Anaerobic bioprocessing of sewage sludge, focusing on degradation of linear alkylbenzene sulfonates (LAS)

2004 ◽  
Vol 49 (10) ◽  
pp. 115-122 ◽  
Author(s):  
I. Angelidaki ◽  
L. Toräng ◽  
C.M. Waul ◽  
J.E. Schmidt
Keyword(s):  
Mass Balance ◽  
Anaerobic Degradation ◽  
Uasb Reactor ◽  
Second Step ◽  
Anaerobic Sludge ◽  
Continuous Stirred Tank Reactor ◽  
Anaerobic Process ◽  
Linear Alkylbenzene ◽  
Linear Alkylbenzene Sulfonates ◽  
Uasb Reactors

Anaerobic degradation of sludge amended with linear alkylbenzene sulfonates (LAS) was tested in a one stage continuous stirred tank reactor (CSTR) and a two stage reactor system consisting of a CSTR as first step and upflow anaerobic sludge bed (UASB) reactor as the second step. Anaerobic removal of LAS was only observed at the second step but not at the first step. Removal of LAS in the UASB reactors was approx. 80% where half was due to absorption and the other half was apparently due to biological removal as shown from the LAS mass balance. At the end of the experiment the reactors were spiked with 14C-LAS which resulted in 5.6% 14CO2 in the produced gas. Total mass balance of the radioactivity was however not achieved. In batch experiments it was found that LAS at concentrations higher than 50 mg/l is inhibitory for most microbial groups of the anaerobic process. Therefore, low initial LAS concentration is a prerequisite for successful LAS degradation. The results from the present study suggest that anaerobic degradation of LAS is possible in UASB reactors when the concentration of LAS is low enough to avoid inhibition of microorganisms active in the anaerobic process.

Anaerobic pre-treatment of petrochemical effluents: terephthalic acid wastewater

1997 ◽  
Vol 36 (2-3) ◽  
pp. 237-248 ◽  
Author(s):  
Robbert Kleerebezem ◽  
Joost Mortier ◽  
Look W. Hulshoff Pol ◽  
Gatze Lettinga
Keyword(s):  
Acetic Acid ◽  
Benzoic Acid ◽  
Terephthalic Acid ◽  
Anaerobic Degradation ◽  
Anaerobic Treatment ◽  
High Rate ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Pre Treatment ◽  
Uasb Reactors

During petrochemical production of purified terephthalic acid (PTA, 1,4-benzene dicarboxylic acid), a large quantity of concentrated effluent is produced. Main polluting compounds in this wastewater are terephthalic acid, acetic acid and benzoic acid in decreasing order of concentration. Acetic acid and benzoic acid are known to be rapidly degraded in high rate anaerobic treatment systems, such as Upflow Anaerobic Sludge Bed (UASB) reactors. Concerning the kinetics of anaerobic mineralization of terephthalic acid, however, no information is available in literuature. Therefore our work focused on the anaerobic degradation of neutralized terephthalic acid (disodium terephthalate) in laboratory scale UASB-reactors and batch reactors. It was found that high rate anaerobic treatment of terephthalate was difficult to obtain due to the low growth rate (μ ≈ 0.04 day−1) of the terephthalate mineralizing mixed culture. The maximum removal capacity of a lab-scale UASB-reactor was found to be 3.9 g COD.1−1 .day−1 at a loading rate of 4.5 g COD.1−1 .day−1 and a hydraulic retention time of 24 hours. Terephthalate was used as sole carbon source during these experiments. Addition of small amounts of sucrose (co-substrate) to the influent, as a source of reducing equivalents, was found to have a negative influence on the anaerobic degradation of terephthalate. Also benzoate was found to inhibit the mineralization of terephthalate. Batch-toxicity experiments showed that terephthalate is not toxic to any of the species involved in its mineralization. Based on these observations, a staged anaerobic reactor system is suggested for the anaerobic pre-treatment of PTA-wastewater.

Study on Mechanism of Anaerobic Sludge Granulation in UASB Reactors

1993 ◽  
Vol 28 (7) ◽  
pp. 171-178 ◽  
Author(s):  
Chen Jian ◽  
Lun Shi-yi
Keyword(s):  
Kinetic Data ◽  
Fermentation Broth ◽  
Wide Spectrum ◽  
Decisive Role ◽  
Uasb Reactor ◽  
Second Step ◽  
Anaerobic Sludge ◽  
Nucleus Formation ◽  
Uasb Reactors ◽  
Sludge Granulation

Sludge granulation in a 15 m3 UASB reactor, with alcoholic stillage from ethanol fermentation broth as influent, has been studied. Based on kinetic data as well as both scanning and transmitting scope observation and identification, a hypothesis for the mechanism of anaerobic sludge granulation is suggested. The first step of granulation is the formation of nuclei. The bacteria involved in the nucleus formation are mainly M. sarcina and M. thrix. The acetic acid concentration and the “selection pressure” play a decisive role for determining the nucleus formation. A wide spectrum of other bacteria, which the methanogens must syntrophically grow with, also play a very important role during the second step, that is the process of a nucleus growing into a granule.

Anaerobic Degradation Pathway of Linear Alkylbenzene Sulfonates (LAS) in Sulfate-Reducing Marine Sediments

2010 ◽  
Vol 44 (5) ◽  
pp. 1670-1676 ◽  
Author(s):  
Pablo A. Lara-Martín ◽  
Abelardo Gómez-Parra ◽  
José Luis Sanz ◽  
Eduardo González-Mazo
Keyword(s):  
Marine Sediments ◽  
Anaerobic Degradation ◽  
Degradation Pathway ◽  
Linear Alkylbenzene ◽  
Sulfate Reducing ◽  
Linear Alkylbenzene Sulfonates

Effect of micro-nutrients in anaerobic degradation of sulfate laden organics

2004 ◽  
Vol 31 (3) ◽  
pp. 420-431 ◽  
Author(s):  
S K Patidar ◽  
Vinod Tare
Keyword(s):  
Anaerobic Degradation ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Sulfide Concentration ◽  
Anaerobic Baffled Reactor ◽  
Sulfide Toxicity ◽  
Anaerobic Sludge Blanket

The effect of micro-nutrients, such as Fe, Ni, Zn, Co, and Mo, on anaerobic degradation of sulfate laden organics was investigated using bench-scale models of upflow anaerobic sludge blanket (UASB) reactor, anaerobic baffled reactor (ABR), and hybrid anaerobic baffled reactor (HABR), operating in varying conditions in ten phases (organic loading of 1.9–5.75 kg COD/(m3·d), sulfate loading of 0.54–1.88 kg SO42–/(m3·d), chemical oxygen demand (COD):SO42–ratio of 2.0–8.6). In the initial phase, no nutrient limitation was observed with COD removal of more than 94% in all three systems. Subsequently, increase in sulfate loading resulted in Ni and Co limitation and their supplementation restored COD removal in UASB system. However, baffled systems did not recover because of severe inhibition by sulfide. Results indicate that precipitation of nutrients could seriously deteriorate process performance, leading to failure even before sulfide concentration attains toxic level. The limitation of Fe coupled with high sulfate loading (1.88 kg SO42–/(m3·d)) resulted in growth of low-density, fragile, hollow, and granular biomass in UASB that washed out and caused process instability. Supplementation of Fe with other nutrients stabilized UASB process and also improved COD removal.Key words: anaerobic degradation, nutrients, UASB, ABR, HABR, sulfide toxicity, sulfate laden organics.

Denitrification on the top of UASB reactors of rice wastewaters

2001 ◽  
Vol 44 (4) ◽  
pp. 79-82 ◽  
Author(s):  
L. F. Lopes ◽  
P. R. Koetz ◽  
M. S. Santos
Keyword(s):  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Food Industries ◽  
Denitrification Reactor ◽  
Mixed Reactor ◽  
South Of Brazil ◽  
Anaerobic Sludge Blanket ◽  
Uasb Reactors ◽  
Maximum Removal

Parboiled rice industry is one of main food industries in the south of Brazil. The main parts of the processing are the humidification and gelatinization of the grain. This procedure increases the productivity and nutritive and cooking values of the product. Some of these industries in the region utilize upflow anaerobic sludge blanket (UASB) reactors as a biological treatment for carbon removal. For nitrogen removal, the proposed system aims to eliminate an extra denitrification reactor, making this step in the top of the UASB, an anoxic zone of the reactor. Nitrification was performed in aerated mixed reactor of 3,6 L. A fraction of the NR was recycled in the top of UASB reactor above the sludge blanket. Recycled ratio varied from 0; 1:0.5; 1:1.0; to 1:1.5. The maximum removal efficiency of NTK was 80%. The results confirm the viability of the proposed system for denitrification.

Control of scum accumulation in a double stage biogas collection (DSBC) UASB reactor treating domestic wastewater

2009 ◽  
Vol 59 (6) ◽  
pp. 1077-1083 ◽  
Author(s):  
J. O. Pereira ◽  
J. S. S. Celani ◽  
C. A. L. Chernicharo
Keyword(s):  
Mass Balance ◽  
Municipal Wastewater ◽  
Control Mechanism ◽  
Domestic Wastewater ◽  
Uasb Reactor ◽  
Uasb Reactors

This paper presents an innovative reactor concept which is based on a double-stage biogas collection (DSBC) device aimed at controlling scum formation and accumulation in UASB reactors treating municipal wastewater. Scum production inside a control reactor and a DSBC-UASB reactor was compared and much lower scum yield coefficients were observed for the DSBC-UASB reactor. However, the mass balance indicated that the dominant control mechanism was scum disaggregation and exit to settler zone rather than scum degradation.

Degradation of chlorinated aromatic compounds in UASB reactors

1995 ◽  
Vol 31 (1) ◽  
pp. 249-259 ◽  
Author(s):  
Nina Christiansen ◽  
Hanne V. Hendriksen ◽  
Kimmo T. Järvinen ◽  
Birgitte K. Ahring
Keyword(s):  
Metabolic Pathways ◽  
Granular Sludge ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Ring Cleavage ◽  
Anaerobic Sludge ◽  
Chlorinated Phenols ◽  
Desulfomonile Tiedjei ◽  
Anaerobic Sludge Blanket ◽  
Uasb Reactors

Data on anaerobic degradation of chloroaromatic compounds in Upflow Anaerobic Sludge Blanket Reactors (UASB-reactor) are presented and compared. Special attention is given to the metabolic pathways for degradation of chlorinated phenols by granular sludge. Results indicate that PCP can be degraded in UASB-reactors via stepwise dechlorination to phenol. Phenol will subsequently be converted to benzoate before ring cleavage. Dechlorination proceeds via different pathways dependent upon the inocula used. Results are further presented on the design of special metabolic pathways in granules which do not possess this activity using the dechlorinating organism, Desulfomonile tiedjei. Additionally, it is shown that it is possible to immobilize Dechlorosporium hafniense, a newly isolated dechlorinating anaerobe, into granular sludge, thereby introducing an ability not previously present in the granules.

scholarly journals Anaerobic treatment of chocolate-processing industry wastewater at different organic loading rates and temperatures

2019 ◽  
Vol 79 (12) ◽  
pp. 2251-2259 ◽  
Author(s):  
M. Esparza-Soto ◽  
A. Jacobo-López ◽  
M. Lucero-Chávez ◽  
C. Fall
Keyword(s):  
Operating Temperature ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Optimum Operating ◽  
Anaerobic Sludge ◽  
Organic Loading ◽  
Processing Industry ◽  
Loading Rates ◽  
Uasb Reactors ◽  
Industry Wastewater

Abstract The objective of the present study was to determine the optimum operating temperature of laboratory-scale upflow anaerobic sludge blanket (UASB) reactors during the treatment of a chocolate-processing industry wastewater at medium applied organic loading rates (OLRappl). Four UASB reactors were operated at different temperature (15, 20, 25 and 30 °C) and three OLRappl (2, 4 and 6 kg soluble chemical oxygen demand (CODs)/(m3 d)). The flowrate and the hydraulic retention time were constant (11.5 L/d and 6 h, respectively). The monitored parameters were pH, temperature, CODs, and total and volatile suspended solids. The CODs removal efficiency (RE) and biogas production rate (BPR) were calculated. The 15 °C UASB reactor had the lowest RE (39 to 78%) due to the low operating temperature. Regardless of the OLRappl, the RE of the 20, 25 and 30 °C reactors was high and similar to each other (between 88 and 94%). The BPR of the four UASB reactors had the same behaviour as the RE (BPR of 15 °C: 0.3 to 0.5 Lbiogas/(Lreactor d) (Lb/(Lr d)) and BPR of 20, 25 and 30 °C: 0.5 to 1.9 Lb/(Lr d)).

Single-stage anaerobic/aerobic biotreatment of resin acid-containing wastewater

1998 ◽  
Vol 38 (4-5) ◽  
pp. 255-262 ◽  
Author(s):  
S. R. Guiot ◽  
R. J. Stephenson ◽  
J.-C. Frigon ◽  
J. A. Hawari
Keyword(s):  
High Efficiency ◽  
Resin Acid ◽  
Integrated System ◽  
Resin Acids ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Feed Stock ◽  
Stable Performance ◽  
Acid Loading ◽  
Uasb Reactors

The present study compares the coupled anaerobic/aerobic integrated system (CANOXIS) operated at different aeration and liquid recycle rates to the conventional upflow anaerobic sludge bed (UASB) system for the laboratory scale treatment of a resin acid-containing effluent. Dehydroabietic and abietic acids were added in equal proportions to a sucrose-based feed stock. Even under oxygenation conditions, methane was formed, indicating that the aerobic and facultative microorganisms consumed oxygen fast enough to maintain a reduced microenvironment essential to the methanogens. Eight weeks of resin acid loading at 100 mg/L exerted no significant effects on the high efficiency and stable performance of UASB reactors. The CANOXIS systems showed with time a reduced discharge of residual resin acids in the effluent and a decrease of the amount of resin acids adsorbed onto the biomass when compared to the UASB reactor.

Anaerobic digestion of olive oil mill effluents together with swine manure in UASB reactors

2002 ◽  
Vol 45 (10) ◽  
pp. 213-218 ◽  
Author(s):  
I. Angelidaki ◽  
B.K. Ahring ◽  
H. Deng ◽  
J.E. Schmidt
Keyword(s):  
Anaerobic Digestion ◽  
Olive Oil ◽  
Degradation Products ◽  
Swine Manure ◽  
Degradation Process ◽  
Anaerobic Treatment ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Uasb Reactors

Combined anaerobic digestion of olive oil mill effluent (OME) with swine manure, was investigated. In batch experiments was shown that for anaerobic degradation of OME alone nitrogen addition was needed. A COD:N ratio in the range of 65:1 to 126:1 was necessary for the optimal degradation process. Furthermore, it was found that methane productions rates during digestion of either swine manure alone or OME alone were much lower than the rates achieved when OME and manure were digested together. Admixing OME with manure at a concentration of 5 to 10% OME resulted in the highest methane production rates. Using upflow anaerobic sludge blanket (UASB) reactors, it was shown that codigestion of OME with swine manure (up to 50% OME) was successful with a COD reduction up to 75%. The process was adapted for degradation of OME with stepwise increase of the OME load to the UASB reactor. The results showed that the high content of ammonia in swine manure, together with content of other nutrients, make it possible to degrade OME without addition of external alkalinity and without addition of external nitrogen source. Anaerobic treatment of OME in UASB reactors resulted in reduction of simple phenolic compounds such as mequinol, phenyl ethyl alcohol and ethyl methyl phenol. After anaerobic treatment the concentration of these compounds was reduced between 75 and 100%. However, the concentration of some degradation products such as methyl phenol and ethyl phenol were detected in significantly higher concentrations after treatment, indicating that the process has to be further optimised to achieve satisfactory removal of all xenobiotic compounds.

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