Exploiting the Nutrient Potential of Anaerobically Digested Sewage Sludge: A Review

The world is currently witnessing a rapid increase in sewage sludge (SS) production, due to the increased demand for wastewater treatment. Therefore, SS management is crucial for the economic and environmental sustainability of wastewater treatment plants. The recovery of nutrients from SS has been identified as a fundamental step to enable the transition from a linear to a circular economy, turning SS into an economic and sustainable source of materials. SS is often treated via anaerobic digestion, to pursue energy recovery via biogas generation. Anaerobically digested sewage sludge (ADS) is a valuable source of organic matter and nutrients, and significant advances have been made in recent years in methods and technologies for nutrient recovery from ADS. The purpose of this study is to provide a comprehensive overview, describing the advantages and drawbacks of the available and emerging technologies for recovery of nitrogen (N), phosphorus (P), and potassium (K) from ADS. This work critically reviews the established and novel technologies, which are classified by their ability to recover a specific nutrient (ammonia stripping) or to allow the simultaneous recovery of multiple elements (struvite precipitation, ion exchange, membrane technologies, and thermal treatments). This study compares the described technologies in terms of nutrient recovery efficiency, capital, and operational costs, as well as their feasibility for full-scale application, revealing the current state of the art and future perspectives on this topic.

Life cycle assessment of sewage sludge pyrolysis: environmental impacts of biochar as carbon sequestrator and nutrient recycler

The pyrolysis of sewage sludge is an alternative method to recycle the contained nutrients, such as phosphorus, by material use of the resulting biochar. However, the ecological effects of pyrolysis are not easy to evaluate. Therefore, a life cycle assessment (LCA) was carried out to determine the environmental impact of sewage sludge pyrolysis and to compare it with the common method of sewage sludge incineration. In order to identify the most sustainable applications of the resulting biochar, four different scenarios were analyzed. The modeled life cycles include dewatering, drying and pyrolysis of digested sewage sludge and utilization paths of the by-products as well as various applications of the produced biochar and associated transports. The life cycle impact assessment was carried out using the ReCiPe midpoint method. The best scenario in terms of global warming potential (GWP) was the use of biochar in horticulture with net emissions of 2 g CO2 eq./kg sewage sludge. This scenario of biochar utilization can achieve savings of 78% of CO2 eq. emissions compared to the benchmark process of sewage sludge mono-incineration. In addition, no ecological hotspots in critical categories such as eutrophication or ecotoxicity were identified for the material use of biochar compared to the benchmark. Pyrolysis of digested sewage sludge with appropriate biochar utilization can therefore be an environmentally friendly option for both sequestering carbon and closing the nutrient cycle.

Influence of Valorization of Sewage Sludge on Energy Consumption in the Drying Process

Valorization of digested sewage sludge generated in a medium-sized sewage treatment plant and the effect of valorization on energy consumption during sludge drying used for energy recovery are presented. Anaerobic digestion of sewage sludge reduces dry matter content compared to raw sludge. This lowers its calorific value leading to the lower interest of consumers in using it as fuel. The aim of the study was to valorize digested sewage sludge prior to drying with high-energy waste with low moisture content. The procedure led to the reduction in moisture content by about 50% in the substrate supplied for solidification and drying. The calorific value of digested sewage sludge increased by 50%–80%, and the energy consumption of the drying process decreased by about 50%. Physical and chemical properties of sewage sludge and moisture content of substrates and mixtures after valorization were determined. The heat of combustion of valorized sewage sludge mixtures, their elemental composition, and ash content is investigated. Their calorific value in the analytical and working states of 10% H2O was calculated. The highest calorific value was obtained for the mixture of sewage sludge valorized with waste plastics or combined with wood dust, averaging 23 MJ/kg. A mathematical approximation of sewage sludge valorization is presented.

The effect of temperature and digested sewage sludge cover over tailings on the leaching of contaminants from Ballangen tailings deposit

Dry covers can be applied above tailings to reduce and prevent formation of acid mine drainage and leaching of contaminants. Efficiency of covers is affected by different parameters, of which temperature change under climate change context is one. Here, a laboratory column leaching experiment was performed under four temperatures, 5, 10, 14, and 18 °C on unoxidized tailings from Ballangen, Norway. 600 mL of water was added to each column every second week and leachate collected and analyzed for pH, salinity, alkalinity, concentrations of sulfate, Co, Fe, Mn, Ni, and Zn. A thin layer of digested sewage sludge was added to columns after the 16th leaching cycle. In total, 21 leaching cycles were performed. Results showed low oxidation of tailings and therefore high pH and low salinity, SO42−, Fe, Ni, and Co in the leachates at leaching temperature of 5 °C. Addition of sludge cover slowed down oxidation of underlying tailings and decreased leaching of SO42−, Fe, Mn, Co, Ni, and Zn from the tailings deposit, especially at relatively high temperature. 10 °C is a threshold temperature, below which leaching is not affected by the cover addition so much. At a leaching temperature higher than 10 °C, the sludge cover addition can reduce the leaching of elements significantly.