Phosphorus sorption and chemical characteristics of lightweight aggregates (LWA)-potential filter media in treatment wetlands

1997 ◽  
Vol 35 (5) ◽  
pp. 103-108 ◽  
Author(s):  
T. Zhu ◽  
P. D. Jenssen ◽  
T. Mæhlum ◽  
T. Krogstad

Five light-weight aggregates (LWAs), suitable for filter media in subsurface flow constructed wetlands, were tested for potential removal of phosphorus (P). P-sorption variation is dependent on the chemical characteristics of the LWA. All LWAs exhibited high pH and high total metal content; however, P-sorption capacity varied by two orders of magnitude. Of the LWAs' chemical characteristics (total metal content, cation exchange capacity, and oxalate soluble Fe and Al), total metal content has the closest relationship with the P-sorption capacity. Among the four major metal ions (Mg, Ca, Fe and Al), Ca has the strongest correlation with the P-sorption capacity.

Author(s):  
Victor Cucarella ◽  
Tomasz Zaleski ◽  
Ryszard Mazurek

Phosphorus sorption capacity of different types of opoka The bedrock opoka has been lately reported as an appropriate reactive media for onsite wastewater treatment systems due to its high phosphorus (P) sorption capacity. However, variations on its chemical composition may affect its reactivity with P, therefore leading to a variable P removal efficiency. In this paper, the P-sorption capacity of three different types of opoka from the region of Miechów, Poland, is reported. According to the silica and carbonate content, opoka samples were classified as light-weight and heavy-weight opoka. When heated over 900°C, opoka showed a very high P-sorption capacity that was well correlated to its Ca content. P-sorption isotherms from batch experiments with an artificial P solution were plotted and fitted to the Langmuir and Freundlich adsorption models. The Freundlich isotherm appeared to model better the P-sorption of light opoka and the Langmuir isotherm of heavy opoka, suggesting different dominating mechanisms of P-sorption by light and heavy opoka.


Soil Research ◽  
1996 ◽  
Vol 34 (1) ◽  
pp. 81 ◽  
Author(s):  
MDA Bolland ◽  
RJ Gilkes ◽  
RF Brennan ◽  
DG Allen

Seven methods of estimating or predicting phosphorus (P) sorption capacity were compared for 47 neutral to acid Western Australian soils. Two methods, the P buffer capacity (PBC) and the Fox and Kamprath procedure, provided reliable indices of P sorption from well defined P sorption isotherms, but they are not quick routine methods because several levels of P addition are required. The other five routine procedures included two versions of the P retention index (PRI), determined by adding one level of P, and three soil properties, oxalate extractable iron (oxalate Fe), oxalate extractable aluminium (oxalate Al), and pH measured in sodium fluoride [pH (F)], that are known to indicate P sorption capacity. All the indices were well related to one another. The oxalate Fe index was the least well related to PBC whereas oxalate Al, one of the PRI indices, and pH (F) were closely related to PBC and could be used as quick, economical procedures to assess the P sorption capacity of soils.


Author(s):  
Berhanu Dinssa ◽  
Eyasu Elias

<span>One of the most soil fertility management problems for crop production on acidic soils of the Ethiopian highlands is phosphorus fixation. The research was executed to assess the P-sorption capacity and to determine the external P requirement of different acidic soils in the Southwestern highlands of Ethiopia. Phosphorus sorption capacity (Kf) and its relation with selected soil characteristics were assessed for some major agricultural soils in the Ethiopian highlands to answer the questions, ‘What are the amount of P-sorption capacity and external P requirement of Nitisols, Luvisols, Alisols, and Andosols in Ethiopia?’. Twelve surface soil samples (at depth of 0-30 cm) were gathered and the P-sorption capacity was estimated. Phosphorus-sorption data were obtained by equilibrating 1 g of the 12 soil samples with 25 ml of KH<sub>2</sub>PO<sub>4</sub> in 0.01 M CaCl2, having 0, 30, 60, 90, 120, 150, 180, 210, 240, 270, 300, and 330 mg P L<sup>-1</sup> for 24 hours. The data were adjusted to the Freundlich adsorption model and the relationship among P-sorption and soil characteristics was established by correlation analysis.  Clay content and exchangeable acidity, organic matter, Al<sub>2</sub>O<sub>3</sub>, and Fe<sub>2</sub>O<sub>3</sub> oxides have affected phosphorus-sorption at a significance level of (P &lt; 0.05).  Alisols had the highest Kf value (413 mg kg<sup>-1</sup>) but Nitisols had the lowest Kf (280 mg kg<sup>-1</sup>). The external phosphorus fertilizer requirement of the soils was in the order of 25, 30, 32, and 26 mg P kg<sup>-1</sup> for Nitisols, Luvisols, Alisols, and Andosols sequentially. The Kf varies among different soil types of the study area. The magnitude of the soil’s Kf was affected by the pH of the soil, soil OM content, and oxides of Fe and Al. Therefore, knowledge of the soils’ P retention capacity is highly crucial to determine the correct rate of P </span><span>fertilizer</span><span> for crop production.</span>


2020 ◽  
Vol 20 (4) ◽  
pp. 1882-1890 ◽  
Author(s):  
Gilmar Luiz Mumbach ◽  
Luciano Colpo Gatiboni ◽  
Daniel João Dall’Orsoletta ◽  
Djalma Eugênio Schmitt ◽  
Patrícia Pretto Pessotto ◽  
...  

2017 ◽  
Vol 44 ◽  
pp. 50-58 ◽  
Author(s):  
Josiane M.T. Carneiro ◽  
Katherine Chacón-Madrid ◽  
Rodrigo M. Galazzi ◽  
Bruna K. Campos ◽  
Sandra C.C. Arruda ◽  
...  

Soil Research ◽  
2004 ◽  
Vol 42 (1) ◽  
pp. 89 ◽  
Author(s):  
L. L. Burkitt ◽  
C. J. P. Gourley ◽  
P. W. G. Sale

Five field sites established in the high rainfall zone of southern Victoria were used to examine the downwards vertical movement of phosphorus (P) fertiliser on soils which ranged in P sorption capacity. Fertiliser was applied either as a single application of 280 kg P/ha at the beginning of the experiment (April 1998), or as 35�kg�P/ha reapplied every 6 months (totalling 210 kg P/ha by the end of the third year). Soil cores were sampled in June 2001 to a depth of 40 cm, and soil at depths of 0–5, 5–10, 10–20, 20–30, and 30–40 cm was analysed for a range of soil properties and total P concentration.Total P concentration changed very little down the profile, indicating that there was minimal vertical movement of P fertiliser below the 10 cm layer of 5 pasture soils following the single application of 280 kg P/ha or 35 kg P/ha reapplied every 6 months. Soils with low to moderate surface P sorption capacity showed a trend for higher total P concentrations at depth. However, quantitative relationships between vertical P movement and soil properties at depth were poor. A P audit resulted in variable recovery of the applied P (45–128%) in the surface 40 cm at each of the 5 sites. Consistently low P recoveries were achieved at one site, where the surface soil had a high P sorption capacity. Some applied P may have bypassed the high P sorbing surface layers at this site through macropore flow and moved beyond the 40 cm sampling zone, or have been lost to surface runoff. These results question the usefulness of P audit or mass-balance methods for accounting for P movement in a pasture-based system, as spatial heterogeneity of soil properties, both horizontally and vertically, was high in the current study.


1991 ◽  
Vol 71 (4) ◽  
pp. 453-463 ◽  
Author(s):  
Y. K. Soon

Phosphate solubility and sorption characteristics of 39 agricultural soils in the northwestern Canadian Prairie were studied to gain insights into the retention of fertilizer P added to soil. The soils were mostly acidic with base saturation of 59–95%. The solubility of P as determined by the equilibrium P concentration and phosphoric acid potential was low and appeared to be controlled by sorption of phosphate by soil components. The mean equilibrium solution P concentration was 0.03 mg L−1. Phosphorus concentration in saturation extracts was about one order of magnitude higher, but would have included organic and colloidal P since P analysis in these extracts was done by ICP. Sorption capacity of P as determined by Langmuir isotherm was greater for the Dark Gray and Black soils and gleysols, i.e., soils with higher amounts of organic matter, than the Gray Luvisolic and Solodic soils by about 30%. Partial correlation showed that clay content, Al-organic matter complexes (AlOM) and amorphous iron oxide (FeOX) were significantly correlated with P sorption capacity. When both topsoils and subsoils were considered, clay content was the most important soil property influencing P sorption capacity, followed by AlOM and FeOX (standard partial regression coefficients, b′, of 0.47, 0.39 and 0.38, respectively). When only topsoils were considered, AlOM and FeOX became more important than clay content in influencing P sorption (b′ = 0.47, 0.47, and 0.33, respectively). Native P, estimated by oxalate and anion-resin extractions, was associated with the hydrous iron oxides only, although soil pH also affected the resin-extractable P fraction. Key words: P retention, solubility, Luvisols, solodic soils


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