A study on wastewater minimization in indirect electrochemical synthesis of benzaldehyde

1996 ◽  
Vol 34 (10) ◽  
pp. 113-120 ◽  
Author(s):  
Ding Zhou ◽  
Zhirong Sun ◽  
Wanli Hu
Keyword(s):  
Environmental Protection ◽  
Electrochemical Oxidation ◽  
Electrochemical Synthesis ◽  
Chemical Process ◽  
New Technology ◽  
Pollution Prevention ◽  
Strategic Orientation ◽  
Waste Minimization

Development of methods of pollution prevention is a strategic orientation for environmental protection. This paper describes studies on waste minimization in benzaldehyde production by using indirect electrochemical oxidation of toluene instead of the seriously polluting traditional chemical process. The new technology developed eliminates the discharge of wastewater by recycling the reactive solution and gives a higher yield of benzaldehyde.

scholarly journals Wastewater Minimization in Indirect Electrochemical Synthesis of Phenylacetaldehyde

2002 ◽  
Vol 2 ◽  
pp. 48-52 ◽  
Author(s):  
Zhirong Sun ◽  
Xiang Hu ◽  
Ding Zhou
Keyword(s):  
Sulfuric Acid ◽  
Current Efficiency ◽  
Electrochemical Oxidation ◽  
Acid Concentration ◽  
Electrochemical Synthesis ◽  
Chemical Process ◽  
Sulfuric Acid Concentration ◽  
High Yield ◽  
High Current ◽  
High Current Efficiency

Wastewater minimization in phenylacetaldehyde production by using indirect electrochemical oxidation of phenylethane instead of the seriously polluting traditional chemical process is described in this paper. Results show that high current efficiency of Mn(III) and high yield of phenylacetaldehyde can be obtained at the same sulfuric acid concentration (60%). The electrolytic mediator can be recycled and there will be no waste discharged.

NEW TECHNOLOGIES AND PRACTICES FOR WASTE MINIMIZATION IN THE CHEMICAL AND PETROCHEMICAL INDUSTRIES : FINDINGS OF THE SALVADOR, BRAZIL, 1993 CONFERENCE

1994 ◽  
Vol 30 (3) ◽  
pp. 1-9
Author(s):  
Francisco Fontes Lima ◽  
Francisco Alves Pereira
Keyword(s):  
Waste Management ◽  
Environmental Protection ◽  
Case Studies ◽  
New Technologies ◽  
Waste Minimization ◽  
Source Control ◽  
International Conference ◽  
The Third ◽  
Control Programmes ◽  
Petrochemical Industries

This paper describes the findings of the “Third International Conference on Waste Management in the Chemical and Petrochemical Industries,” held in Salvador, Brazil, October 20-23, 1993. A summary of the 74 technical papers, divided into six major categories, is presented together with comments on the more stringent legislation concerning source control programmes. Case studies of two large chemical complexes that have been developing successful waste minimization programmes are described in detail: CETREL-Environmental Protection Company in Camaçari, Brazil, and BASF AG in Ludwigshafen, Germany.

Analysis and Design of Environmental Protection and Energy Saving in Modern Society Building

2014 ◽  
Vol 908 ◽  
pp. 355-358
Author(s):  
Jie Zhao
Keyword(s):  
Energy Saving ◽  
Environmental Protection ◽  
Architectural Design ◽  
New Technology ◽  
Modern Society ◽  
Modern Architecture ◽  
Analysis And Design ◽  
The People ◽  
Development Direction ◽  
Design Requirements

With the development of economy and the improvement of people's living level, improving living conditions and public buildings, architectural design requirements are also constantly improved. Modern architecture should consider not only beautiful and comfortable, but also take into account the design individuality, while taking into consideration the people-oriented design concept of environmental protection and energy saving. This also makes the environmental friendly and energy-saving building is the development direction of future architecture. This paper analyzes the modern architecture of the ecological and environmental protection, gives the method to realize the construction of energy-saving environmental protection design and the use of new materials, new equipment and new technology of the existing.

The direct electrochemical synthesis of some metal derivatives of lapachol

1997 ◽  
Vol 75 (5) ◽  
pp. 499-506 ◽  
Author(s):  
E.H. De Oliveira ◽  
G.E.A. Medeiros ◽  
C. Peppe ◽  
Martyn A. Brown ◽  
Dennis G. Tuck
Keyword(s):  
Electrochemical Oxidation ◽  
Copper Atom ◽  
Electrochemical Synthesis ◽  
Acetonitrile Solution ◽  
Triclinic Space Group ◽  
X Ray ◽  
Metal Anode ◽  
X Ray Crystallography ◽  
Metal Derivatives ◽  
Derivatives Of

The electrochemical oxidation of a sacrificial metal anode (M = Zn, Cd, Cu) in an acetonitrile solution of 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphthoquinone, lapachol, C15H14O3 (=HL) gives ML2. The results are in keeping with earlier work on direct electrochemical synthesis in related systems. Adducts with 2,2′-bipyridine (bpy) and N,N,N′,N′-tetramethylethanediamine (tmen) have also been prepared. The structure of the 2,2′-bipyridine adduct of Cu(lapacholate)2 has been established by X-ray crystallography. The parameters are triclinic, space group [Formula: see text], a = 12.748(59) Å, b = 13.859(49) Å, c = 11.770(59) Å, α = 108.30(4)°, β = 108.08(3)°, γ = 68.94(3)°, Z = 2, R = 0.059 for 2256 unique reflections. The copper atom is in a distorted CuN2O2O2′ environment. The mechanism of the formation of this Cu(lapacholate)2 is discussed. Keywords: electrochemical synthesis, lapachol, X-ray crystallography, copper(II) complex.

Electrochemical synthesis of 1-N-phenyl-4-(sulfonyl)benzene-1,2-diamine derivatives: a mild and regioselective protocol

2016 ◽  
Vol 40 (6) ◽  
pp. 5442-5447 ◽  
Author(s):  
Mahnaz Sharafi-Kolkeshvandi ◽  
Davood Nematollahi ◽  
Farzad Nikpour ◽  
Eslam Salahifar
Keyword(s):  
Aqueous Solution ◽  
Electrochemical Oxidation ◽  
Electrochemical Synthesis ◽  
Regioselective Synthesis ◽  
Sulfinic Acids

Regioselective synthesis of 1-N-phenyl-4-(arylsulfonyl)benzene-1,2-diamine derivatives was carried out by the electrochemical oxidation of 2-aminodiphenylamine in aqueous solution in the presence of sulfinic acids as nucleophiles.

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