Determination of Technetium and Selenium Transport Properties in Laboratory Soil Columns

1988 ◽  
Vol 127 ◽  
Author(s):  
J. A. Del Debbio ◽  
T. R. Thomas
Keyword(s):  
Transport Properties ◽  
Soil Column ◽  
Retardation Factor ◽  
Soil Columns ◽  
Water Contact ◽  
Near Surface ◽  
One Dimensional ◽  
High Level ◽  
Water Saturated

ABSTRACTLaboratory studies are being conducted to measure the transport properties of various radionuclide species through soil columns. The studies are being conducted to support evaluations for potential near-surface disposal of high-level radioactive waste (HLW) calcine stored at the Idaho National Engineering Laboratory. The data will be used to model radionuclide transport through the vadose (unsaturated) zone of the site under various water-contact scenarios. Retardation factors and dispersion coefficients for technetium and selenium species have been measured in water-saturated soil columns made up of sediments taken from 12 and 35 meters below the surface. A one-dimensional, convective-dispersive, solute-transport equation was fitted to column effluent data by optimizing three parameters (retardation factor, dispersion coefficient and pulse time) using a non-linear, least-squares fitting routine. The data indicated no retardation of the pertechnetate ion (TcO4-)and selenate ion (SeO4-) and a large retardation of the selenite ion (SeO3-) relative to water transport through the soil column.

A note on the methods for determining soil water diffusivity

Soil Research ◽  
1982 ◽  
Vol 20 (1) ◽  
pp. 61
Author(s):  
HS Acharya
Keyword(s):  
Quadratic Programming ◽  
Soil Water ◽  
Water Distribution ◽  
Soil Column ◽  
Experimental Methods ◽  
Soil Columns ◽  
Method Of Calculation ◽  
Water Diffusivity ◽  
Horizontal Infiltration

In experimental methods for determination of soil water diffusivity using the water distribution from horizontal infiltration into a soil column, hand smoothing of the experimentally obtained distribution introduces uncertainties in the calculations. A method of calculation involving techniques of quadratic programming has been used to minimize the possible errors caused by inhomogeneous packing of the horizontal soil columns. Examples are given to illustrate the method of calculations.

scholarly journals Sorption-Capacity Limited Retardation of Radionuclides Transport in Water-Saturated Packing Materials

1984 ◽  
Vol 44 ◽  
Author(s):  
C. Pescatore ◽  
T. Sullivan
Keyword(s):  
Sorption Capacity ◽  
Retardation Factor ◽  
High Level Waste ◽  
Radionuclide Transport ◽  
Breakthrough Time ◽  
Packing Materials ◽  
Sorption Data ◽  
Waste Package ◽  
High Level ◽  
Water Saturated

AbstractRadionuclides breakthrough times as calculated through constant retardation factors obtained in dilute solutions are non-conservative. The constant retardation approach regards the solid as having infinite sorption capacity throughout the solid. However, as the solid becomes locally saturated, such as in the proximity of the waste form-packing materials interface, it will exhibit no retardation properties, and transport will take place as if the radionuclides were locally non-reactive. The magnitude of the effect of finite sorption capacity of the packing materials on radionuclide transport is discussed with reference to high-level waste package performance. An example based on literature sorption data indicates that the breakthrough time may be overpredicted by orders of magnitude using a constant retardation factor as compared to using the entire sorption isotherm to obtain a concentrationdependent retardation factor.

Evaluation of surfactant efficiency in remediation on non aqueous phase liquid (NAPL) contaminated soils

2000 ◽  
Vol 42 (1-2) ◽  
pp. 325-330 ◽  
Author(s):  
H. Rubin ◽  
U. Zoller ◽  
D. Dveyrin
Keyword(s):  
Mass Transfer ◽  
Aqueous Phase ◽  
Contaminated Soils ◽  
Soil Column ◽  
Soil Columns ◽  
Water Flows ◽  
Phase Liquid ◽  
Flow Experiments ◽  
Remediation Of Soil

This study represents a possible approach for the determination of the parameters characterizing the efficiency of surfactant mix for the remediation of soil and aquifers contaminated by entrapped non aqueous phase liquid (NAPL). The method incorporates the performance of two sets of experiments and their appropriate analysis. In one set, called the “vessel experiments”, the CMC of the surfactant mix is determined. The second set of experiments is called the “flow experiments”. In this set of experiments soil columns are contaminated by entrapped NAPL. Water flows through these columns with various types of surfactant mix solutions. According to the soil permeabilityvariation and the dissolved NAPL concentration in the water leaving the soil column, the effect of the surfactant mix on the coefficient of mass transfer is determined.

scholarly journals Modeling of NO3 transport in gypsiferous soil under unsaturated flow

2021 ◽  
Vol 8 (3) ◽  
Author(s):  
Ramzi M. Shihab ◽  
Ahmed A. Fattah ◽  
Noor Aldeen M. Muhawish
Keyword(s):  
Unsaturated Flow ◽  
Nitrate Concentration ◽  
Dispersion Model ◽  
Soil Column ◽  
Potassium Nitrate ◽  
Breakthrough Curves ◽  
Retardation Factor ◽  
Soil Columns ◽  
Water Head ◽  
Gypsum Content

"This study was conducted to determine the effect of gypsum content and depth of water head on displacement and transport of nitrate in gypsiferous soil under unsaturated flow conditions. Also, to predict the concentration of nitrate using convection dispersion model (CDE). Soil columns with 63, 97, 142, 180, and 236 g kg-1 of gypsum were prepared. 200 mg L-1 of potassium nitrate were added to the surface of each soil column. The soil columns were leached by intermittent ponding in 2 pore volumes of water. A constant head depth of 0.005, 0.01, and 0.015 m of water was kept on the top of soil column. Samples of effluent were collected for measuring nitrate concentration. The CDE model was analyzed to estimate the best fitting between measured and predicted nitrate concentration, and to calculate dispersion coefficient (D), the retardation factor (R), and Peclet number (P). Results showed that CDE can be used to predict nitrate concentration in soil. Good fit was observed to describe breakthrough curves (BTC's), and predict the transport of nitrates in the leachate of gypsum soil columns. D values increased with the increase in the content of soil gypsum and decrease with increase the water head. Its values ranged between 6.59-9.87 m 2h-1. P and pore water velocity (v) decreased with the increase in soil gypsum content. The R values were less than 1 for all treatments"

Structure of the exudate gum from Meryta sinclairii

2020 ◽  
Author(s):  
Ian Sims ◽  
Richard Furneaux
Keyword(s):  
Average Molecular Weight ◽  
Gum Arabic ◽  
Arabinogalactan Protein ◽  
Weight Average Molecular Weight ◽  
1H And 13C Nmr ◽  
One Dimensional ◽  
Linkage Analyses ◽  
Yariv Reagent ◽  
Native Tree ◽  
High Level

A gum that exudes from the wounded trunk of the New Zealand native tree Meryta sinclairii has been isolated. The gum was completely precipitated by the β-glucosyl Yariv reagent and was thus determined to be an arabinogalactan-protein (AGP). It contained >95% w/w carbohydrate and only 2% w/w protein with a high level of hydroxyproline. SEC-MALLS showed that the gum had a weight-average molecular weight of 4.45×106Da compared with 6.02×105Da for gum arabic. Constituent sugar and linkage analyses were consistent with polymers comprised of a highly branched backbone of 1,3-linked galactopyranosyl (Galp) residues, with side-chains made up of arabinofuranose- (Araf) containing oligosaccharides, terminated variously by rhamnopyranosyl (Rhap), arabinopyranosyl (Arap), Galp and glucuronopyranosyl (GlcpA) residues. Analysis by one-dimensional and two-dimensional 1H and 13C NMR experiments confirmed the linkage analyses. The structure of the gum is discussed in comparison with the structure of gum arabic and other AGPs. © 2003 Elsevier Science Ltd. All rights reserved.

Immediate implantation in a patient with chronic generalized parodontitis and apical granuloma

2019 ◽  
Vol 24 (2) ◽  
pp. 145-149
Author(s):  
A. I. Musienko ◽  
K. I. Nesterova
Keyword(s):  
Tooth Extraction ◽  
Tooth Root ◽  
Duration Of Treatment ◽  
Promising Direction ◽  
Aesthetic Result ◽  
Bone Atrophy ◽  
Alveolar Tissue ◽  
High Level ◽  
Immediate Implantation

Relevance. Rehabilitation of patients with moderate to severe generalized periodontitis is a leading problem in periodontology. It was the determination of the prospects for immediate implantation in patients with chronic periodontitis, combined with the pathology of the tooth root and maxillary sinus.Materials and methods. A group of 94 people with periodontitis and chronic odontogenic rhinosinus was observed who underwent sinus surgical treatment, tooth extraction and one-stage implantation with FRP growth factor according to the author's technology.Results. The method showed high efciency on the basis of assessing the clinical, aesthetic result and restoration of bone density after surgery.Conclusions. The developed technology is a promising direction, it allows to combine a high level of sanation of alveolar tissue with the advantages of immediate implantation, prevents bone atrophy, helps reduce the duration of treatment and the number of surgical and orthopedic interventions.

Methodical approaches to managing economic safety of tourism enterprises

2020 ◽  
pp. 160-164
Author(s):  
Leonid Tsubov ◽  
Oresta Shcherban
Keyword(s):  
Safety Management ◽  
Integrated Approach ◽  
Small Enterprise ◽  
Complex Nature ◽  
Efficient Management ◽  
Tourism Enterprises ◽  
High Level ◽  
Functional Components ◽  
Stimulation Control

The set of scientific-methodological tools to secure the mechanism of economic safety management of tourism entrepreneurship is examined as an aggregate of methods, tools, and conceptual activities directed at maintaining the high level of economic safety of tourism entrepreneurship. The features of managing the tourism enterprise and economic safety are analyzed. The basic valuation principles of the reliability and efficiency of the economic safety of the tourism enterprise are determined. The basic tasks of ensuring the economic safety of a small enterprise are outlined. The need to use the integrated approach that secures more opportunities to avoid threats and limits the danger of their emergence is emphasized. The most important principles for securing the economic safety of the tourism enterprise on the microeconomic level are described. Possible practical methods of risk management for the implementation of adopted decisions are proposed. The paper proves the fact that the complex nature of the management of the economic safety of the tourism enterprise and securing the sufficiently efficient management system of detecting and eliminating the threats are provided by the establishment of the management of the economic safety system of the tourism enterprise and its functional components. Research of the methodical approaches to the management of the tourism enterprises’ economic safety allows building and describing the functional structure of the mechanism of management of the tourist enterprise’s economic safety (it is formalized and described by 5 functions: determination of aims; planning; organization and adjusting; motivation and stimulation; control and monitoring).

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