scholarly journals Dry Methane Reforming on Carbon-Doped Nickel Foams

2011 ◽  
Vol 14 (1) ◽  
pp. 9 ◽  
Author(s):  
Juan Matos ◽  
Carlos Paredes ◽  
Maibelin Rosales

<p>The catalytic activity of carbon-doped nickel foams in the dry methane reforming was studied at mild experimental conditions. The catalysts were synthesized by the controlled pyrolysis of different Nicontaining re-crystallized saccharose under N<sub>2</sub> flow. The results showed that carbon proportion clearly influences the catalytic activity of Ni-foams from low to moderate catalytic activity attributed to an in situ formation during pre-treatment of very active reduced Ni phases. It can be conclude that carbon-doped nickel foams catalysts prepared from the controlled pyrolysis of saccharose are interesting materials for natural gas conversion reactions.</p>


Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2358 ◽  
Author(s):  
David Lopez-Tejedor ◽  
Blanca de las Rivas ◽  
Jose M. Palomo

A novel heterogeneous enzyme-palladium (Pd) (0) nanoparticles (PdNPs) bionanohybrid has been synthesized by an efficient, green, and straightforward methodology. A designed Geobacillus thermocatenulatus lipase (GTL) variant genetically and then chemically modified by the introduction of a tailor-made cysteine-containing complementary peptide- was used as the stabilizing and reducing agent for the in situ formation of ultra-small PdNPs nanoparticles embedded on the protein structure. This bionanohybrid was an excellent catalyst in the synthesis of trans-ethyl cinnamate by Heck reaction at 65 °C. It showed the best catalytic performance in dimethylformamide (DMF) containing 10–25% of water as a solvent but was also able to catalyze the reaction in pure DMF or with a higher amount of water as co-solvent. The recyclability and stability were excellent, maintaining more than 90% of catalytic activity after five cycles of use.



1970 ◽  
Vol 10 (01) ◽  
pp. 51-55 ◽  
Author(s):  
Robert A. Albrecht ◽  
Sullivan S. Marsden

Abstract Although foam usually will flow in porous media, under certain controllable conditions it can also be used to block the flow of gas, both in unconsolidated sand packs and in sandstones. After steady gas or foam flow has been established at a certain injection pressure pi, the pressure is decreased until flow pressure pi, the pressure is decreased until flow ceases at a certain blocking pressure pb. When flow is then reestablished at a second, higher pi, blocking can again occur at another pb that will usually be greater than the first pi. The relationship between pi and Pb depends on the type of porous medium and the foamer solution saturation in the porous medium. A process is suggested whereby porous medium. A process is suggested whereby this phenomenon might be used to impede or block leakage in natural gas storage projects. Introduction The practice of storing natural gas in underground porous rocks has developed rapidly, and it now is porous rocks has developed rapidly, and it now is the major way of meeting peak demands in urban areas of the U. S. Many of these storage projects have been plagued with gas leakage problems that have, in some cases, presented safety hazards and resulted in sizeable economic losses. Usually these leaks are due to such natural factors as faults and fractures, or to such engineering factors as poor cement jobs and wells that were improperly abandoned. For the latter, various remedies such as spot cementing have been tried but not always with great success. In recent years several research groups have been studying the flow properties of aqueous foams and their application to various petroleum engineering problems. Most of this work has been done under problems. Most of this work has been done under experimental conditions such that the foam would flow in either tubes or porous media. However, under some extreme or unusual experimental conditions, flow in porous media becomes very difficult or even impossible. This factor also has suggested m us as well as to others that foam can be used as a gas flow impeder or as a sealant for leaks in gas storage reservoirs. In such a process, the natural ability of porous media to process, the natural ability of porous media to generate foam would be utilized by injecting a slug of foamer solution and following this with gas to form the foam in situ. This paper presents preliminary results of a sandy on the blockage of gas flow by foam in porous media. It also describes how this approach might be applied to a field process for sealing leaks in natural gas storage reservoirs. Throughout this report, we use the term "foam" to describe any dispersed gas-liquid system in which the liquid is the continuous phase, and the gas is the discontinuous phase. APPARATUS AND PROCEDURE A schematic drawing of the apparatus is shown in Fig. 1. At least 50 PV of filtered, deaerated foamer solution were forced through the porous medium to achieve liquid saturation greater than 80 percent. Afterwards air at controlled pressures was passed into the porous medium in order to generate foam in situ. Table 1 shows the properties and dimensions of the several porous media that were used. The beach sands were washed, graded and packed into a vibrating lucite tube containing a constant liquid level to avoid Stoke's law segregation over most of the porous medium. JPT P. 51



2020 ◽  
Vol 103 (5) ◽  
pp. 2991-3001 ◽  
Author(s):  
Daniel Schumacher ◽  
Michaela Wilhelm ◽  
Kurosch Rezwan


2015 ◽  
Vol 17 (8) ◽  
pp. 4157-4161 ◽  
Author(s):  
Sankararao Chappa ◽  
Rakesh N. Shinde ◽  
Ashok K. Pandey

Highly stable metal nanocatalysts formed in self-reducing asymmetric polymer membrane exhibit good catalytic activity in inorganic and organic redox reactions.



1993 ◽  
Vol 97 (13) ◽  
pp. 3355-3358 ◽  
Author(s):  
A. T. Ashcroft ◽  
A. K. Cheetham ◽  
R. H. Jones ◽  
S. Natarajan ◽  
J. M. Thomas ◽  
...  


2014 ◽  
Vol 50 (74) ◽  
pp. 10871-10874 ◽  
Author(s):  
Huaixia Zhao ◽  
Yangxin Wang ◽  
Ruihu Wang

A new strategy for the synthesis of well-dispersed palladium nanoparticles (NPs) immobilized in imidazolium-based porous organic ionic polymers was presented in this study. The as-synthesized polymers showed excellent catalytic activity and reusability in the hydrogenation of nitroarenes without extra addition of palladium species.



Nanoscale ◽  
2020 ◽  
Vol 12 (28) ◽  
pp. 15185-15192
Author(s):  
Abbas Beheshti Askari ◽  
Mustafa al Samarai ◽  
Nozomu Hiraoka ◽  
Hirofumi Ishii ◽  
Lukas Tillmann ◽  
...  

The effect of cobalt on the catalytic activity of a NiCoO dry methane reforming catalyst was investigated by in situ XES and HERFD XAS. Co is shown to hamper the reduction of the Ni in the NiCoO catalyst by modulation of its electronic structure.



2016 ◽  
Vol 7 ◽  
pp. 1815-1821 ◽  
Author(s):  
Jingxia Yang ◽  
Johannes Ofner ◽  
Bernhard Lendl ◽  
Ulrich Schubert

Raman and IR investigations indicated the presence of reduced graphene oxide (rGO)-like residues on ceria nanoparticles after solvothermal treatment in ethanol. The appearance of such structures is closely related to cerium tert-butoxide as precursor and ethanol as solvothermal solvent. The rGO-like residues improve the catalytic CO oxidation activity. This was also confirmed by introduction of “external” graphene oxide during sol–gel processing, by which the rGO structures and the catalytic activity were enhanced.



Author(s):  
M. Adachi ◽  
R. Matsuyama ◽  
T. Nakagawa ◽  
S. Kuroshima ◽  
T. Ogatsu ◽  
...  

Abstract. In 2010, eight companies which are exploiting natural gas and brine water in the Southern Kanto natural gas field, Chiba prefecture, Japan constructed an in-situ formation deformation monitoring well with a depth of approximately 80 m, and in-situ formation deformation was measured on a trial basis. After this field test, by conducting the simulation study, we verified whether the deformation behavior at the monitoring well was perfectly elastic or not. In addition, we compared in-situ rock properties like Young's modulus and Poisson's ratio which were estimated by the simulation study with those determined from a triaxial compression test.



2017 ◽  
Vol 39 (1) ◽  
pp. 71-77 ◽  
Author(s):  
Zewu Zhang ◽  
Qiong Wu ◽  
Xiaohai Bu ◽  
Zusheng Hang ◽  
Zhangzhong Wang ◽  
...  


Sign in / Sign up

Export Citation Format

Share Document