Investigations of Model Multilayer Ceramic Casting Molds in a Raw State by Nondestructive Methods

This article presents the results of research on the use of modern nondestructive methods such as 3D scanning, thermography and computed tomography (CT) to assess the quality of multilayer ceramic molds. Tests were performed on spherical samples of multilayer ceramic molds in the raw state. Samples were made of molding sands composed of quartz and molochite powders, the alcoholic binder hydrolyzed ethyl silicate (ZKE) and an aqueous binder based on colloidal silica. Thickness measurements of spherical forms were made using a 3D scanner. Porosity measurements were made using CT. Additionally, thermography observations of the mold cooling process were made with controlled temperature and humidity. The results of temperature measurements of samples were compared with measurements of thickness and porosity. The practical goal was to determine the possibility of using thermography, 3D scanning and CT as a quick method for detecting mold defects by varying their thickness, porosity and cracks and for final verification of the ceramic molds’ condition before casting.

Determination of Porosity in Fluidized-Bed Carburized P/M Compacts Using an Image Software Analysis

The aim of this research was to study the porosity in carburizing in fluidized-bed on sintered alloys produced by powder metallurgy route using an image analysis software and to compare the obtained results with the conventional method for porosity measurements. Porosity is a measure of the void fraction in a material. The total porosity is defined by the ratio of the volume of void space to the total bulk volume of the material, expressed as a percentage. Development of digital images and computer software lead to a new and suitable method to determine the porosity of powder metallurgy materials.

Application of Nanosilicon to the Sintering of Mg-Mg2Si Interpenetrating Phases Composite

The new in situ fabrication process for Mg-Mg2Si composites composed of interpenetrating metal/intermetallic phases via powder metallurgy was characterized. To obtain the designed composite microstructure, variable nanosilicon ((n)Si) (i.e., 2, 4, and 6 vol.% (n)Si) concentrations were mixed with magnesium powders. The mixture was ordered using a sonic method. The powder mixture morphologies were characterized using scanning electron microscopy (SEM), and heating and cooling-induced thermal effects were characterized using differential scanning calorimetry (DSC). Composite sinters were fabricated by hot-pressing the powders under a vacuum of 2.8 Pa. Shifts in the sintering temperature resulted in two observable microstructures: (1) the presence of Mg2Si and MgO intermetallic phases in α-Mg (580 °C); and (2) Mg2Si intermetallic phases in the α-Mg matrix enriched with bands of refined MgO (640 °C). Materials were characterized by light microscopy (LM) with quantitative metallography, X-ray diffraction (XRD), open porosity measurements, hardness testing, microhardness testing, and nanoindentation. The results revealed that (n)Si in applied sintering conditions ensured the formation of globular and very fine Mg2Si particles. The particles bonded with each other to form an intermetallic network. The volume fraction of this network increased with (n)Si concentration but was dependent on sintering temperature. Increasing sintering temperature intensified magnesium vaporization, affecting the composite formation mechanism and increasing the volume fraction of silicide.

Sink or float: microtextural controls on the fate of pumice deposition during the 2012 submarine Havre eruption

Silicic submarine volcanic eruptions can produce large volumes of pumices that may rise buoyantly to the ocean surface and/or sink to the seafloor. For eruptions that release significant volumes of pumice into rafts, the proximal to medial submarine geologic record is thus depleted in large volumes of pumice that would have sedimented closer to source in any subaerial eruption. The 2012 eruption of Havre volcano, a submarine volcano in the Kermadec Arc, presents a unique opportunity to study the partitioning of well-constrained rafted and seafloor pumice. Macro- and microtextural analysis was performed on clasts from the Havre pumice raft and from coeval pumiceous seafloor units around the Havre caldera. The raft and seafloor clasts have indistinguishable macrotextures, componentry, and vesicularity ranges. Microtextural differences are apparent as raft pumices have higher vesicle number densities (109 cm−3 vs. 108 cm−3) and significantly lower pore space connectivity (0.3–0.95 vs. 0.9–1.0) than seafloor pumices. Porosity analysis shows that high vesicularity raft pumices required trapping of gas in the connected porosity to remain afloat, whereas lower vesicularity raft pumices could float just from gas within isolated porosity. Measurements of minimum vesicle throat openings further show that raft pumices have a larger proportion of small vesicle throats than seafloor pumices. Narrow throats increase gas trapping as a result of higher capillary pressures acting over gas–water interfaces between vesicles and lower capillary number inhibiting gas bubble escape. Differences in isolated porosity and pore throat distribution ultimately control whether pumices sink or float and thus whether pumice deposits are preserved or not on the seafloor.

Micromechanical modeling of ultrasonic velocity for pore-structure and porosity characterization considering anisotropy in carbonate samples

This work presents an approach to characterize the pore-structure and anisotropy in carbonate samples based on the Effective Medium Method (EMM). It considers a matrix with spheroidal inclusions which induce a transverse anisotropy. The compressional wave (VP), vertical (VSV) and horizontal (VSH) shear wave velocities are estimated taking into account parameters as characteristic length, frequency, angle of wave incidence, aspect ratio, mineralogy, and pore-filling fluid to predict pore shape in carbonates. Ranges of aspect ratios are shown to discriminate different pore types: intercrystalline, intergranular, moldic, and vuggy. The angle of wave incidence is a determinant parameter in the estimation of VP(0º, 45º, 90º), VSV(0º) and VSH(90º) to calculate dynamic anisotropic Young’s modulus (E33) and Poisson’s ratio (v31), as well as the Thomsen parameters, Epsilon, Gamma and Delta for quantification of the anisotropic pore-structure. The obtained results establish that the size, as well as the pore-structure, have a more significant impact on the elastic properties when the porosity takes values greater than 4% for the three frequencies, ultrasonic, sonic, and seismic. This investigation predicts the pore-structure and pore-size to improve characterization and elastic properties modeling of carbonate reservoirs. Validation of results includes porosity measurements and ultrasonic velocity data for different carbonate samples.

The Variable Frequency Conductivity of Geopolymers during the Long Agieng Period

The variable frequency conductivity was applied to characterize the process of solidification of geopolymers based on fly ash with sand additives. XRD qualitative and quantitative analysis, porosity measurements, and sorption analysis of specific surface area were performed. The conductivity was correlated with porosity and specific surface area of geopolymer concretes. Both values of conductivity, real and imaginary parts, decreased during polymerization processing time. Characteristic maximum on graphs describing susceptance vs. frequency curve was observed. The frequency of this maximum depends on time of polymerization and ageing, and can also indicate porosity of material. Low-porous geopolymer concrete shows both low-conductivity values, and susceptance maximum frequency peak occurs more in the higher frequencies than in high-porous materials.

The regulating effects and mechanism of biochar and maifanite on copper and cadmium in a polluted soil-Lolium perenne L. system

Arable land polluted by copper (Cu) and cadmium (Cd) is a widespread problem. The use of biochar and/or clay mineral as a soil amendment can effectively solidify heavy metals in the soil. We applied biochar (BC), iron modified biochar (Fe-BC), maifanite (MF, a kind of clay minerals), a combination of BC with MF (BC:MF), and Fe-BC with MF (Fe-BC:MF) at a 2 wt % dose as soil amendments to study their ability to prevent Cu and Cd from accumulating in ryegrass (Lolium perenne L.). We found that after 90 days of cultivation, the Cd and Cu content both significantly decreased in ryegrass shoots from 2.06 and 209.3 mg kg−1 (control) to 1.44–2.01 and 51.50–70.92 mg kg−1, respectively, across treatments (p < 0.05). Similarly, the bioconcentration factor (BCF) for Cd/Cu was significantly smaller (P < 0.05) in all amendments versus control soil. This trend differed among the shoot, BCF, and transportation factor (TF). Combining BC:MF or Fe-BC:MF did not significantly improve the Cd/Cu stabilization in the soil compared to the corresponding single amendment (p > 0.05). Our adsorption balance experiment showed that BC, Fe-BC, and MF physically and chemically adsorbed Cd and Cu by complexation with functional groups (mesoporous nanomaterials) whose porosity measurements ranged from 0.68 to 78.57 m2 g−1. Furthermore, the amorphous crystalline iron oxide binding Cd and Cu was the key to immobilizing these metals in the soil. The amendments applied in our study show promise for enhancing immobilization of Cu and Cd in contaminated paddy soils.

In-vitro Evaluation of Chitosan - Hydroxyapatite Nanocomposite Scaffolds as Bone Substitutes with Antibiofilm Properties

An opaque, white chitosan/ Hydroxyapatite nanocomposite was prepared by a simple blend method. Morphology, pore size and dispersion of nano-hydroxyapatite in chitosan matrix were visualized using SEM images. The FTIR and SEM with EDX analysis confirmed the bony apatite layer was formed on the outside of the composite. Porosity measurements and water uptake studies of the nanocomposite were evaluated which revealed the maximum porosity of 80% to 92% in the chitosan: hydroxyapatite nanocomposite at the ratio of 20:80. The results also showed that water absorption ability was inversely proportional to the hydroxyapatite present in the nanocomposite. The porosity of prepared nanocomposite was corresponding to the cancellous bone porosity of 50% to 90% suggesting possible applications in bone transplantation. The nanocomposite exhibited antibacterial activity towards the tested Gram-negative and Gram-positive species of bacteria and reduced the bacterial adhesion in biofilm formation.