Application of 1-hydroxyethylidene-1, 1-diphosphonic acid in boiler water for industrial boilers

2013 ◽  
Vol 67 (7) ◽  
pp. 1544-1550 ◽  
Author(s):  
Bin Zeng ◽  
Mao-dong Li ◽  
Zhi-ping Zhu ◽  
Jun-ming Zhao ◽  
Hui Zhang

The primary method used for boiler water treatment is the addition of chemicals to industrial boilers to prevent corrosion and scaling. The static scale inhibition method was used to evaluate the scale inhibition performance of 1-hydroxyethylidene-1, 1-diphosphonic acid (HEDP). Autoclave static experiments were used to study the corrosion inhibition properties of the main material for industrial boilers (20# carbon steel) with an HEDP additive in the industrial boiler water medium. The electrochemical behavior of HEDP on carbon steel corrosion control was investigated using electrochemical impedance spectroscopy and Tafel polarization techniques. Experimental results indicate that HEDP can have a good scale inhibition effect when added at a quantity of 5 to 7 mg/L at a test temperature of not more than 100 °C. To achieve a high scale inhibition rate, the HEDP dosage must be increased when the test temperature exceeds 100 °C. Electrochemical and autoclave static experimental results suggest that HEDP has a good corrosion inhibition effect on 20# carbon steel at a concentration of 25 mg/L. HEDP is an excellent water treatment agent.

2012 ◽  
Vol 535-537 ◽  
pp. 1180-1184
Author(s):  
Mao Dong Li ◽  
Bin Zeng ◽  
Lin Yang ◽  
Jun Ming Zhao ◽  
Yu Hui Du ◽  
...  

The static scale inhibition method will be used to evaluate the scale inhibition performance of HEDP. In order to study the corrosion inhibition of 20A steel with additive of HEDP in the industrial boiler water medium,the total iron ions in the solution are determined through autoclave static experiments. The results indicated that the scale inhibition efficiency,in the simulation boiler water with a certain concentration ratio and temperature,reached the maximum when CHEDP is 7 mg/L. It has a good corrosion inhibition effect on the 20A steel when the HEDP concentration exceeds 15ppm.


Proceedings ◽  
2020 ◽  
Vol 55 (1) ◽  
pp. 1 ◽  
Author(s):  
Simona Căprărescu ◽  
Annette Madelene Dăncilă ◽  
Cristina Modrogan ◽  
Violeta Purcar

The aim of this work was to investigate the corrosion inhibition effect of natural seaweeds in seawater on carbon steel. The corrosion efficiency of carbon steel in the absence and the presence of natural seaweeds in seawater was evaluated by the gravimetric method at room temperature and calculating the corrosion rate and protection degree. The experimental results showed that the corrosion rate on carbon steel decreased when the seaweeds were used. In addition, the value of protection degree (P) was greater than 60% when seaweeds were used. Natural seaweeds reduce the corrosion rate and can be considered an ecofriendly corrosion inhibitor for carbon steel.


2013 ◽  
Vol 781-784 ◽  
pp. 299-303
Author(s):  
Shu Lan Cai ◽  
Kang Quan Qiao ◽  
Fa Mei Feng

A new corrosion inhibior N,N-diethylammonium O,O-di (p-chlorophenyl) dithiophosphate (EDPDP) has been synthesized and its inhibition effect towards the corrosion of carbon steel in 1.0 molL-1 HCl solution at 25 °C has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The obtained results show that EDPDP is a excellent inhibitor and the inhibition efficiencies exceed 90 %. The polarization measurements reveal that EDPDP is a mixed type inhibitor and the equivalent circuit model of the corrosion inhibition process is obtained by the analysis of EIS data.


Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4200
Author(s):  
Bing Lin ◽  
Junlei Tang ◽  
Yingying Wang ◽  
Hu Wang ◽  
Yu Zuo

The synergistic corrosion inhibition effect between calcium lignosulfonate (CLS) and three kinds of inorganic inhibitors (Na2MoO4, Na2SnO3, and NaWO4) with various molar ratios on Q235 carbon steel in alkaline solution (pH 11.5) with 0.02 mol/L NaCl was investigated by cyclic potentiodynamic polarization, electrochemical impedance spectroscopy, linear polarization, scanning electron microscopy, and X-ray photoelectron spectroscopy. Molybdate and stannate in hybrid inhibitor could promote the passivation of steel and form a complex film, which could suppress the corrosion effectively. Moreover, the insoluble metal oxides in the complex film formed by three kinds of inorganic inhibitor could help the adsorption of CLS onto the steel surface. The CLS molecules could adsorb onto the steel surface and metal oxides to form an adsorption film to protect the steel from corrosion. A three-layer protection film formed by a hybrid inhibitor, including passivation film, deposition film, and adsorption film, would effectively inhibit the corrosion reactions on the steel surface. The CLS compound with molybdate with the ratio of 2:3 shows the best inhibition effect on both general corrosion and localized corrosion.


2021 ◽  
Vol 123 ◽  
pp. 108366
Author(s):  
M. Bouassiria ◽  
T. Laabaissi ◽  
F. Benhiba ◽  
M. El Faydy ◽  
H. Fakhry ◽  
...  

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