Evaluation of surfactant efficiency in remediation on non aqueous phase liquid (NAPL) contaminated soils

2000 ◽  
Vol 42 (1-2) ◽  
pp. 325-330 ◽  
Author(s):  
H. Rubin ◽  
U. Zoller ◽  
D. Dveyrin

This study represents a possible approach for the determination of the parameters characterizing the efficiency of surfactant mix for the remediation of soil and aquifers contaminated by entrapped non aqueous phase liquid (NAPL). The method incorporates the performance of two sets of experiments and their appropriate analysis. In one set, called the “vessel experiments”, the CMC of the surfactant mix is determined. The second set of experiments is called the “flow experiments”. In this set of experiments soil columns are contaminated by entrapped NAPL. Water flows through these columns with various types of surfactant mix solutions. According to the soil permeabilityvariation and the dissolved NAPL concentration in the water leaving the soil column, the effect of the surfactant mix on the coefficient of mass transfer is determined.

Soil Research ◽  
1982 ◽  
Vol 20 (1) ◽  
pp. 61
Author(s):  
HS Acharya

In experimental methods for determination of soil water diffusivity using the water distribution from horizontal infiltration into a soil column, hand smoothing of the experimentally obtained distribution introduces uncertainties in the calculations. A method of calculation involving techniques of quadratic programming has been used to minimize the possible errors caused by inhomogeneous packing of the horizontal soil columns. Examples are given to illustrate the method of calculations.


1988 ◽  
Vol 127 ◽  
Author(s):  
J. A. Del Debbio ◽  
T. R. Thomas

ABSTRACTLaboratory studies are being conducted to measure the transport properties of various radionuclide species through soil columns. The studies are being conducted to support evaluations for potential near-surface disposal of high-level radioactive waste (HLW) calcine stored at the Idaho National Engineering Laboratory. The data will be used to model radionuclide transport through the vadose (unsaturated) zone of the site under various water-contact scenarios. Retardation factors and dispersion coefficients for technetium and selenium species have been measured in water-saturated soil columns made up of sediments taken from 12 and 35 meters below the surface. A one-dimensional, convective-dispersive, solute-transport equation was fitted to column effluent data by optimizing three parameters (retardation factor, dispersion coefficient and pulse time) using a non-linear, least-squares fitting routine. The data indicated no retardation of the pertechnetate ion (TcO4-)and selenate ion (SeO4-) and a large retardation of the selenite ion (SeO3-) relative to water transport through the soil column.


2000 ◽  
Vol 413 ◽  
pp. 49-63 ◽  
Author(s):  
MARIOS M. FYRILLAS

The two-dimensional problem of advection–dispersion associated with a non-aqueous-phase liquid (NAPL) pool is addressed using the boundary element method. The problem is appropriately posed with an inhomogeneous boundary condition taking into consideration the presence of the pool and the impermeable layer. We derive a Fredholm integral equation of the first kind for the concentration gradient along the pool location and compute the average mass transfer coefficient numerically using the boundary-element method. Numerical results are in agreement with asymptotic analytical solutions obtained for the cases of small and large Péclet number (Pex). The asymptotic solution for small Pex, which is obtained by applying a novel perturbation technique to the integral equation, is used to de-singularize the integral equation. Results predicted by this analysis are in good agreement with experimentally determined overall mass transfer coefficients.


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