Oxredmetry as a method to ensure optimum distribution of precious metals in pressure oxidation leaching of pyrrhotite material depending on the type of surfactant used

2019 ◽  
pp. 46-55
Author(s):  
M. N. Naftal ◽  
◽  
L. V. Antonenko ◽  
S. S. Naboychenko ◽  
N. S. Kuznetsov ◽  
...  
Author(s):  
A. V. Kritskii ◽  
M. A. Tretyak ◽  
К. A. Karimov ◽  
S. S. Naboichenko

The existing technologies for copper-porphyry ores enrichment, located in deposits in the Urals of Russia, allow the production of chalcopyrite concentrates of the following composition, %: 21.5 Cu, 24.5 Fe, 26.5 S, 0.4 Pb, 17.6 SiO2, 1.8 CaO, 2–6 Au (ppm), 20– 40 Ag (ppm). A conventional technology for processing such concentrates includes autogenous smelting, matte desulfurization and blister copper refining. Pressure oxidation leaching (POX) is considered the most promising alternative technology for chalcopyrite concentrate processing. The POX of concentrates originated from Mikheevskii GOK allow the production a cake of the following chemical composition, %: 56–65 Fe2O3, 25–30 SiO2, 2.7 Ca, 0.3–1.0 Cu, 2–7 S, 0.6–0.8 Pb, 4–12 Au (ppm), 40–80 Ag (ppm); mass loss was 37–45 %. A standard method of cake cyaniding provides satisfactory indicators of precious metal extraction, but it requires a cumbersome area to be arranged for their processing and offers no solution for residue disposal. In this regard, this paper investigates the method of subsequent cake processing using autoclave treatment (AT) for iron removal. The study shows how the following parameters affect the results of this process: t = 110÷210 °C, H2SO4 = 15÷60 g/dm3, τ = 45÷ ÷120 min. A statistic description of the AT operation is developed. Recommended AT conditions (t = 110 °C, H2SO4 = 60 g/dm3, τ = 60÷100 min) allow to obtain the POX cake yield reduced to 30–35 % of the source material with the following composition, %: 28–33 Fe2O3, 47–53 SiO2, 2–5 Ca, 0.6–2.0 Cu, 0.8–1.5 Pb, 2–8 S. At the same time, the content of precious metals in the cake reaches 12–16 Au (ppm) and 80–120 Ag (ppm). Options for using AT products are proposed.


Author(s):  
R. H. Geiss ◽  
R. L. Ladd ◽  
K. R. Lawless

Detailed electron microscope and diffraction studies of the sub-oxides of vanadium have been reported by Cambini and co-workers, and an oxidation study, possibly complicated by carbon and/or nitrogen, has been published by Edington and Smallman. The results reported by these different authors are not in good agreement. For this study, high purity polycrystalline vanadium samples were electrochemically thinned in a dual jet polisher using a solution of 20% H2SO4, 80% CH3OH, and then oxidized in an ion-pumped ultra-high vacuum reactor system using spectroscopically pure oxygen. Samples were oxidized at 350°C and 100μ oxygen pressure for periods of 30,60,90 and 160 minutes. Since our primary interest is in the mechanism of the low pressure oxidation process, the oxidized samples were cooled rapidly and not homogenized. The specimens were then examined in the HVEM at voltages up to 500 kV, the higher voltages being necessary to examine thick sections for which the oxidation behavior was more characteristic of the bulk.


Author(s):  
Peter Pegler ◽  
N. David Theodore ◽  
Ming Pan

High-pressure oxidation of silicon (HIPOX) is one of various techniques used for electrical-isolation of semiconductor-devices on silicon substrates. Other techniques have included local-oxidation of silicon (LOCOS), poly-buffered LOCOS, deep-trench isolation and separation of silicon by implanted oxygen (SIMOX). Reliable use of HIPOX for device-isolation requires an understanding of the behavior of the materials and structures being used and their interactions under different processing conditions. The effect of HIPOX-related stresses in the structures is of interest because structuraldefects, if formed, could electrically degrade devices.This investigation was performed to study the origin and behavior of defects in recessed HIPOX (RHIPOX) structures. The structures were exposed to a boron implant. Samples consisted of (i) RHlPOX'ed strip exposed to a boron implant, (ii) recessed strip prior to HIPOX, but exposed to a boron implant, (iii) test-pad prior to HIPOX, (iv) HIPOX'ed region away from R-HIPOX edge. Cross-section TEM specimens were prepared in the <110> substrate-geometry.


2018 ◽  
Vol 63 (2) ◽  
pp. 39-52
Author(s):  
Daniela Violeta Dumitrescu ◽  
◽  
Vasile Soare ◽  
Ionuţ Constantin ◽  
Marian Burada ◽  
...  

2017 ◽  
Vol 12 (30) ◽  
pp. 53-61
Author(s):  
A.A. Solodenko ◽  
◽  
A.B. Solodenko ◽  
S.I. Evdokimov ◽  
Yu.G. Klykov ◽  
...  
Keyword(s):  

Author(s):  
Ngoc Anh Nguyen

The analysis of a data set of observation for Vietnamese banks in period from 2011 - 2015 shows how Capital Adequacy Ratio (CAR) is influenced by selected factors: asset of the bank SIZE, loans in total asset LOA, leverage LEV, net interest margin NIM, loans lost reserve LLR, Cash and Precious Metals in total asset LIQ. Results indicate based on data that NIM, LIQ have significant effect on CAR. On the other hand, SIZE and LEV do not appear to have significant effect on CAR. Variables NIM, LIQ have positive effect on CAR, while variables LLR and LOA are negatively related with CAR.


Author(s):  
Yu. Kanataev

The author, head of the Association of science-intensive enterprises having great experience in exploration of oil, precious metals, etc. in Russia and abroad (Austria, China, Israel, Ethiopia), first implemented on an industrial scale deep processing of oil using domestic technology, discusses the problems of further development of the Russian economy through the prism of their solutions to the main industries — oil and petrochemical complex.


Sign in / Sign up

Export Citation Format

Share Document