scholarly journals Study on the hydro-chemistry process after mixing between water and rocks

2018 ◽  
Vol 54 (2) ◽  
pp. 104-114
Author(s):  
Xiuyan Jing ◽  
Hongbin Yang ◽  
Na Wang

Abstract The chemical evolution of groundwater has received close attention from hydro-geologists. Northwest China largely consists of arid and semi-arid regions, where surface water and groundwater frequently exchange with each other, and where the mixing and water–rock interactions significantly affect the direction of water quality evolution. Based on experimental simulation, this paper investigates the interactions among the Yellow River water, groundwater and rocks in Yinchuan. The study found that when groundwater is mixed with the Yellow River water, the Yellow River water has a certain dilution effect on the hydro-chemical composition of groundwater; however, this effect is not simply diluted by proportion for no reaction between irons, but a portion of calcium, sulfur, and carbonate form precipitates. After mixing of the Yellow River water, groundwater and rocks, the pH increased, and the carbon dioxide system reached equilibrium again. In addition, CO32− was produced. While Na+ increase was mainly due to dissolution, SO42− decrease was because of precipitation. The precipitation or dissolution of Ca2+, Mg2+, and CO32− mainly depended on the mixing ratio between groundwater and river water, which suggested the reversible behavior of the dissolution-precipitation of carbonate minerals.

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 632
Author(s):  
Weinan Lu ◽  
Wenxin Liu ◽  
Mengyang Hou ◽  
Yuanjie Deng ◽  
Yue Deng ◽  
...  

Improving agricultural water use efficiency (AWUE) is an important way to solve the shortage of water resources in arid and semi-arid regions. This study used the Super-DEA (data envelopment analysis) to measure the AWUE of 52 cities in Northwest China from 2000 to 2018. Based on spatial and temporal perspectives, it applied Exploratory Spatial Data Analysis (ESDA) to explore the dynamic evolution and regional differences of AWUE. A spatial econometric model was then used to analyze the main factors that influence the AWUE in Northwest China. The results showed firstly that the overall AWUE in Northwest China from 2000 to 2018 presented a steady upward trend. However, only a few cities achieved effective agricultural water usage by 2018, and the differences among cities were obvious. Secondly, AWUE showed an obvious spatial autocorrelation in Northwest China and showed significant high–high and low–low agglomeration characteristics. Thirdly, economic growth, urbanization development, and effective irrigation have significant, positive effects on AWUE, while per capita water resource has a significant, negative influence. Finally, when improving the AWUE in arid and semi-arid regions, plans should be formulated according to local conditions. The results of this study can provide new ideas on the study of AWUE in arid and semi-arid regions and provide references for the formulation of regional agricultural water resource utilization policies as well.


2014 ◽  
Vol 18 (1) ◽  
pp. 27-38 ◽  
Author(s):  
Peiyue Li ◽  
Jianhua Wu ◽  
Hui Qian

<p class="MsoNormal" style="line-height: 200%;">Statistical analyses, a Piper diagram, the saturation index and the correlations of chemical parameters were used to reveal the hydrogeochemistry and hydrogeochemical evolution of shallow groundwater in the southern part of the Zhongwei section of the Yellow River alluvial plain. The water quality for agricultural and domestic uses was also assessed in the study. The results suggest that the shallow groundwater in the study area is fresh to moderately mineralized water. Higher Ca<sup>2+</sup> and HCO<sub>3</sub><sup>-</sup> are observed in the less mineralized water, whereas Na<sup>+</sup> and SO<sub>4</sub><sup>2-</sup> are common ions in the highly mineralized water. The major hydrochemical facies for groundwater with total dissolved solids (TDS) &lt;1 g/L are HCO<sub>3</sub>-Ca·Mg and HCO<sub>3</sub>-Ca·Na·Mg, and for groundwater with TDS &gt; 1 g/L, SO<sub>4</sub>·Cl-Na and SO<sub>4</sub>·Cl-Na·Mg·Ca are the predominant hydrochemical types. The main reactions in the groundwater system are the dissolution/precipitation of gypsum, fluorite, halite, calcite and dolomite. Cation exchange is also important in controlling the groundwater chemistry. The water samples assessed in the paper are of acceptable quality for agricultural use, but most of them are not fit for direct human consumption (drinking). TDS, total hardness (TH), Cl<sup>-</sup> and SO<sub>4</sub><sup>2-</sup> are the main indices that result in the poor drinking water quality.</p><p class="MsoNormal" style="line-height: 200%;"> </p><p class="MsoNormal" style="line-height: 200%;"><strong>Resumen</strong></p><p>Análisis estadísticos, un diagrama de Piper, el índice de saturación y la correlación de los parámetros químicos fueron utilizados para revelar la hidrogeoquímica y la evolución hidrogeoquímica de las aguas subterráneas poco profundas en la parte sur de la sección Zhongwei en la planicie aluvial del río Amarillo. La calidad del agua para el uso doméstico y agrícola también fue evaluada en este estudio. Los resultados sugieren que las aguas subterráneas poco profundas en el área de estudio son entre frescas y moderadamente mineralizadas. Un índice mayor de Ca2+ y HCO3- se observó en las aguas menos mineralizadas, mientras que Na+ y SO42- son iones comunes en las aguas altamente mineralizadas. Los perfiles hidroquímicos predominantes para las aguas subterráneas con Total de Sólidos Disueltos (TDS) &lt;1 g/L son HCO3-Ca·Mg y HCO3-Ca·Na·Mg, y para las aguas subterráneas con TDS &gt;1 g/L, SO4·Cl-Na y SO4·Cl-Na·Mg·Ca. Las mayores reacciones en el sistema de aguas subterráneas son la disolución/ precipitación de yeso, fluorita, halita, calcita y dolomita. El intercambio de cationes también es importante en el control de la química de las aguas subterráneas. Las muestras de agua evaluadas en este manuscrito son de calidad aceptable para el uso agrícola, pero la mayoría no son aptas para el consumo humano. El índice TDS, la dureza total del agua (TH), Cl- y SO42- son las razones principales que influyen en la baja calidad de esta agua.</p>


Author(s):  
Hao Han ◽  
Jingming Hou ◽  
Rengui Jiang ◽  
Jiahui Gong ◽  
Ganggang Bai ◽  
...  

Abstract Precipitation variations mostly affect the water resource planning in semi-arid regions of northwest China. The objective of this study is to quantitatively explore the spatial and temporal variations of precipitation in different time scales in Xi'an city area. The Mann–Kendall test and wavelet analysis methods were applied to analyze the precipitation variability. In terms of temporal variation of precipitation, the results indicated that the annual precipitation exhibited a significant decreasing trend during 1951–2018. Except for summer precipitation representing a slightly increasing trend, the other seasonal precipitations had a similar decreasing trend to annual precipitation throughout 1951–2018. The monthly precipitation had different change trends, showing the precipitation from June to September could account for 58.4% of the total annual precipitation. In addition, it was clear that annual precipitation had a significant periodic change, with the periods of 6, 13, 19, and 27 years. For the spatial variation of precipitation during 1961–2018, the results showed that annual and seasonal precipitation exhibited obvious spatial differences, indicating an increasing spatial trend from north to south. Thus, understanding the precipitation variation in Xi'an city can provide a theoretical foundation of future water resources management for other cities in semi-arid regions of northwest China.


2020 ◽  
Vol 12 (5) ◽  
pp. 837-853
Author(s):  
Jian Feng ◽  
Lingdi Zhao ◽  
Yibo Zhang ◽  
Lingxiao Sun ◽  
Xiang Yu ◽  
...  

2015 ◽  
Vol 12 (4) ◽  
pp. 921-932 ◽  
Author(s):  
L. Ran ◽  
X. X. Lu ◽  
J. E. Richey ◽  
H. Sun ◽  
J. Han ◽  
...  

Abstract. Carbon transport in river systems is an important component of the global carbon cycle. Most rivers of the world act as atmospheric CO2 sources due to high riverine CO2 partial pressure (pCO2). By determining the pCO2 from alkalinity and pH, we investigated its spatial and temporal variation in the Yellow River watershed using historical water chemistry records (1950s–1984) and recent sampling along the mainstem (2011–2012). Except the headwater region where the pCO2 was lower than the atmospheric equilibrium (i.e. 380 μatm), river waters in the remaining watershed were supersaturated with CO2. The average pCO2 for the watershed was estimated at 2810 ± 1985 μatm, which is 7-fold the atmospheric equilibrium. As a result of severe soil erosion and dry climate, waters from the Loess Plateau in the middle reaches had higher pCO2 than that from the upper and lower reaches. From a seasonal perspective, the pCO2 varied from about 200 μatm to > 30 000 μatm with higher pCO2 usually occurring in the dry season and lower pCO2 in the wet season (at 73% of the sampling sites), suggesting the dilution effect of water. While the pCO2 responded exponentially to total suspended solids (TSS) export when the TSS concentration was less than 100 kg m−3, it decreased slightly and remained stable if the TSS concentration exceeded 100 kg m−3. This stable pCO2 is largely due to gully erosion that mobilizes subsoils characterized by low organic carbon for decomposition. In addition, human activities have changed the pCO2 dynamics. Particularly, flow regulation by dams can diversely affect the temporal changes of pCO2, depending on the physiochemical properties of the regulated waters and adopted operation scheme. Given the high pCO2 in the Yellow River waters, large potential for CO2 evasion is expected and warrants further investigation.


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