The Use of Technogenic Waste to Clean the Flue Gases of Thermal Devices from Harmful Substances

2019 ◽  
Vol 23 (6) ◽  
pp. 4-7
Author(s):  
A.M. Pogodaev ◽  
A.F. Shimansky ◽  
Yu.I. Storozhev ◽  
Ya.V. Kazantsev ◽  
V.S. Zlobin

The thermodynamics of the process of calcium sulfate decomposition is considered. An adsorbent for cleaning flue gases from sulfur dioxide in the form of sludge from alumina production is proposed. Conducted semi-industrial experiments on cleaning the flue gases of small thermal power plants and boiler houses from sulfur dioxide using a laboratory installation. Established high (more than 90%) the effectiveness of the proposed adsorbent. The unique possibility of flue gas cleaning from nitrogen oxides of thermal devices using lignite fuel is revealed. A scheme of sequential flue gas cleaning in a suspended and fixed bed of the adsorbent is proposed.

2018 ◽  
Vol 245 ◽  
pp. 07014 ◽  
Author(s):  
Evgeny Ibragimov ◽  
Sergei Cherkasov

The article presents data on the calculated values of improving the efficiency of fuel use at the thermal power plant as a result of the introduction of a technical solution for cooling the flue gases of boilers to the lowest possible temperature under the conditions of safe operation of reinforced concrete and brick chimneys with a constant value of the flue gas temperature, when changing the operating mode of the boiler.


2021 ◽  
Vol 808 (1) ◽  
pp. 012017
Author(s):  
D S Protsko ◽  
S Yu Panov ◽  
N N Lobachova ◽  
S V Lavrov ◽  
A S Belozercev

Author(s):  
I.A. Volchyn ◽  
O.M. Kolomiets ◽  
V.A. Raschepkin

The mathematical modeling is performed of the efficiency of flue gas cleaning from fly ash particles of coal-fired thermal power plants, upon installation of a preliminary flue gas cleaning system that consists of a louvered dust concentrator and a battery cyclone, with the recirculation of flue gas from the battery cyclone outlet to the electrostatic precipitator pre-chamber. Based on the available experimental data for the fractional composition of fly ash downstream the boilers of coal-fired TPPs, the size distribution functions were calculated, of fly ash particles at each stage of the preliminary dust-cleaning process, as well as concentrations and modified particle size distributions, to be further used as the input data for designing options and scope of the reconstruction of existing electrostatic precipitators. Bibl. 13, Fig. 3.


2020 ◽  
Vol 216 ◽  
pp. 01082
Author(s):  
Elvira Khusnutdinova ◽  
Larisa Nikolaeva

This paper proposes an adsorption-based method of removing sulfur dioxide from the flue gases produced by the thermal power plant. A power plant waste – chemical water treatment sludge available at Kazan CHPP-1 – was used as an adsorption material. Presented here is the chemical composition of the chemical water treatment sludge for a modified sorption material to be designed therefrom. The new sorp-tion material was trial tested for removal of sulfur dioxide from gases. This resulted in kinetic dependence and adsorption isotherm. The test results were then used to design the adsorber. The economic and envi-ronmental effect of using the chemical water treatment sludge as the sorption material was calculated.


Clay Minerals ◽  
2015 ◽  
Vol 50 (1) ◽  
pp. 31-40 ◽  
Author(s):  
Magdalena Wdowin ◽  
Mariusz Macherzyński ◽  
Rafał Panek ◽  
Jerzy Górecki ◽  
Wojciech Franus

AbstractThe removal of gaseous mercury from flue gases from coal-fired power plants is currently an environmental challenge under investigation. Therefore, the main aim of this paper was to evaluate the suitability of faujasite group zeolites (Na-X) to adsorb mercury compounds. Previous, initial tests showed negligible Hg0 uptake by Na-X zeolite, but silver impregnation improved adsorption markedly. Therefore, the testing of mercury adsorption from flue gases into Ag+- impregnated Na-X synthetic zeolite (Ag-X zeolite) derived from coal fly ash was carried out. This material was characterized by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy, X-ray fluorescence and nitrogen adsorption/desorption before being evaluated for mercury removal from exhaust gas. After preliminary mercury adsorption tests (fixed bed) under a nitrogen atmosphere, the adsorbent was examined with a simulated flue gas composition under various conditions, i.e. weight of zeolite, temperature of experiment and zeolite in powder and granulated forms. The removal of mercury was shown to depend on the sorbent texture (powder or granulate), exhaust gas flow rate and contact time, as well as the temperature of the experiment. The Ag-X zeolite tested reduced the level of mercury in the flue gas and, depending on the experimental conditions, long-time mercury breakthrough ranges from 15 to 40% were obtained. The best results for mercury capture were obtained for granulated material.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3860
Author(s):  
Mária Hagarová ◽  
Milan Vaško ◽  
Miroslav Pástor ◽  
Gabriela Baranová ◽  
Miloš Matvija

Corrosion of boiler tubes remains an operational and economic limitation in municipal waste power plants. The understanding of the nature, mechanism, and related factors can help reduce the degradation process caused by corrosion. The chlorine content in the fuel has a significant effect on the production of gaseous components (e.g., HCl) and condensed phases on the chloride base. This study aimed to analyze the effects of flue gases on the outer surface and saturated steam on the inner surface of the evaporator tube. The influence of gaseous chlorides and sulfates or their deposits on the course and intensity of corrosion was observed. The salt melts reacted with the steel surface facing the flue gas flow and increased the thickness of the oxide layer up to a maximum of 30 mm. On the surface not facing the flue gas flow, they disrupted the corrosive layer, reduced its adhesion, and exposed the metal surface. Beneath the massive deposits, a local overheating of the inner surface of the evaporator tubes occurred, which resulted in the release of the protective magnetite layer from the surface. Ash deposits reduce the boiler’s thermal efficiency because they act as a thermal resistor for heat transfer between the flue gases and the working medium in the pipes. The effect of insufficient feedwater treatment was evinced in the presence of mineral salts in the corrosion layer on the inner surface of the tube.


2021 ◽  
Vol 410 ◽  
pp. 806-811
Author(s):  
Kapar Sh. Aryngazin ◽  
Alexey V. Bogomolov ◽  
Askar K. Tleulessov

The article discusses the experience of recycling industrial waste from the electric power industry and metallurgy. Based on the experience of Ecostroy NII-PV LLP. The proposed technology for manufacturing building products from ash and slag waste provides innovative compositions of raw mixtures. What provides an increase in operational characteristics and labor productivity in construction. The applied technology, in comparison with the existing analogues, provides for the use of local waste (ash and slag waste from the combustion of Ekibastuz coal, bauxite sludge from the Pavlodar aluminum plant, steel-making slags), differing in chemical and granulometric composition. as well as binding properties from other analogs and prototypes. In the manufacture of building products introduced mixture, including, wt %: slag Portland cement - 14.32-17.00; sand - 18.74-25.52, crushed stone - 46.50-49.71, sludge from alumina production obtained during the recycling of bauxite from Kazakhstan - 5-7; self-disintegrating steelmaking slag - 5-7; ash and slag waste from thermal power plants from burning Ekibastuz coals - 5-7. According to the test results, the average tensile strength of building products (paving slabs, curbs, hollow bricks) is 3.2 - 3.8 MPa (strength class V2.5).


2019 ◽  
Vol 11 (4) ◽  
pp. 288-293 ◽  
Author(s):  
A. T. Zamalieva ◽  
M. G. Ziganshin

Energy is the basic sector of the economy and the largest consumer of primary energy resources of any country, which is why the development of world energy is accompanied by global pressure on the environment. The issues are considered of reducing the atmospheric impact of emissions of thermal power plants, improving the reliability and working life of their units, systems, and plants as a whole. The principles are presented of development and improvement of technologies for processing industrial emissions of thermal power plants, the neutralization of which is currently relevant on a regional and global scale. Analysis is carried out of existing methods of cyclone and filtration treatment. An improved design of a cyclone filter is proposed, which allows to increase the reliability of gas turbine and steam-gas units of TPP, while ensuring the efficiency of separation of the suspended part of the flow at the gas treatment point (GTP) of TPP. Similar devices can also be used to increase the degree of cleaning atmospheric emissions released by the TPP coal dust preparation and flue gas systems at coal generation from fi ne particles of PM10 and PM2,5 classes (coal dust and ash), owing to reduction of the size of caught particles from average values for cyclones and wet scrubbers of the order of 5–10 μm to 0.5 μm. The design of the cyclone filter is improved as a result of research of cyclone filtration by methods of Computational Fluid Dynamics (CFD). A system of Reynolds-averaged equations of a single-phase Navier-Stokes flow is used for mathematical modeling of motion in the cyclone filter. To determine the efficiency of separation of the suspended part of the flow in the cyclone filter, the Rercomplex is used obtained by reducing a set comprising the Navier-Stokes equations and the equation of particle motion based on Newton's law to a dimensionless form. Numerical characteristics of the suspension sedimentation from a multiphase flow in a cyclone separator of specified dimensions are found by means of the Rercomplex. The results of bench tests of the proposed design of the cyclone filter are given. 


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