Removal of cadmium from dilute solutions by flotation

1995 ◽  
Vol 31 (3-4) ◽  
pp. 315-326 ◽  
Author(s):  
Anastasios I. Zouboulis ◽  
Konstantine A. Matis
Keyword(s):  
Sodium Dodecyl ◽  
Toxic Metal ◽  
Dilute Solutions ◽  
Water And Wastewater Treatment ◽  
Dissolved Air Flotation ◽  
Bubble Generation ◽  
Flotation Technique ◽  
Air Flotation ◽  
Ph Range ◽  
Dissolved Air

Cadmium constitutes a priority pollutant existing in waste streams from metal plating and various other industries. The removal of this toxic metal employing the dissolved air flotation technique was investigated in laboratory batch experiments; the mechanism of precipitate flotation as the respective hydroxide was followed. Main examined parameters include: recycle ratio, pH of the solution, concentrations of added surfactant (sodium dodecyl sulphate), frother (ethanol) and cadmium. Promising results have been obtained, at the pH range between 10 and 11 approximately, showing the significance of flotation as a separation process in water and wastewater treatment for dilute solutions (around 10 mg/l of metal). Under the optimum conditions removal of cadmium was near to 100%, while the remaining concentration in the solution after flotation was less than 0.10 mg/l. A comparison was also attempted between two flotation techniques applying different bubble generation methods, i.e. dissolved air and dispersed air flotation. These experiments run in parallel and under the same conditions.

Effect of pressure on bubble size in dissolved air flotation

2002 ◽  
Vol 2 (5-6) ◽  
pp. 41-46 ◽  
Author(s):  
M. Han ◽  
Y. Park ◽  
J. Lee ◽  
J. Shim
Keyword(s):  
Bubble Size ◽  
Critical Pressure ◽  
Theoretical Work ◽  
Particle Sizes ◽  
Water And Wastewater Treatment ◽  
Dissolved Air Flotation ◽  
Recent Theoretical Work ◽  
Water And Wastewater ◽  
Air Flotation ◽  
Dissolved Air

Although dissolved air flotation (DAF) has been successfully adopted for water and wastewater treatment, the fundamental characteristics of the process have not been fully investigated. According to recent theoretical work on DAF, bubble size is one of the most important factors that affect the efficiency of the process, with better removal efficiency when the sizes of both bubbles and particles are similar. In this study, a newly developed particle counter method (PCM) was introduced to measure particle sizes. To confirm its usefulness, the results were compared with those from image analysis. Then, using PCM, the size of bubbles in DAF was measured under various pressure conditions which are known to affect the bubble size the most (from 2 to 6 atmospheres). The bubble size decreased as the pressure increased up to a pressure of 3.5 atmospheres. Above this critical pressure, the bubble size did not decrease with further increases in pressure. According to these experimental results, it is not only costly, but also unnecessary, to maintain a pressure above 3.5 atmospheres if the goal is only to generate smaller bubbles.

Oil Removal from Refinery Wastes by Air Flotation

1974 ◽  
Vol 9 (1) ◽  
pp. 328-339 ◽  
Author(s):  
B. Volesky ◽  
S. Agathos
Keyword(s):  
Suspended Solids ◽  
Suspended Solid ◽  
Oil Removal ◽  
Dissolved Air Flotation ◽  
Physical Separation ◽  
Sedimentation Technique ◽  
Flocculation Aid ◽  
Flotation Technique ◽  
Air Flotation ◽  
Dissolved Air

Abstract Air flotation as a physical separation process for removing oily products and suspended solid matter from refinery wastewaters achieves removal efficiencies from 65% to more than 90%. Demonstrated capacity of the process for COD and BOD removal ranges up to 90%. With addition of flotation and flocculation aid chemicals better performance is achieved. Current results are presented and critically reviewed. It appears that the pressure dissolved-air flotation system employing recycle-flow operation can produce effluent containing consistently less than 15 p.p.m. of oil and suspended solids. Its performance and capacity of handling overload situations makes it superior to the conventional flocculation-sedimentation technique. Oil removal limitations of the process and current research trends are stressed including an electro-flotation technique. Some aspects of process optimization are also discussed.

Effects of floc and bubble size on the efficiency of the dissolved air flotation (DAF) process

2007 ◽  
Vol 56 (10) ◽  
pp. 109-115 ◽  
Author(s):  
Mooyoung Han ◽  
Tschung-il Kim ◽  
Jinho Kim
Keyword(s):  
Bubble Size ◽  
Saturation Pressure ◽  
Collision Efficiency ◽  
Water And Wastewater Treatment ◽  
Dissolved Air Flotation ◽  
Floc Size ◽  
Recycle Ratio ◽  
Air Flotation ◽  
The 1960S ◽  
Dissolved Air

Dissolved air flotation (DAF) is a method for removing particles from water using micro bubbles instead of settlement. The process has proved to be successful and, since the 1960s, accepted as an alternative to the conventional sedimentation process for water and wastewater treatment. However, limited research into the process, especially the fundamental characteristics of bubbles and particles, has been carried out. The single collector collision model is not capable of determining the effects of particular characteristics, such as the size and surface charge of bubbles and particles. Han has published a set of modeling results after calculating the collision efficiency between bubbles and particles by trajectory analysis. His major conclusion was that collision efficiency is maximum when the bubbles and particles are nearly the same size but have opposite charge. However, experimental verification of this conclusion has not been carried out yet. This paper describes a new method for measuring the size of particles and bubbles developed using computational image analysis. DAF efficiency is influenced by the effect of the recycle ratio on various average floc sizes. The larger the recycle ratio, the higher the DAF efficiency at the same pressure and particle size. The treatment efficiency is also affected by the saturation pressure, because the bubble size and bubble volume concentration are controlled by the pressure. The highest efficiency is obtained when the floc size is larger than the bubble size. These results, namely that the highest collision efficiency occurs when the particles and bubbles are about the same size, are more in accordance with the trajectory model than with the white water collector model, which implies that the larger the particles, the higher is the collision efficiency.

Toxic metals removal from dilute solutions by biosorptive flotation

1995 ◽  
Vol 32 (9-10) ◽  
pp. 211-220
Author(s):  
A. I. Zouboulis ◽  
P. Solari ◽  
K. A. Matis ◽  
G. A. Stalidis
Keyword(s):  
Toxic Metal ◽  
Separation Process ◽  
Dissolved Air Flotation ◽  
Metals Removal ◽  
Dilute Aqueous Solutions ◽  
Flotation Technique ◽  
Solid Liquid ◽  
Solid Liquid Separation ◽  
Digested Sewage Sludge ◽  
Dissolved Air

Toxic metal ions (cadmium, nickel and zinc), considered as priority pollutants, were removed from dilute aqueous solutions by sorption onto non-living (sterilized) anaerobically digested sewage sludge. The desorption of cadmium from metal-laden sludge was also examined. Flotation was subsequently applied as an effective solid/liquid separation process. The dissolved-air flotation technique was applied for the generation of fine bubbles and, in parallel, electrokinetic measurements were carried out. Promising results were succeeded from the combined process of biosorption/flotation (termed biosorptive flotation).

Enhanced separation of water quality parameters in the DAF (Dissolved Air Flotation) system using ozone

2007 ◽  
Vol 56 (10) ◽  
pp. 149-155 ◽  
Author(s):  
Byoung-Ho Lee ◽  
Won-Chul Song ◽  
Hye-Young Kim ◽  
Jeong-Hyeon Kim
Keyword(s):  
Water Quality ◽  
Heterotrophic Bacteria ◽  
Removal Rate ◽  
Quality Parameters ◽  
Water Quality Parameters ◽  
Water And Wastewater Treatment ◽  
Dissolved Air Flotation ◽  
Micro Bubble ◽  
Air Flotation ◽  
Dissolved Air

Dissolved Air Flotation (DAF) has been used in water and wastewater treatment because it has an excellent separation capability. It was found that the separation capability of the DAF system could be even more enhanced by ozone. Ozone was applied as a substitute for air in the DAF system, so that the system was named as the DOF (Dissolved Ozone Flotation) system. Ozone not only enhances coagulation as is well known, but also provides larger micro-bubble volume because the solubility of ozone in water is much higher than that of air. Ozone enhanced the separation rate of SS by 13.6%, and turbidity by 21% in the DOF system compared to the DAF system. T-P was also removed 7.7% more in the DOF system. 41.5% of color and 7.4% of CODCr were enhanced in their removal rate. Coliform and heterotrophic bacteria were removed 54% and 57.3% more in the DOF system. Separation capability of the DOF system was greatly enhanced for most of the water quality parameters because ozone provides strong oxidation power with large volume of micro-bubbles.

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