STUDY OF THE COPPER, MANGANESE AND IRON SELECTIVE EXTRACTION REGULARITIES FROM TECHNOGENIC HYDROMINERAL DEPOSITS BY THE NEUTRALIZATION METHOD

2021 ◽  
Vol 27 (6) ◽  
pp. 15-22
Author(s):  
N. Medyanik ◽  
◽  
O. Mishurina ◽  
E. Mullina ◽  
◽  
...  
Keyword(s):  
Heavy Metal ◽  
Research Methods ◽  
Metal Cations ◽  
Selective Extraction ◽  
Mine Waters ◽  
Ph Values ◽  
Copper Manganese ◽  
Copper Pyrite ◽  
Multicomponent Solutions ◽  
Technical Solutions

The article presents a factor analysis of the processes of selective concentration of metals by the neutralization method. In this work, the chemistry of the selective extraction process of heavy metal cations from aqueous solutions by the neutralization method is experimentally studied. The mutual influence of the components of matrix solutions on the index of the extraction degree of Cu (II), Mn (II) and iron ions in mono- and multicomponent model systems has been studied. Based on the results obtained, it is established that the use of the neutralization method for the staged isolation and concentration of valuable components from technical solutions in the form of the target product is possible only in a combination of a set of methods: flotation, flocculation and coagulation. It was found that in the process of neutralization of multicomponent solutions, quantitative extraction from technical solutions is possible at the following pH values: Fe (III)– 4.0, Fe (II) – 6.3, Cu (II) – 6.4, Mn (II) – 9.9. It is indicated that a decrease in the initial concentration of Fe3 + ions in a solution leads to an increase in the pH values of the beginning of its precipitation in the form of a dispersed phase of ferric hydroxide. The rational parameters of the pH values of the studied aqueous systems, at which the selective separation and concentration of the main components of technological solutions with a priority content of Fe (III), Fe (II), Cu (II) and Mn (II) ions is possible, have been experimentally substantiated. The extraction of manganese cations, using the method of neutralization from the studied multicomponent solutions, is impossible for the coprecipitation of all designated metal cations. Therefore, based on the high reductive activity of the divalent form of manganese, it is advisable to selectively concentrate it using the method of redox electrodeposition, the products of which are sparingly soluble stable compounds of trivalent and tetravalent manganese. The relevance of research lies in the need to process acidic mine waters of mining enterprises of the copper-pyrite complex in order to significantly expand the raw material base of mining enterprises, as well as to improve the ecological situation of the city-forming mining enterprises of the South Urals. The purpose of the study is to study the material composition of mine waters and develop a technology for the selective extraction of cationic forms of copper, manganese and iron. The object of research is technical mono- and multicomponent solutions with a high content of metal cations: Cu2+, Mn2+, Fe2+ and Fe3+. The subject is the possibility of using the neutralization method for the selective processing of hydromineral resources of mining enterprises of the copper-pyrite complex. Material and research methods. General scientific and special research methods have been used during the work. In the implementation of the experiments, a complex of physicochemical methods of analysis has been used: thermodynamic analysis, UV spectroscopy, chemical and assay analyzes. To determine the content of heavy metal ions, adapted methods of photometric analysis have been used: for copper (II) - with pyramine epsilon, for total iron – with o-phenanthroline, for manganese (II) ions – with their preliminary oxidation to permanganate ions

Polymers contamination by heavy metal compounds

2002 ◽  
Vol 56 (11) ◽  
pp. 483-488
Author(s):  
Sasa Jovanic ◽  
Dragoslav Stoiljkovic ◽  
Ivanka Popovic
Keyword(s):  
Heavy Metal ◽  
Aqueous Medium ◽  
Metal Compound ◽  
Medium Temperature ◽  
Metal Compounds ◽  
Metal Type ◽  
Copper Manganese ◽  
Increasing Temperature

The contamination of important synthetic (surface unmodified) polymers by various heavy metal compounds (such as copper, manganese and lead) in aqueous medium was investigated in this study. The influence of the pH of the aqueous medium, temperature and metal type on contamination was investigated during a 10 day period. It was found that increasing pH contributed to higher polymer contamination (at higher pH 100 times for copper and up to 400 times for lead), as well as contact with easily penetrable substances. Increasing temperature decreased contamination by the metal compound for PELD and PET which was not the case for PEHD and PR.

scholarly journals Novel phthalonitrile derivatives as potential compounds for extraction and complexation of metal cations

2016 ◽  
Vol 11 (10) ◽  
pp. 3870-3874
Author(s):  
Lassaad Baklouti
Keyword(s):  
Heavy Metal ◽  
Transition Metal ◽  
Metal Cations ◽  
Uv Spectra ◽  
Transition Metal Cations ◽  
Binding Properties ◽  
Heavy Metal Cations ◽  
Uv Visible ◽  
The Stability ◽  
Ligand Species

The synthesis and the binding properties of novel phthalonitrile derivatives 1-3 towards metal cations have been described in this paper. The complexation and extraction of some transition and heavy metal cations have been followed by UV-visible spectrophotometry absorption in methanol. The conductivity studies have been used in order to confirm complex’s stoichiometries. The treatment of UV spectra by digital program showed the formation of ML (with ML2 in some cases) (M=metal, L=ligand) species. Beyond the discussion of the stability profiles of complexes particular attention is paid to the selectivity towards Cu2+ in the 1st sequence of transition metal cations and towards Hg2+ in the sequence of heavy metal cations.

scholarly journals Pengaruh Lama Waktu Osmosis Terhadap Kandungan Vitamin C dalam Minuman Sari buah Stroberi dan Apel

2019 ◽  
Vol 4 (1) ◽  
pp. 19-22
Author(s):  
Vika Ayu Devianti ◽  
Anisa Rizki Amalia
Keyword(s):  
Heavy Metal ◽  
Vitamin C ◽  
Human Body ◽  
Apple Juice ◽  
Fruit Juice ◽  
Metal Cations ◽  
Oxygen Solubility ◽  
Heavy Metal Cations ◽  
Sugar Addition ◽  
Strawberry Juice

ABSTRAKVitamin C berperan penting dalam mempertahankan daya tahan tubuh. Vitamin C mudah teroksidasi dan tidakstabil dalam bentuk larutan. Vitamin C banyak ditemukan dalam buah – buahan, diantaranya adalah apel danstroberi. Apel dan stroberi ini sering diolah dalam bentuk minuman sari buah melalui proses ekstraksi osmosis. Tujuan penelitian ini adalah untuk mengetahui pengaruh lama waktu osmosis (30 dan 60 menit) dan penambahan gula 10% terhadap kandungan vitamin C dalam minuman sari buah apel dan stroberi. Penambahan gula 10% mampu memperkecil penurunan kadar vitamin C dalam minuman sari buah. Penurunan kadar vitamin C pada sampel sari buah stroberi tanpa penambahan gula adalah 18,7% pada menit ke-30 dan 37,5% pada menit ke-60, sedangkan penambahan gula 10% mengalami penurunan sebesar 2,7% pada menit ke-30 dan 7,9% pada menit ke-60. Penurunan kadar vitamin C pada sampel sari buah apel tanpa penambahan gula adalah 24,2% pada menitke-30 dan 41,6% pada menit ke-60, sedangkan penambahan gula 10% mengalami penurunan sebesar 10,6% pada menit ke-30 dan 21,4% pada menit ke-60.Kata kunci: Vitamin C, sukrosa, minuman sari buah, apel, strawberry, osmosis ABSTRACTVitamin C plays an important in human body. Vitamin C is easily degraded by heat, light, oxygen, and heavy metal cations. Vitamin C mostly found in fruits, such as strawberry and apple. Generally strawberry and apple are processed into fruit juice by adding sugar using osmosis extraction. The objective of this research is to findout the effect of osmosis time and sugar addition towards the vitamin C level in strawberry and apple juice. The result showed that sugar addition can affect the vitamin C level in strawberry and apple juice. Sugars can decrease the oxygen solubility causing less oxygen availability for oxidation of vitamin C. The diminish of vitamin C content in apple juice with sugar addition were 10,6% and 21,4% for 30 and 60 minutes of osmosis time; while strawberry juice with sugar addition able to lowering vitamin C level until 18,7% and 37,5% for 30 and 60 minutes of osmosis time.Keywords: Vitamin C, sucrose, apple juice, strawberry juice, osmosis,

STALE TAILINGS OF COPPER-CRUSTED ORES FLOTATION WITH THE POSSIBILITY OF GOLD AND SILVER SELECTIVE EXTRACTION: RESOURCE POTENTIAL ANALYSIS

2021 ◽  
Vol 27 (6) ◽  
pp. 31-39
Author(s):  
N. Medyanik ◽  
◽  
E. Leontieva ◽  
O. Mishurina ◽  
E. Mullina ◽  
...  
Keyword(s):  
Elemental Composition ◽  
Phase Analysis ◽  
Mineral Composition ◽  
Selective Extraction ◽  
Material Composition ◽  
Raw Material ◽  
Resource Potential ◽  
Flotation Tailings ◽  
Copper Pyrite ◽  
Pyrite Ores

The article analyzes the possibility and efficiency of processing stale tailings of flotation plants of the copper pyrite complex. The resource potential, material composition and technological capabilities of processing a number of technogenic objects are considered. The interrelation and influence of mineralogical and technological factors on the choice of tailings processing technology are analyzed. The results of chemical, mineral and phase analysis of stale flotation tailings of the studied pyrite ores are presented. According to the complex studies’ results, it is established that the stale flotation tailings of copper pyrite ores belong to a refractory type of geo-resources due to the high content of pyrite and low, at the level of ppm, gold and silver content, which are present mainly in the “resistant” minerals - chalcogenides, sulphides, their intergrowths. The article presents a factor analysis and conditions for the elemental composition of tailings formation: mineralogical, technological and environmental. The territorial accessibility and technological capability of the investigated technogenic formations are analyzed. In the course of experimental studies, the elemental composition of stale tailings has been revealed - the main components of which are: iron, sulfur, silicon and aluminum. According to the results of X-ray phase analysis, it has been found that the main ore mineral of the tailings is pyrite. At the same time, it is noted that the main share of gold in the stale flotation tailings is presented in the form of sulphides in the form of finely dispersed and isomorphic inclusions. The heterogeneous morphometric and mineral composition of sulphide aggregates, their difficult opening and high dispersion characterize stale tailings as a raw material that is difficult to float. The revealed features of the material composition of stale tails indicate the impossibility of extracting valuable components (gold and silver) from this resource using existing traditional technologies. It has been proved that it is possible to effectively extract precious metals from this category of raw materials only after their deep opening by chemical processing. The relevance of the research lies in the need to process gold-containing man-made waste in order to significantly expand the raw material base of mining enterprises, as well as to improve the ecological situation of the city-forming mining enterprises of the South Urals. The aim of the research is to study the material composition of stale tailings and develop a technology for selective extraction of gold and silver. The object of research is the stale flotation tailings of copper-pyrite enterprises of the Southern Urals. The subject is the mineral composition, the content of useful components of lying tailings and the technology of gold and silver selective extraction from them. Material and research methods. During the experiments, a set of physicochemical and chemical methods of analysis has been used: thermodynamic analysis, synchronous thermal analysis using a combined thermal analyzer of the Netzsch STA 449 F3 Jupiter brand, UV spectroscopy with an automated data processing system), qualitative chemical and assay analyzes

scholarly journals Adsorptive Behavior of an Activated Carbon for Bisphenol A Removal in Single and Binary (Bisphenol A—Heavy Metal) Solutions

Water ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 2150 ◽  
Author(s):  
M.A. Martín-Lara ◽  
M. Calero ◽  
A. Ronda ◽  
I. Iáñez-Rodríguez ◽  
C. Escudero
Keyword(s):  
Heavy Metal ◽  
Activated Carbon ◽  
Bisphenol A ◽  
Contact Time ◽  
Water Solution ◽  
Metal Cations ◽  
Maximum Adsorption Capacity ◽  
Batch Mode ◽  
Heavy Metal Cations ◽  
Adsorptive Behavior

Bisphenol A (BPA) is an extensively produced and consumed chemical in the world. Due to its widespread use, contamination by this pollutant has increased in recent years, reaching a critical environmental point. This work investigates the feasibility of bisphenol A adsorption from industrial wastewater solutions, testing the reduction of bisphenol A in synthetic solutions by a commercial activated carbon, AC-40, in batch mode. Besides, mixtures of bisphenol A and different heavy metal cations were also studied. So far, no works have reported a complete study about bisphenol A removal by this activated carbon including the use of this material to remove BPA in the presence of metal cations. First, adsorption experiments were performed in batch changing pH, dose of adsorbent, initial bisphenol A concentration and contact time. Results showed greater retention of bisphenol A by increasing the acidity of the medium. Further, the percentage of bisphenol A adsorbed increased with increasing contact time. The selected conditions for the rest of the experiments were pH 5 and a contact time of 48 h. In addition, an increase in retention of bisphenol A when the dose of adsorbent increased was observed. Then, specific experiments were carried out to define the kinetics and the adsorption isotherm. Equilibrium data were adequately fitted to a Langmuir isotherm and the kinetics data fitted well to the pseudo-second-order model. The maximum adsorption capacity provided by Langmuir model was 94.34 mg/g. Finally, the effect of the presence of other heavy metals in water solution on the adsorption of bisphenol A was analyzed. Binary tests revealed competition between the adsorbates and a significant selectivity toward bisphenol A. Finally, the study of the adsorption performance in three consecutive adsorption–desorption cycles showed efficiencies higher than 90% in all cycles, indicating that the activated carbon has good reusability.

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