães Guilherme ◽  
Andrew C Chang
Keyword(s):  
Trace Elements ◽  
Sewage Sludge ◽  
Organic Acid ◽  
Root Exudates ◽  
Chemical Species ◽  
Soil Solutions ◽  
Rhizosphere Environment ◽  
Corn Plants ◽  
Chemical Conditions ◽  
Soluble Complexes

Synthetic root exudates were formulated based on the organic acid composition of root exudates derived from the rhizosphere of aseptically grown corn plants, pH of the rhizosphere, and the background chemical matrices of the soil solutions. The synthetic root exudates, which mimic the chemical conditions of the rhizosphere environment where soil-borne metals are dissolved and absorbed by plants, were used to extract metals from sewage-sludge treated soils 16 successive times. The concentrations of Zn, Cd, Ni, Cr, and Cu of the sludge-treated soil were 71.74, 0.21, 15.90, 58.12, and 37.44 mg kg-1, respectively. The composition of synthetic root exudates consisted of acetic, butyric, glutaric, lactic, maleic, propionic, pyruvic, succinic, tartaric, and valeric acids. The organic acid mixtures had concentrations of 0.05 and 0.1 mol L-1 -COOH. The trace elements removed by successive extractions may be considered representative for the availability of these metals to plants in these soils. The chemical speciation of the metals in the liquid phase was calculated; results showed that metals in sludge-treated soils were dissolved and formed soluble complexes with the different organic acid-based root exudates. The most reactive organic acid ligands were lactate, maleate, tartarate, and acetate. The inorganic ligands of chloride and sulfate played insignificant roles in metal dissolution. Except for Cd, free ions did not represent an important chemical species of the metals in the soil rhizosphere. As different metals formed soluble complexes with different ligands in the rhizosphere, no extractor, based on a single reagent would be able to recover all of the potentially plant-available metals from soils; the root exudate-derived organic acid mixtures tested in this study may be better suited to recover potentially plant-available metals from soils than the conventional extractors.

scholarly journals Sewage Sludge as a Tool in Limiting the Content of Trace Elements in Avena sativa L. on the Soil Polluted with Diesel Oil

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4003
Author(s):  
Mirosław Wyszkowski ◽  
Jadwiga Wyszkowska ◽  
Agata Borowik ◽  
Natalia Kordala
Keyword(s):  
Trace Elements ◽  
Sewage Sludge ◽  
Soil Contamination ◽  
Avena Sativa ◽  
Negative Impact ◽  
Diesel Oil ◽  
Average Content ◽  
Nickel Copper ◽  
Copper Manganese ◽  
Positive Effect

The aim of the research was to determine the effect of soil contamination with diesel oil (0; 5; 10 and 15 cm3 kg−1 of soil) on the content of trace elements in the aboveground parts of oat (Avena sativa L.). Stabilised sewage sludge was used to mitigate the likely negative impact of diesel oil on the plant. Growing soil contamination with diesel oil had a significant impact on the content of trace elements in the aboveground biomass of oat. In the series without sewage sludge, the contents of the analysed elements, except for chromium, zinc, copper and cobalt, were positively correlated with the increasing doses of diesel oil. The largest increase in the content was recorded in the case of manganese. The sewage sludge used to reduce the influence of diesel oil on the chemical composition of oat had a positive effect on the content of the analysed trace elements. Compared to the series without the addition of a stabilised sewage sludge, it contributed to a reduction in the average content of chromium, nickel, copper, manganese and cobalt in the aboveground parts of oat plants. No significant effect of the applied remediation treatment was noted for cadmium, and the results were equivocal for iron.

scholarly journals Root excretion and plant tolerance to cadmium toxicity - a review

2008 ◽  
Vol 53 (No. 5) ◽  
pp. 193-200 ◽  
Author(s):  
J. Dong ◽  
W.H. Mao ◽  
G.P. Zhang ◽  
F.B. Wu ◽  
Y. Cai
Keyword(s):  
Root Exudates ◽  
Anthropogenic Activities ◽  
Cadmium Toxicity ◽  
Research Work ◽  
Future Research ◽  
Rhizosphere Ph ◽  
Plant Tolerance ◽  
Rhizosphere Environment ◽  
Safe Food ◽  
Tolerance To Cadmium

Significant quantities of Cd have been added to soils globally due to various anthropogenic activities, posing a serious threat to safe food production and human health. Rhizosphere, as an important interface of soil and plant, plays a significant role in the agro-environmental system. This article presents a review of relationship between root excretion and microorganisms and plant resistance to Cd toxicity and possible mechanisms. Root exudates markedly altered in species and quantity under Cd stress. Root exudates can affect Cd absorption by plants through changing the physical and chemical characteristics of rhizospheres. The influence of root exudates on Cd bioavailability and toxicity may include modifying the rhizosphere pH and Eh, chelating/complexing and depositing with Cd ions, and altering the community construction, the numbers and activities of rhizospheric microbes. In this paper, the methods to reduce the transfer of Cd in soil-plant system by adjusting rhizosphere environment are discussed, and some aspects are also proposed that should be emphasized in the future research work.

scholarly journals Growth, yield and content of trace elements in coffee fruits grown in soils under successive application of sewage sludge

2016 ◽  
Vol 11 (29) ◽  
pp. 2536-2546
Author(s):  
Lucrecio da Costa Alisson ◽  
L uacute cia Pinheiro Gabriela ◽  
Villela Soares Fl aacute via ◽  
Alberto Silva Carlos ◽  
Maria de Lima Jos eacute
Keyword(s):  
Trace Elements ◽  
Sewage Sludge ◽  
Growth Yield

Volatilisation of trace elements for coal–sewage sludge blends during their combustion☆

Fuel ◽  
2003 ◽  
Vol 82 (15-17) ◽  
pp. 1939-1948 ◽  
Author(s):  
M.Belén Folgueras ◽  
Ramona M Dı́az ◽  
Jorge Xiberta ◽  
Ismael Prieto
Keyword(s):  
Trace Elements ◽  
Sewage Sludge

scholarly journals The chemistry influencing ODEs in the Polar Boundary Layer in spring: a model study

2008 ◽  
Vol 8 (2) ◽  
pp. 7391-7453 ◽  
Author(s):  
M. Piot ◽  
R. von Glasow
Keyword(s):  
Boundary Layer ◽  
Ozone Depletion ◽  
Chemical Species ◽  
Field Measurements ◽  
The Arctic ◽  
Direct Reaction ◽  
Mixing Ratios ◽  
Model Study ◽  
Sensitivity Studies ◽  
Chemical Conditions

Abstract. Near-total depletions of ozone have been observed in the Arctic spring since the mid 1980s. The autocatalytic cycles involving reactive halogens are now recognized to be of main importance for Ozone Depletion Events (ODEs) in the Polar Boundary Layer (PBL). We present sensitivity studies using the model MISTRA in the box-model mode on the influence of chemical species on these ozone depletion processes. In order to test the sensitivity of the chemistry under polar conditions, we compared base runs undergoing fluxes of either Br2, BrCl, or Cl2 to induce ozone depletions, with similar runs including a modification of the chemical conditions. The role of HCHO, H2O2, DMS, Cl2, C2H4, C2H6, HONO, NO2, and RONO2 was investigated. Cases with elevated mixing ratios of HCHO, H2O2, DMS, Cl2, and HONO induced a shift in bromine speciation from Br/BrO to HOBr/HBr, while high mixing ratios of C2H6 induced a shift from HOBr/HBr to Br/BrO. Cases with elevated mixing ratios of HONO, NO2, and RONO2 induced a shift to BrNO2/BrONO2. The shifts from Br/BrO to HOBr/HBr accelerated the aerosol debromination, but also increased the total amount of deposited bromine at the surface (mainly via increased deposition of HOBr). These shifts to HOBr/HBr also hindered the BrO self-reaction. In these cases, the ozone depletion was slowed down, where increases in H2O2 and HONO had the greatest effect. The tests with increased mixing ratios of C2H4 highlighted the decrease in HOx which reduced the production of HOBr from bromine radicals. In addition, the direct reaction of C2H4 with bromine atoms led to less available reactive bromine. The aerosol debromination was therefore strongly reduced. Ozone levels were highly affected by the chemistry of C2H4. Cl2-induced ozone depletions were found unrealistic compared to field measurements due to the rapid production of CH3O2, HOx, and ROOH which rapidly convert reactive chlorine to HCl in a "chlorine counter-cycle". This counter-cycle efficiently reduces the concentration of reactive halogens in the boundary layer. Depending on the relative bromine and chlorine mixing ratios, the production of CH3O2, HOx, and ROOH from the counter-cycle can significantly affect the bromine chemistry. Therefore, the presence of both bromine and chlorine in the air may unexpectedly lead to a slow down in ozone destruction. For all NOy species studied (HONO, NO2, RONO2) the chemistry is characterized by an increased bromine deposition on snow reducing the amount of reactive bromine in the air. Ozone is less depleted under conditions of high mixing ratios of NOx. The production of HNO3 led to the acid displacement of HCl, and the release of chlorine out of salt aerosols (Cl2 or BrCl) increased.

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