Comparison of seven phosphorus sorption indices

Soil Research ◽  
1996 ◽  
Vol 34 (1) ◽  
pp. 81 ◽  
Author(s):  
MDA Bolland ◽  
RJ Gilkes ◽  
RF Brennan ◽  
DG Allen
Keyword(s):  
Sorption Capacity ◽  
Buffer Capacity ◽  
Sorption Isotherms ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Routine Procedures ◽  
P Addition ◽  
Western Australian ◽  
Extractable Iron

Seven methods of estimating or predicting phosphorus (P) sorption capacity were compared for 47 neutral to acid Western Australian soils. Two methods, the P buffer capacity (PBC) and the Fox and Kamprath procedure, provided reliable indices of P sorption from well defined P sorption isotherms, but they are not quick routine methods because several levels of P addition are required. The other five routine procedures included two versions of the P retention index (PRI), determined by adding one level of P, and three soil properties, oxalate extractable iron (oxalate Fe), oxalate extractable aluminium (oxalate Al), and pH measured in sodium fluoride [pH (F)], that are known to indicate P sorption capacity. All the indices were well related to one another. The oxalate Fe index was the least well related to PBC whereas oxalate Al, one of the PRI indices, and pH (F) were closely related to PBC and could be used as quick, economical procedures to assess the P sorption capacity of soils.

scholarly journals Phosphorus sorption capacity of different types of opoka

2007 ◽  
Vol 38 (1) ◽  
pp. 11-18 ◽  
Author(s):  
Victor Cucarella ◽  
Tomasz Zaleski ◽  
Ryszard Mazurek
Keyword(s):  
Sorption Capacity ◽  
Sorption Isotherms ◽  
Freundlich Isotherm ◽  
Carbonate Content ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Onsite Wastewater Treatment Systems ◽  
Different Types ◽  
Phosphorus Sorption Capacity

Phosphorus sorption capacity of different types of opoka The bedrock opoka has been lately reported as an appropriate reactive media for onsite wastewater treatment systems due to its high phosphorus (P) sorption capacity. However, variations on its chemical composition may affect its reactivity with P, therefore leading to a variable P removal efficiency. In this paper, the P-sorption capacity of three different types of opoka from the region of Miechów, Poland, is reported. According to the silica and carbonate content, opoka samples were classified as light-weight and heavy-weight opoka. When heated over 900°C, opoka showed a very high P-sorption capacity that was well correlated to its Ca content. P-sorption isotherms from batch experiments with an artificial P solution were plotted and fitted to the Langmuir and Freundlich adsorption models. The Freundlich isotherm appeared to model better the P-sorption of light opoka and the Langmuir isotherm of heavy opoka, suggesting different dominating mechanisms of P-sorption by light and heavy opoka.

Phosphorus sorption and chemical characteristics of lightweight aggregates (LWA)-potential filter media in treatment wetlands

1997 ◽  
Vol 35 (5) ◽  
pp. 103-108 ◽  
Author(s):  
T. Zhu ◽  
P. D. Jenssen ◽  
T. Mæhlum ◽  
T. Krogstad
Keyword(s):  
Sorption Capacity ◽  
Metal Content ◽  
Exchange Capacity ◽  
Chemical Characteristics ◽  
Phosphorus Sorption ◽  
Filter Media ◽  
Total Metal Content ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Total Metal

Five light-weight aggregates (LWAs), suitable for filter media in subsurface flow constructed wetlands, were tested for potential removal of phosphorus (P). P-sorption variation is dependent on the chemical characteristics of the LWA. All LWAs exhibited high pH and high total metal content; however, P-sorption capacity varied by two orders of magnitude. Of the LWAs' chemical characteristics (total metal content, cation exchange capacity, and oxalate soluble Fe and Al), total metal content has the closest relationship with the P-sorption capacity. Among the four major metal ions (Mg, Ca, Fe and Al), Ca has the strongest correlation with the P-sorption capacity.

scholarly journals Evaluation of phosphate sorption capacity and external phosphorus requirement of some agricultural soils of the southwestern Ethiopian highlands

2021 ◽  
Vol 18 (2) ◽  
pp. 136
Author(s):  
Berhanu Dinssa ◽  
Eyasu Elias
Keyword(s):  
Sorption Capacity ◽  
Crop Production ◽  
Agricultural Soils ◽  
Soil Characteristics ◽  
Soil Samples ◽  
Phosphorus Sorption ◽  
Acidic Soils ◽  
Ethiopian Highlands ◽  
P Sorption ◽  
P Sorption Capacity

<span>One of the most soil fertility management problems for crop production on acidic soils of the Ethiopian highlands is phosphorus fixation. The research was executed to assess the P-sorption capacity and to determine the external P requirement of different acidic soils in the Southwestern highlands of Ethiopia. Phosphorus sorption capacity (Kf) and its relation with selected soil characteristics were assessed for some major agricultural soils in the Ethiopian highlands to answer the questions, ‘What are the amount of P-sorption capacity and external P requirement of Nitisols, Luvisols, Alisols, and Andosols in Ethiopia?’. Twelve surface soil samples (at depth of 0-30 cm) were gathered and the P-sorption capacity was estimated. Phosphorus-sorption data were obtained by equilibrating 1 g of the 12 soil samples with 25 ml of KH<sub>2</sub>PO<sub>4</sub> in 0.01 M CaCl2, having 0, 30, 60, 90, 120, 150, 180, 210, 240, 270, 300, and 330 mg P L<sup>-1</sup> for 24 hours. The data were adjusted to the Freundlich adsorption model and the relationship among P-sorption and soil characteristics was established by correlation analysis.  Clay content and exchangeable acidity, organic matter, Al<sub>2</sub>O<sub>3</sub>, and Fe<sub>2</sub>O<sub>3</sub> oxides have affected phosphorus-sorption at a significance level of (P &lt; 0.05).  Alisols had the highest Kf value (413 mg kg<sup>-1</sup>) but Nitisols had the lowest Kf (280 mg kg<sup>-1</sup>). The external phosphorus fertilizer requirement of the soils was in the order of 25, 30, 32, and 26 mg P kg<sup>-1</sup> for Nitisols, Luvisols, Alisols, and Andosols sequentially. The Kf varies among different soil types of the study area. The magnitude of the soil’s Kf was affected by the pH of the soil, soil OM content, and oxides of Fe and Al. Therefore, knowledge of the soils’ P retention capacity is highly crucial to determine the correct rate of P </span><span>fertilizer</span><span> for crop production.</span>

Extractable iron and aluminium predict the P sorption capacity of Thai soils

Soil Research ◽  
2005 ◽  
Vol 43 (6) ◽  
pp. 757 ◽  
Author(s):  
W. Wiriyakitnateekul ◽  
A. Suddhiprakarn ◽  
I. Kheuruenromne ◽  
R. J. Gilkes
Keyword(s):  
Sorption Capacity ◽  
Stepwise Regression ◽  
Clay Content ◽  
Langmuir Equation ◽  
Soil Types ◽  
Sorption Data ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Freundlich Equation ◽  
Extractable Iron

The objective of this study was to determine if dithionite- and oxalate-extractable Fe and Al can be used to predict the P sorption capacity of Thai soils. Forty-five samples from diverse soil types were taken from surface and subsurface horizons of soils on sandstone, shale/limestone, granite, and basalt. The samples were analysed for P sorption, dithionite- and oxalate-extractable Fe and Al (Fed, Feo, Ald, Alo), specific surface area (SSA), and other soil properties. Generally P sorption data for these soils were slightly better fitted by the Langmuir equation than the Freundlich equation. The Langmuir P sorption maximum ranged from 35 to 1111 μg/g with a median value of 370 μg/g soil. Soils developed on basalt had higher values of P sorption maximum (xm) (range 400–1111 μg/g, median 597 μg/g) than soils on other parent materials. Fed concentrations in soils (4–74 g/kg) were much higher than Feo concentrations (0.2–13.8 g/kg) with values of Feo/Fed ranging from 0.01 to 0.28 (median 0.09), indicating that most of the free iron oxides were crystalline. Amounts of Ald and Alo were about equal with median values of 1.6 and 1.0 g/kg, respectively. About 80% of the samples had SSA values <40 m2/g. Both the P sorption maximum and Freundlich k were linearly related to SSA (R2 = 0.77, 0.74), Ald (R2 = 0.78, 0.79), Alo (R2 = 0.64, 0.74), Fed (R2 = 0.48, 0.41), Feo (R2 = 0.43, 0.72), and clay content (R2 = 0.48, 0.36). Stepwise regression indicated that 81% of the variability in P sorption by these soils could be explained by a combination of dithionite and oxalate Fe and Al, however, Ald alone is almost as effective in predicting the P sorption capacity of Thai soils.

Sodium-fluoride pH of South-Western Australian soils as an indicator of P-sorption

Soil Research ◽  
1994 ◽  
Vol 32 (4) ◽  
pp. 755 ◽  
Author(s):  
RJ Gilkes ◽  
JC Hughes
Keyword(s):  
Clay Minerals ◽  
Iron Oxides ◽  
Sorption Capacity ◽  
Sodium Fluoride ◽  
Secondary Importance ◽  
P Sorption ◽  
Soil Constituent ◽  
Western Australian ◽  
Soil Constituents ◽  
Measuring Ph

Phosphate sorption by the surface horizon of 228 acid to neutral Western Australian (W.A.) soils is more closely related (r(2) = 0.76) to the content of oxalate-extractable aluminium than to any other soil constituent. This fraction corresponds to poorly ordered inorganic and organic Al compounds that release considerable amounts of OH- to NaF solution. Thus the abundance of these compounds in soil may be estimated by measurement of the pH of a NaF extract (pH((NaF)) This association enables the rapid and moderately accurate prediction in the field of the P-sorption capacity of soils (r(2) = 0.72) by measuring pH(NaF) With a. simple, portable pH meter. For many W.A. soils, it is probable that well crystalline aluminium and iron oxides, clay minerals and other soil constituents are of secondary importance in determining P-sorption and that most P-sorption is due to poorly ordered and organically complexed forms of Al.

Phosphorus Extraction with Soil Test Methods Affected by Soil P Sorption Capacity

2020 ◽  
Vol 20 (4) ◽  
pp. 1882-1890 ◽  
Author(s):  
Gilmar Luiz Mumbach ◽  
Luciano Colpo Gatiboni ◽  
Daniel João Dall’Orsoletta ◽  
Djalma Eugênio Schmitt ◽  
Patrícia Pretto Pessotto ◽  
...  
Keyword(s):  
Sorption Capacity ◽  
Test Methods ◽  
Soil Test ◽  
Soil P ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Phosphorus Extraction

Phosphorus auditing cannot account for all of the phosphorus applied to different pasture soils

Soil Research ◽  
2004 ◽  
Vol 42 (1) ◽  
pp. 89 ◽  
Author(s):  
L. L. Burkitt ◽  
C. J. P. Gourley ◽  
P. W. G. Sale
Keyword(s):  
Soil Properties ◽  
Sorption Capacity ◽  
Vertical Movement ◽  
Single Application ◽  
Macropore Flow ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Sampling Zone ◽  
P Movement ◽  
Total P

Five field sites established in the high rainfall zone of southern Victoria were used to examine the downwards vertical movement of phosphorus (P) fertiliser on soils which ranged in P sorption capacity. Fertiliser was applied either as a single application of 280 kg P/ha at the beginning of the experiment (April 1998), or as 35�kg�P/ha reapplied every 6 months (totalling 210 kg P/ha by the end of the third year). Soil cores were sampled in June 2001 to a depth of 40 cm, and soil at depths of 0–5, 5–10, 10–20, 20–30, and 30–40 cm was analysed for a range of soil properties and total P concentration.Total P concentration changed very little down the profile, indicating that there was minimal vertical movement of P fertiliser below the 10 cm layer of 5 pasture soils following the single application of 280 kg P/ha or 35 kg P/ha reapplied every 6 months. Soils with low to moderate surface P sorption capacity showed a trend for higher total P concentrations at depth. However, quantitative relationships between vertical P movement and soil properties at depth were poor. A P audit resulted in variable recovery of the applied P (45–128%) in the surface 40 cm at each of the 5 sites. Consistently low P recoveries were achieved at one site, where the surface soil had a high P sorption capacity. Some applied P may have bypassed the high P sorbing surface layers at this site through macropore flow and moved beyond the 40 cm sampling zone, or have been lost to surface runoff. These results question the usefulness of P audit or mass-balance methods for accounting for P movement in a pasture-based system, as spatial heterogeneity of soil properties, both horizontally and vertically, was high in the current study.

Mapping soil phosphorus sorption capacity in four depths with uncertainty propagation

2020 ◽  
Author(s):  
Anders Bjørn Møller ◽  
Goswin Johann Hechrath ◽  
Cecilie Hermansen ◽  
Trine Nørgaard ◽  
Maria Knadel ◽  
...  
Keyword(s):  
Sorption Capacity ◽  
Agricultural Land ◽  
Mineral Fertilizer ◽  
Parent Material ◽  
Depth Interval ◽  
Detailed Knowledge ◽  
Phosphorus Sorption ◽  
Aeolian Deposits ◽  
Phosphorus Sorption Capacity ◽  
Extractable Iron

&lt;p&gt;Phosphorus (P) is one of the most important plant nutrients, and farmers regularly apply P as mineral fertilizer and with animal manures. Typically, reactions with amorphous aluminum and iron oxides or carbonates retain P in the soil. However, if P additions exceed the soil&amp;#8217;s ability to bind them, P may leach from soil to surface waters, where it causes eutrophication. The phosphorus sorption capacity (PSC) is thus an inherent soil property that, when related to bound P, can describe the P saturation of the soil. Detailed knowledge of the spatial distribution of the PSC is therefore important information for assessing the risk of P leaching from agricultural land.&lt;/p&gt;&lt;p&gt;In weakly acidic soils predominant in Denmark, the PSC depends mainly on the oxalate-extractable contents of aluminum and iron. In this study, we aimed to map PSC in four depth intervals (0 &amp;#8211; 25; 25 &amp;#8211; 50; 50 &amp;#8211; 75; 75 &amp;#8211; 100 cm) for Denmark using measurements of oxalate-extractable aluminum and iron from 1,623 locations.&lt;/p&gt;&lt;p&gt;We mapped both elements using quantile regression forests. Predictions of oxalate-extractable aluminum had a weighted RMSE of 13.9 mmol kg&lt;sup&gt;-1&lt;/sup&gt;. For oxalate-extractable iron, weighted RMSE was 33.5 mmol kg&lt;sup&gt;-1&lt;/sup&gt;.&lt;/p&gt;&lt;p&gt;We included depth as a covariate and therefore trained one model for each element. For each element in each depth interval, we predicted the mean prediction value as well as 100 quantiles ranging from 0.5% to 99.5% in 1% intervals. The maps had a 30.4 m resolution. We then calculated PSC by convoluting the prediction quantiles of the two elements, using every combination of quantiles, in order to obtain the prediction uncertainty for PSC.&lt;/p&gt;&lt;p&gt;Oxalate-extractable aluminum was roughly normal distributed, while oxalate-extractable iron had a large positive skew. The age and origin of the parent material had a large effect on oxalate-extractable aluminum, and soil-forming processes such as weathering and podzolization had clear effects on the distribution in depth. Meanwhile, organic matter, texture and wetland processes were the main factors affecting oxalate-extractable iron, so much so that they obscured any trends with depth.&lt;/p&gt;&lt;p&gt;The weighted RMSE of the predicted PSC was 19.1 mmol kg&lt;sup&gt;-1&lt;/sup&gt;. PSC was highest in wetland areas and lowest in young upland deposits, such as aeolian deposits and the loamy Weichselian moraines of eastern Denmark. The sandy glaciofluvial plains and Saalian moraines of western Denmark had intermediate PSC. In most cases, PSC was highest in the top soil, but in the sandy soils of western Denmark, PSC was highest in the depth interval 25 &amp;#8211; 50 cm due to podzolization.&lt;/p&gt;

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