scholarly journals CHARACTERIZATION OF PROPERTIES OF PVDF/POLY(DIMETHYLSILOXANE) COMPOSITES SEPARATOR WITH BLENDING MEMBRANE METHOD

2018 ◽  
Vol 3 (2) ◽  
pp. 236
Author(s):  
Devi Eka Septiyani Arifin

<span lang="IN">The aims of this research to make</span><span> poly(vinylidene fluoride) (PVDF) and poly(dimetilsiloksan) (PDMS) </span><span lang="IN">composites </span><span>separator with blending membrane method. </span><span lang="IN">Synthesized of<span>  </span></span><span>PVDF/PDMS</span><span lang="IN"> composites separator </span><span lang="IN">used various ratio </span><span>were 10/0, 9/1, 8/2, and 7/3. The purpose of increasing concentration of PDMS</span><span lang="IN">/</span><span>PVDF to improve the performance of the composites separator which includes </span><span lang="IN">a</span><span> dimensions of porosity, </span><span lang="IN">a </span><span>pore density, and </span><span lang="IN">a </span><span>electrical conductivity. Based on crystallographic analysis using XRD, the </span><span lang="IN">increasing</span><span> concentration </span><span lang="IN">number </span><span>of PDMS </span><span lang="IN">to make compositess was influence</span><span> decreas</span><span lang="IN">ing of</span><span> crystallinity </span><span lang="IN">until </span><span>29.26% in </span><span lang="IN">a </span><span>ratio 7/3</span><span lang="IN">.</span><span lang="IN">The analysing of</span><span> FTIR </span><span lang="IN">have sound the wavenumber of each phase can distinguish, which </span><span>this material includes in the criteria </span><span lang="IN">of the </span><span>composites</span><span lang="IN">. The result using XRD and FTIR to material PVDF/PDMS composites in all of the ratio constituens have shown the identification of the structure </span><span>α-</span><span lang="IN">phase of PVDF. The increase of concentration number PDMS influenced decreasing of pore dimension and increasing of pore density </span><span>with the small </span><span lang="IN">of </span><span>pore dimension 1.71 µm and pore density 4.07x10<sup>11</sup> count/m<sup>2 </sup>inthe ratio 7/3. In </span><span lang="IN">a</span><span> ratio 7/3, the value of the electrical conductivity w</span><span lang="IN">as </span><span>3.45x10<sup>-4</sup></span><span>S/cm and the resistance </span><span lang="IN">i</span><span>ncrease</span><span lang="IN">d</span><span> up to 80%.</span>

2020 ◽  
Vol 394 (1) ◽  
pp. 2000136
Author(s):  
Bianca B. dos Santos ◽  
Victor J. R. R. Pita ◽  
Marysilvia F. da Costa

2010 ◽  
Vol 152-153 ◽  
pp. 44-50 ◽  
Author(s):  
Gui Bao Guo ◽  
Er Ding Han ◽  
Sheng Li An

A new method based on a solution graft technique was used to prepare poly (vinylidene fluoride) grafted polystyrene sulfonated acid (PVDF-g-PSSA) proton exchange membrane. Polystyrene is grafted into PVDF modified by plain sodium silicate (Na4SiO4). There is a linear relationship between the degree of grafting and the content of Na4SiO4. Fourier transform infrared spectroscopy is used to characterize changes of the membrane's microstructures after grafting and sulfonation. The morphology of the membrane's microstructures after grafting and sulfonation is studied by scanning electrolytic microscope (SEM). The effect of plain sodium silicate (Na4SiO4) concentration and relative humidity on the conductivity of the electrolyte was investigated by the impedance at room temperature. The results show that the styrene has been grafted into PVDF. The conductivity of PVDF-g-PSSA electrolyte doped 10% plain sodium silicate (Na4SiO4) is 0.016 S/cm at room temperature. The conductivity of the electrolyte changes slightly at a relative humidity range of 20%-70%. The weightlessness of PVDF-g-PSSA electrolyte heated to 40°C was less than 2%, which indicated that water capacity was good.


2008 ◽  
Vol 1071 ◽  
Author(s):  
Koji Aizawa

AbstractCharacterization of 700-nm-thick poly(vinylidene fluoride/trifluoroethylene) [P(VDF/TrFE)]/TiO2/Al-doped ZnO (AZO) structures on a glass substrate were investigated. In this study, the sputtered TiO2 films as insulator were used for the reduction of leakage current. The leakage current density of the fabricated Pt/P(VDF/TrFE)/AZO and Pt/P(VDF/TrFE)/170-nm-thick TiO2/AZO structures were approximately 8.7 and 3.9 nA/cm2 at the applied voltage of 10 V, respectively. In the polarization vs. voltage characteristics, the fabricated Pt/P(VDF/TrFE)/TiO2/AZO structures showed hysteresis loops caused by ferroelectric polarization. The remnant polarization (2Pr) and coercive voltage (2Vc) measured from a saturated hysteresis loop at the frequency of 50 Hz were approximately 12 μC/cm2 and 105 V, respectively. These results suggest that the insertion of TiO2 film is available for reducing the gate leakage current without changing the ferroelectric properties.


Desalination ◽  
2014 ◽  
Vol 336 ◽  
pp. 1-7 ◽  
Author(s):  
Yan Jin ◽  
Ying Hua ◽  
Pin Zhang ◽  
Yanbin Yun ◽  
Panyue Zhang ◽  
...  

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