scholarly journals Synthesis of Needlelike Leucite Crystals Using Potassium Sulfate Flux.

2000 ◽  
Vol 108 (1260) ◽  
pp. 710-713 ◽  
Author(s):  
Shinobu HASHIMOTO ◽  
Akira YAMAGUCHI
Author(s):  
K. Cowden ◽  
B. Giammara ◽  
T. Devine ◽  
J. Hanker

Plaster of Paris (calcium sulfate hemihydrate, CaSO4. ½ H2O) has been used as a biomedical implant material since 1892. One of the primary limiting factors of these implants is their mechanical properties. These materials have low compressive and tensile strengths when compared to normal bone. These are important limiting factors where large biomechanical forces exist. Previous work has suggested that sterilization techniques could affect the implant’s strength. A study of plaster of Paris implant mechanical and physical properties to find optimum sterilization techniques therefore, could lead to a significant increase in their application and promise for future use as hard tissue prosthetic materials.USG Medical Grade Calcium Sulfate Hemihydrate Types A, A-1 and B, were sterilized by dry heat and by gamma radiation. Types A and B were additionally sterilized with and without the setting agent potassium sulfate (K2SO4). The plaster mixtures were then moistened with a minimum amount of water and formed into disks (.339 in. diameter x .053 in. deep) in polyethylene molds with a microspatula. After drying, the disks were fractured with a Stokes Hardness Tester. The compressive strengths of the disks were obtained directly from the hardness tester. Values for the maximum tensile strengths σo were then calculated: where (P = applied compression, D = disk diameter, and t = disk thickness). Plaster disks (types A and B) that contained no setting agent showed a significant loss in strength with either dry heat or gamma radiation sterilization. Those that contained potassium sulfate (K2SO4) did not show a significant loss in strength with either sterilization technique. In all comparisons (with and without K2SO4 and with either dry heat or gamma radiation sterilization) the type B plaster had higher compressive and tensile strengths than that of the type A plaster. The type A-1 plaster however, which is specially modified for accelerated setting, was comparable to that of type B with K2SO4 in both compressive and tensile strength (Table 1).


1977 ◽  
Vol 12 (1) ◽  
pp. 121-134 ◽  
Author(s):  
G.H. Neilsen ◽  
A.F. Mackenzie

Abstract Seven agricultural watersheds in southwestern Quebec and southeastern Ontario, ranging in area from 2,000 to 20,000 hectares, were monitored systematically during 1973–75 for soluble inorganic nitrogen, total soluble phosphorus, calcium, magnesium, potassium, sulfate-sulfur, chemical oxidation demand, discharge, suspended sediment concentration, sediment Kjeldahl nitrogen, Bray extractable phosphorus, and ammonium acetate extractable calcium, magnesium and potassium. For 1974–75, annual Kg/ha, loss rates were calculated for the soluble and sediment associated nutrients. Losses varied with nutrient and watershed, with volume of runoff being an important control of nutrient loss variation. Significant amounts of SO4−S in precipitation were suggested by an average watershed soluble N:P:S loss ratio of 10:1:92. Sediment nutrient losses were especially important for N and P, comprising over 40% of their total loss. The importance of spring snow-melt runoff was demonstrated by the high proportion of all nutrients lost at this time. Correlations of nutrient loss, land use and soils suggested that certain land uses resulted in increased stream nutrient losses while increased watershed area of soils with a high surface runoff potential was particularly conducive to increased soluble nutrient and sediment losses.


1993 ◽  
Vol 58 (8) ◽  
pp. 1848-1854 ◽  
Author(s):  
Miroslav Karel ◽  
Jaroslav Nývlt

The kinetics of the crystallization of potassium sulfate has been determined using the MSMPR technique. Values of the nucleation and crystal growth rates evaluated from the experimental data are compared with the corresponding literature data.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Lichun Ma ◽  
Kai Wang ◽  
Yu Zhang ◽  
Qingfeng Tang ◽  
Hui Yan

AbstractThe Quaternary Lop Nor playa is the largest production base of potassium sulfate in the world. It has a mining history of more than 10 years, and its share in the Chinese potassium sulfate market is about 50% to-date. In this basin, the high-salinity potassium-rich brines are mainly contained in Middle Pleistocene–Holocene glauberite strata. Based on the monitoring of the underground brine table and geochemical analysis, this study reveals variations in the underground brine table and potassium-bearing grade before and after large-scale mining in the Lop Nor potash deposit. The results showed that the underground brine table and potassium sulfate grade decreased by varying degrees over sub-mineral areas after large-scale mining. The underground brine table declined by 8.5 m, on average, in the Luobei depression, by 6.4 m in the Tenglong platform and by 1.9 m in the Xinqing platform. However, the potassium-bearing grade showed the different trend. The Tenglong platform had the largest decline with average decreases in layers W1, W2 and W3 of 18.2%, 13.0% and 24.8%, respectively. In the Xinqing platform, the average decrease in layersW2 and W3 were 17.4% and 16.0% respectively. The Luobei depression decreases were relatively small (W1, W2 and W3 decreased 4.3%, 4.2% and 3.1%, respectively). This research provides a theoretical basis for the rational development and sustainable use of the potassium-rich brines in the Lop Nor basin.


Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1078
Author(s):  
Christopher Brock ◽  
Meike Oltmanns ◽  
Christoph Matthes ◽  
Ben Schmehe ◽  
Harald Schaaf ◽  
...  

Mixed-crop-livestock farms offer the best conditions for sustainable nutrient management in organic farming. However, if stocking rates are too low, sustainability might be threatened. Therefore, we studied the development of soil organic matter and nutrients as well as crop yields over the first course of a new long-term field experiment with a mimicked cattle stocking rate of 0.6 LU ha−1, which is the actual average stocking rate for organic farms in Germany. In the experiment, we tested the effects of additional compost application to improve organic matter supply to soils, and further, potassium sulfate fertilization for an improved nutrition of fodder legumes. Compost was made from internal resources of the farm (woody material from hedge-cutting). Soil organic matter and nutrient stocks decreased in the control treatment, even though yield levels, and thus nutrient exports, were comparably low. With compost application, soil organic matter and nutrient exports could be compensated for. At the same time, the yields increased but stayed at a moderate level. Potassium sulfate fertilization further improved N yields. We conclude that compost from internal resources is a viable solution to facilitate sustainable organic crop production at low stocking rates. However, we are aware that this option does not solve the basic problem of open nutrient cycles on the farm gate level.


Soil Science ◽  
1941 ◽  
Vol 51 (1) ◽  
pp. 73 ◽  
Author(s):  
W. H. MACINTIRE ◽  
W. M. SHAW ◽  
BROOKS ROBINSON
Keyword(s):  

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