Characterisation and conditioning of Fenton sludges issued from wastewater treatment

2002 ◽  
Vol 46 (10) ◽  
pp. 43-49 ◽  
Author(s):  
R.M. Ramírez Zamora ◽  
M.T. Orta de Velásquez ◽  
A. Durán Moreno ◽  
J. Malpica de la Torre

Characterisation tests were conducted to determine the feasibility of land application of the sludges produced in wastewater treatment by means of Fenton's Reagent. Physicochemical and microbiological parameters of Fenton sludges were compared to the values obtained for raw alum sludges. The Fenton sludges presented preferable characteristics such as the specific resistance to filtration (SRF), metals and pathogen content (fecal and total coliforms, helminth ova, and Salmonella sp.). The SRF of the Fenton sludges (1.55 × 1013 m/kg) was 24% less than the alum sludge value (1.92 × 1013 m/kg). The concentrations of fecal coliforms (0 MPN/g TS), Salmonella sp. (0 MPN/g TS), Helminth ova (22 HH/g TS) and metals correspond to the limits for biosolids of Class B for land application of the Mexican legislation. The Fenton reagent efficiently removes most of the pathogens, considered by the norms, by means of the combined action of the different stages that constitute this process. These results exhibit the Fenton reagent as a feasible treatment for generating sludges with characteristics of biosolids of Class B for land application. The preliminary results of conditioning tests show that Fenton sludges present better dewatering characteristics with regard to the alum sludge, for a dose of cationic polymer of 1 mg/g TS.

2008 ◽  
Vol 75 (1) ◽  
pp. 164-174 ◽  
Author(s):  
Emily Viau ◽  
Jordan Peccia

ABSTRACT Accurate modeling of the infectious aerosol risk associated with the land application of biosolids requires an in-depth knowledge of the magnitudes and changes in pathogen concentrations for a variety of class A and class B stabilization methods. The following survey used quantitative PCR (qPCR) and culture assays to detect environmentally resistant bacterial and viral pathogens and biosolid indicator organisms for 36 biosolid grab samples. Biosolids were collected from 14 U.S. states and included 16 class B mesophilic anaerobic digestion (MAD) samples and 20 class A biosolid samples from temperature-phased anaerobic digestion (TPAD), MAD plus composting (COM), and MAD plus heat pelletization processes. The indicator concentrations of fecal coliforms and male-specific coliphages as well as pathogen genome concentrations for human adenovirus species, Legionella pneumophila, Staphylococcus aureus, and Clostridium difficile were significantly lower in the class A samples, and a multivariate analysis of variance ranked the stabilization processes from the lowest pathogen/indicator load to the highest as (i) class A COM, (ii) class A TPAD, and (iii) class B MAD. Human adenovirus genomes were found in 88% of the class B samples and 70 to 100% of the class A samples. L. pneumophila, S. aureus, and C. difficile genomes were detected at the qPCR assay detection limits in 19 to 50% of the class B and class A anaerobic digestion samples, while L. pneumophila was detected in 50% of the class A compost samples. When considering all the stabilization methods, both the fecal coliform and the male-specific coliphage concentrations show a significant linear correlation with the pathogen genome concentrations. This survey provides the necessary pathogen concentrations to add to biosolid aerosol risk and pathogen exposure analyses and clarifies the effectiveness of class A stabilization methods with the pathogen and indicator loads in biosolids.


2000 ◽  
Vol 42 (9) ◽  
pp. 103-110 ◽  
Author(s):  
B. Jimenez ◽  
J. A. Barrios ◽  
C. Maya

Alkaline post-stabilization of wastewater sludge with high pathogenic content (up to 1010 NMP/g TS of Salmonella sp. and up to 89.8 helminth eggs/g TS) was studied to evaluate the feasibility of producing Class B biosolids. The sludge was produced in pilot systems using different advanced primary treatment processes treating wastewater generated in Mexico City. Samples were dewatered to different dryness ranging from 11.5 to 29.0% TS and stabilized using quicklime in doses ranging from 15 to 40% (w/w). The levels of pathogens found in dewatered sludge were up to 8 log and 1.95 log higher than those found in primary sludge generated in the United States for Salmonella sp. and helminth eggs respectively. Distribution of genera of helminths indicated that more than 90% of the eggs found were Ascaris, while the rest were Hymenolepis, Trichuris, Toxocara and Taenia. Minimum and maximum removals ranged between 3.6 to 9.5 log for fecal coliforms; 3.7 to 7.9 log for Salmonella sp.; and 0.1 to 1.3 log for helminths. The recommended quicklime dose was determined for different solids contents in order to achieve the pH-time criteria and the levels of microorganisms required by the US EPA. Metal concentrations were below the maximum levels established for land application of biosolids.


2006 ◽  
Vol 52 (2) ◽  
pp. 150-156 ◽  
Author(s):  
J P Brooks ◽  
B D Tanner ◽  
C P Gerba ◽  
I L Pepper

The purpose of this study was to determine aerosolized endotoxin concentrations downwind of a biosolids land application site. Aerosol samples were collected from biosolids land application sites, tractor operation, and an aeration basin located within an open-air wastewater treatment plant. Aerosolized endotoxin above background concentrations was detected from all sites, at levels ranging from below detection up to 1800 EU m–3 of air. Biosolids loading operations resulted in the greatest concentrations of endotoxin (mean 344 EU m–3). As downwind (perpendicular to wind vector) distance increased from sources (2–200 m), levels of endotoxin decreased to near background (without biosolids application) concentrations. Overall, the detected levels of aerosolized endotoxin were within past proposed aerosolized endotoxin limits (250–2000 EU m–3) by other occupational exposure studies. Occasionally, peak concentrations were found to be above these limits. Sites in which soil was being aerosolized resulted in greater concentrations of endotoxin with or without biosolids, which suggested that the majority of endotoxin may in fact be of soil origin. This study evaluated the presence of aerosolized endotoxin from the land application of biosolids and showed that these levels were within ranges for concern suggested by other studies and that this area of research needs further investigation. Key words: biosolids, endotoxin, aerosol, bioaerosol, lipopolysaccharide.


2017 ◽  
Vol 2017 (1) ◽  
pp. 1056-1064
Author(s):  
Jake Finlinson ◽  
Dave Ruud ◽  
Andy Bary ◽  
Maile Lono-Batura

Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 221
Author(s):  
Rafał Tytus Bray ◽  
Katarzyna Jankowska ◽  
Eliza Kulbat ◽  
Aneta Łuczkiewicz ◽  
Aleksandra Sokołowska

The paper presents the results of research on the use of ultrafiltration, using membranes of 200 and 400 kDa separation, for disinfection of municipal treated wastewater. The research was conducted on a fractional technical scale using real municipal treated wastewater from two large wastewater treatment plants treating most of the wastewater over the one-million polycentric Gdańsk agglomeration (1.2 million inhabitants). UF 200 kDa and UF 400 kDa processes enabled further improvement of the physical and chemical parameters of treated wastewater. Total phosphorus (to below 0.2 mg/L–UF 200 kDa, 0.13 mg/L–UF 400 kDa) and turbid substances (to below 0.2 mg/L, both membranes) were removed in the highest degree. COD was reduced efficiently (to below 25.6 mgO2/L–UF 200 kDa, 26.8 mgO2/L–UF 400 kDa), while total nitrogen was removed to a small extent (to 7.12 mg/L–UF 200 kDa and 5.7 mg/L–UF 400 kDa. Based on the reduction of indicator bacteria; fecal coliforms including E. coli (FC) and fecal enterococci (FE) it was found that the ultrafiltration is an effective method of disinfection. Not much indicator bacterial were observed in the permeate after processes (UF 200 kDa; FC—5 CFU/L; FE—1 CFU/L and UF 400 kDa; FC—70 CFU/L; FE—10 CFU/L. However, microscopic analysis of prokaryotic cells and virus particles showed their presence after the application of both membrane types; TCN 3.0 × 102 cells/mL–UF 200 kDa, 5.0 × 103 cells/mL–UF 400 kDa, VP 1.0 × 105/mL. The presence of potentially pathogenic, highly infectious virus particles means that ultrafiltration cannot be considered a sufficient disinfection method for treated wastewater diverted for reuse or discharged from high load wastewater treatment plants to recreational areas. For full microbiological safety it would be advisable to apply an additional disinfection method (e.g., ozonation).


2010 ◽  
Vol 61 (6) ◽  
pp. 1383-1392 ◽  
Author(s):  
A. Łuczkiewicz ◽  
S. Fudala-Książek ◽  
K. Jankowska ◽  
B. Quant ◽  
K. Olańczuk-Neyman

The occurrence of resistance patterns among wastewater fecal coliforms was determined in the study. Susceptibility of the isolates was tested against 19 antimicrobial agents: aminoglycosides, aztreonam, carbapenems, cephalosporines, β-lactam/β-lactamase inhibitors, penicillines, tetracycline, trimethoprim/sulfamethoxazole, and fluoroquinolones. Additionally the removal of resistant isolates was evaluated in the laboratory-scale wastewater treatment model plant (M-WWTP), continuously supplied with the wastewater obtained from the full-scale WWTP. Number of fecal coliforms in raw (after mechanical treatment) and treated wastewater, as well as in aerobic chamber effluent was determined using selective medium. The selected strains were identified and examined for antibiotic resistance using Phoenix Automated Microbiology System (BD Biosciences, USA). The strains were identified as Escherichia coli (n = 222), Klebsiella pneumoniae ssp. ozaenae (n = 9), and Pantoea agglomerans (n = 1). The isolate of P. agglomerans as well as 48% of E. coli isolates were sensitive to all antimicrobials tested. The most frequent resistance patterns were found for ampicillin: 100% of K. pneumoniae ssp. ozaenae and 41% of E. coli isolates. Among E. coli isolates 12% was regarded as multiple antimicrobial resistant (MAR). In the studied M-WWTP, the applied activated sludge processes reduced considerably the number of fecal coliforms, but increased the ratio of antimicrobial-resistant E. coli isolates to sensitive ones, especially among strains with MAR patterns.


2013 ◽  
Vol 864-867 ◽  
pp. 88-95 ◽  
Author(s):  
Zhi Jiao Liu ◽  
Yun Lng Yang

Coal coking wastewater is generated from coking, coal gas purification and coking product recovery process, its composition is complex and difficult to degrade. By introducing the coking wastewater treatment research and application, such as adsorption,coagulation and sedimentation, flue gas treatment and other physical methods, as well advanced oxidation, wet oxidation, Fenton reagent method, photocatalytic oxidation, ultrasonic oxidation, ozone oxidation method, electrochemical oxidation, supercritical water oxidation, incineration and plasma technology, this paper puts forward the trend of coking wastewater treatment technology.


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