scholarly journals Determination of saturation vapor pressure of low volatile substances through the study of evaporation rate by thermogravimetric analysis

Author(s):  
R.V. Ralys ◽  
G.S. Yablonsky ◽  
A.A. Slobodov
1963 ◽  
Vol 41 (1) ◽  
pp. 180-190 ◽  
Author(s):  
J. R. Dacey ◽  
R. G. Barradas

Systematic infrared analyses, using the standard KBr pellet technique, of samples ranging from the pure polymer (Saran) to the fully carbonized charcoal have been examined in an attempt to clarify the structural changes and mechanism of decomposition of the polymer on pyrolysis. A complementary technique has been investigated for obtaining homogeneous samples of the carbon and of the partially pyrolyzed polymer which will transmit infrared radiation without the use of any halide dispersal medium. The significance, possible applications, and limitations of these spectral studies are discussed. Pore volumes have been examined by means of a modified helium displacement densitometer and also through the adsorption of argon in a McBain–Bakr balance. Porosity measurements based on the adsorption of argon at its saturation vapor pressure are more satisfactory and they contribute towards a better understanding of the microstructure of Saran charcoal and of its partially carbonized antecedents. The influence of pelletizing pressure has been found to play an important role in the determination of pore volumes.


2012 ◽  
Vol 57 (2) ◽  
pp. 219-225 ◽  
Author(s):  
S. I. Lopatin ◽  
V. L. Stolyarova ◽  
V. G. Sevast’yanov ◽  
P. Ya. Nosatenko ◽  
V. V. Gorskii ◽  
...  

Author(s):  
Suma Kuravi ◽  
Dereje Agonafer

Presence of Humidity has many undesired effects in many applications. Moisture balance of the air has become an important task and dehumidification has become a necessity for many applications in many industries. This paper discusses about the study of the factors affecting the evaporation rate of water in cavities exposed to humid conditions. The ASHRAE equation to find the evaporation rate in swimming pools is considered and validated for a small pool of water in humid conditions in humid cavity with fixed dimensions. The equation states that, the evaporation rate, W = (95+0.425*V)*(Pw-Pa)/Y, where W is the Evaporation rate in lb/h-ft2; V is the air velocity at water surface; ft/min; Pw is the saturation vapor pressure at water temperature, in. Hg; Pa is saturation vapor pressure at air dew point, in. Hg; and Y is latent at water temperature, Btu/lb. The evaporation rate inside the humid cavity is found and compared with that of the equation. The evaporation rate obtained inside the humid cavity is 95% of the evaporation rate obtained by the use equation. The factors responsible for the low evaporation rate are identified. A CFD Model is developed using FLUENT to represent the time averaged steady state condition of the humid cavity. The temperature and velocity values at particular points are probed in CFD model and are obtained. The results are compared with the actual physical model. These values are used to find the evaporation rate occurring inside the cavity using the ASHRAE equation. The evaporation rate found in the humid cavity is found to be 76% of the evaporation rate that is calculated from the values of the CFD model, using the equation. Factors affecting the evaporation rate inside the humid cavity are discussed and the effects of these factors are illustrated using the CFD Model. Propositions are made to improve the evaporation rates inside the humid cavity. Future studies are planned to do a multi species modeling to include humidity in the CFD analysis for humid cavity.


2010 ◽  
Vol 55 (13) ◽  
pp. 2073-2088 ◽  
Author(s):  
V. G. Sevast’yanov ◽  
P. Ya. Nosatenko ◽  
V. V. Gorskii ◽  
Yu. S. Ezhov ◽  
D. V. Sevast’yanov ◽  
...  

1965 ◽  
Vol 43 (8) ◽  
pp. 2157-2161 ◽  
Author(s):  
R. A. Back ◽  
J. Betts

The saturation vapor pressure of solid hydroxylamine has been determined at temperatures from −12 to 7° C and found to fit the equation[Formula: see text]From this have been calculated several thermochemical quantities, including a heat of sublimation of 15.34 kcal/mole, and a dissociation energy of 61.3 kcal/mole for the NH2—OH bond. Vapor density measurements showed that hydroxylamine vapor consisted of single molecules of NH2OH at 0.27 Torr and 25 °C.A novel pressure gauge used in the measurements is described. Pressures were determined with an accuracy of ±0.001 Torr by measuring the force acting on a piston, moving freely in a glass cylinder, suspended on the arm of a torsion balance.


1990 ◽  
Vol 14 ◽  
pp. 361-361
Author(s):  
Stephen Warren ◽  
Susan Frankenstein

Climatic warming due to increased greenhouse gases is expected to cause increased precipitation in the next century because of the increased water content of the air, assuming constant relative humidity. Since temperatures over most of Antarctica are far below freezing even in the warmest month of the year, the increase in melting is probably negligible compared to the increase in precipitation.Oerlemans (1982) showed that this increase of precipitation would cause a growth of the ice sheet, tending to lower sea level. This would partially counteract the rise of sea level due to increased melting on mountain glaciers and Greenland, and to a possible (and more difficult to predict) surge of ice from West Antarctica.Oerlemans may have underestimated the increase in accumulation. He used results of General Circulation Models (GCMs) which indicated an increase of precipitation by only 12% for a temperature change ΔΤ = 3 Κ and 30% for ΔΤ = 8 K. In contrast, the change in accumulation rate at Dome C (Lorius and others, 1979) accompanying the warming from the recent ice age to the present was in accord with the simple assumption that accumulation is proportional to saturation vapor pressure at the temperature of the inversion layer, i.e. a 30% increase for ΔΤ = 3 K.The experimental results are to be preferred to the climate model results because GCMs do not represent ice-sheet accumulation processes well. Most of the accumulation is not snow falling from clouds but instead results from clear-sky ice-crystal formation in near-surface air, or hoarfrost deposition on the surface. GCMs lack sufficient vertical resolution to represent the strong temperature inversion on which these accumulation mechanisms depend.The figure shows that the increase of vapor pressure due to ΔΤ = 5 Κ varies from a factor of 1.9 at Τ = −60°C to a factor of 1.6 at Τ = −20°C. A climatic warming of 5 K. over Antarctica, which is possible during the next century, could thus increase the Antarctic accumulation from its present 17g cm−2 yr−1 to 30 g cm−2 yr−1, leading to a 50 cm drop in sea level in 100 years. This assumes that the simple proportionality of precipitation rate to saturation vapor pressure applies as well to the coastal regions, which is doubtful because the accumulation processes are not the same as on the plateau.The potential importance of Antarctic accumulation changes in contributing to changes of sea level argues for further study of the mechanisms of Antarctic precipitation and for their improved representation in climate models.


1990 ◽  
Vol 14 ◽  
pp. 361
Author(s):  
Stephen Warren ◽  
Susan Frankenstein

Climatic warming due to increased greenhouse gases is expected to cause increased precipitation in the next century because of the increased water content of the air, assuming constant relative humidity. Since temperatures over most of Antarctica are far below freezing even in the warmest month of the year, the increase in melting is probably negligible compared to the increase in precipitation. Oerlemans (1982) showed that this increase of precipitation would cause a growth of the ice sheet, tending to lower sea level. This would partially counteract the rise of sea level due to increased melting on mountain glaciers and Greenland, and to a possible (and more difficult to predict) surge of ice from West Antarctica. Oerlemans may have underestimated the increase in accumulation. He used results of General Circulation Models (GCMs) which indicated an increase of precipitation by only 12% for a temperature change ΔΤ = 3 Κ and 30% for ΔΤ = 8 K. In contrast, the change in accumulation rate at Dome C (Lorius and others, 1979) accompanying the warming from the recent ice age to the present was in accord with the simple assumption that accumulation is proportional to saturation vapor pressure at the temperature of the inversion layer, i.e. a 30% increase for ΔΤ = 3 K. The experimental results are to be preferred to the climate model results because GCMs do not represent ice-sheet accumulation processes well. Most of the accumulation is not snow falling from clouds but instead results from clear-sky ice-crystal formation in near-surface air, or hoarfrost deposition on the surface. GCMs lack sufficient vertical resolution to represent the strong temperature inversion on which these accumulation mechanisms depend. The figure shows that the increase of vapor pressure due to ΔΤ = 5 Κ varies from a factor of 1.9 at Τ = −60°C to a factor of 1.6 at Τ = −20°C. A climatic warming of 5 K. over Antarctica, which is possible during the next century, could thus increase the Antarctic accumulation from its present 17g cm−2 yr−1 to 30 g cm−2 yr−1, leading to a 50 cm drop in sea level in 100 years. This assumes that the simple proportionality of precipitation rate to saturation vapor pressure applies as well to the coastal regions, which is doubtful because the accumulation processes are not the same as on the plateau. The potential importance of Antarctic accumulation changes in contributing to changes of sea level argues for further study of the mechanisms of Antarctic precipitation and for their improved representation in climate models.


Sign in / Sign up

Export Citation Format

Share Document