scholarly journals Effect of Energy Density on the Microstructure and Properties of the CrFeCoNiNb High Entropy Cladded Layer

Author(s):  
Pengfang Song ◽  
Fulin Jiang ◽  
Yuling Wang ◽  
Fazhan Yang ◽  
Zhaolin Zhong

Abstract A synergistic combination of mechanical properties and corrosion resistance property is desired for most ocean engineering structural applications. In this paper, we prepared high entropy alloy (HEA) cladded layer of composition CrFeCoNiNb (atomic%). We aim to attain a balance between the mechanical property and the corrosion resistance property through adjusting the energy density. The prepared CrFeCoNiNb cladded layer with the energy density of 116.7J/mm2 exhibited excellent mechanical properties and high corrosion resistance. The improved mechanical properties are attributed to the fine grain strengthening, solid solution strengthening and dispersion strengthening. Whereas the excellent corrosion resistance is due to the fine grained BCC single phase structure and the compact passivation film. The variation of the mechanical properties and corrosion resistance with different energy densities are attribute to the phase composition. The diffraction peak area of the main phase of BCC decreases first and then increases with the increase of energy density, which is the main reason that the hardness of the cladded layer follows the similar trend. The outcome of our research suggests that the prepared CrFeCoNiNb cladded layer could be explored to realise surface strengthening of load-bearing parts in marine engineering equipment.

Metals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1012 ◽  
Author(s):  
Feng Shang ◽  
Xiaoqiu Chen ◽  
Zhiyong Wang ◽  
Zuchun Ji ◽  
Fei Ming ◽  
...  

UNS S32707 hyper-duplex stainless steel (HDSS) parts with complex shapes for ocean engineering were prepared by selective laser melting (SLM) process. In the process of SLM, the balance between austenite and ferrite was undermined due to the high melting temperature and rapid cooling rate, resulting in poor ductility and toughness. The solution annealing was carried out with various temperatures (1050–1200 °C) for one hour at a time. The evolution of microstructures, mechanical properties, and corrosion resistance of UNS S32707 samples prepared by SLM was comprehensively investigated. The results indicate that a decrease in nitrogen content during the SLM process reduced the content of austenite, and a nearly balanced microstructure was obtained after appropriate solution annealing. The ratio between ferrite and austenite was approximately 59.5:40.5. The samples with solution treated at 1150 °C and 1100 °C exhibited better comprehensive mechanical properties and pitting resistance, respectively.


2019 ◽  
Vol 25 (3) ◽  
pp. 259-264
Author(s):  
Shaofeng YANG ◽  
Yan ZHANG ◽  
Xing YAN ◽  
Hang ZHOU

Al0.4FeCrCo1.5NiTi0.3 high-entropy alloy (HEA) was prepared by mechanical alloying (MA) and spark plasma sintering (SPS), which were evaluated in this study by XRD and TEM. After SPS, the bulk alloy exhibited a structure with a dominant fcc phase, a minor volume fraction of bcc phase, and the formation of TiAl3 intermetallic compound. Deformation twinning was observed in the fcc phase in the bulk HEA. The latter had a compressive strength, strain and Vickers hardness of 2225 ± 15 MPa, 17.52 ± 0.50 % and 515 ± 16 HV, respectively. The corrosion resistance studies indicated that Al0.4FeCrCo1.5NiTi0.3 with ultra-fine grained micro-structure was easier to passivate and possessed excellent corrosion resistance. DOI: http://dx.doi.org/10.5755/j01.ms.25.3.19452


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