Corrosion Inhibition of N,N- diethylammonium O,O′- di (p-chlorophenyl) dithiophosphate for Carbon Steel in HCL Solution

2013 ◽  
Vol 781-784 ◽  
pp. 299-303
Author(s):  
Shu Lan Cai ◽  
Kang Quan Qiao ◽  
Fa Mei Feng
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Mixed Type ◽  
Electrochemical Impedance ◽  
Equivalent Circuit Model ◽  
Inhibition Effect ◽  
Inhibition Process ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

A new corrosion inhibior N,N-diethylammonium O,O-di (p-chlorophenyl) dithiophosphate (EDPDP) has been synthesized and its inhibition effect towards the corrosion of carbon steel in 1.0 molL-1 HCl solution at 25 °C has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The obtained results show that EDPDP is a excellent inhibitor and the inhibition efficiencies exceed 90 %. The polarization measurements reveal that EDPDP is a mixed type inhibitor and the equivalent circuit model of the corrosion inhibition process is obtained by the analysis of EIS data.

Inhibition of [NH2Et2][(4-MeC6H4O)2PS2] for Carbon Steel in Hydrochloric Acid Solution

2011 ◽  
Vol 239-242 ◽  
pp. 716-719
Author(s):  
Zhen Xiang ◽  
Xue Yang ◽  
Bin Xie ◽  
Li Ke Zou ◽  
Yang Guang Xiang ◽  
...  
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Mixed Type ◽  
Steel Surface ◽  
Standard Free Energy ◽  
Free Energy Of Adsorption ◽  
Inhibition Effect ◽  
Carbon Steel Surface ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

The inhibition effect of N,N-diethylammonium O,O'-di(4-Methylpheny)dithiophosphate (NOPP, [NH2Et2][(4-MeC6H4O)2PS2])against the corrosion of carbon steel in HCl solution was studied by weight loss measurements, electrochemical measurements, AFM and SEM techniques. The studies of weight loss measurements indicate that the NOPP acts as a good inhibitor for the corrosion of carbon steel in HCl solution. Polarization curves indicate NOPP is a mixed-type inhibitor. The adsorption of NOPP on carbon steel surface obeys the Langmuir isotherm, and the obtained standard free energy of adsorption suggests that the chemisorption takes place spontaneously.

scholarly journals Investigation of Akuamma Seed Extract on Corrosion Inhibition of Aluminum in Hydrochloric Acid Pickling Environment

2019 ◽  
pp. 115-138
Author(s):  
J. O. Ezeugo ◽  
O. D. Onukwuli ◽  
K. O. Ikebudu ◽  
V. C. Ezechukwu ◽  
L. O. Nwaeto
Keyword(s):  
Corrosion Inhibition ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Seed Extract ◽  
Aluminum Surface ◽  
Inhibition Concentration ◽  
Inhibition Process ◽  
Anodic Reactions ◽  
Mixed Type Inhibitor

Inhibitive impact of Akuamma seed (AS) extract toward 1.0M HCl corrosion of aluminum was examined using response surface methodology (RSM). Gravimetric (weight loss), potentiodynamic polarization and electrochemical impedance spectroscopy techniques were used in the corrosion inhibition process. In all the method used, the seed extract acted as good corrosion inhibitor of aluminum in 1.0M HCl solution. Optimal inhibition efficiency of 72.6% was obtained at optimum inhibition concentration of 1.2g/l, temperature of 304.19k and maximized time of 11.53hrs. It showed that the plant extract has excellent inhibitive properties for the corrosion inhibition process. The values of kads are relatively small indicating that the interaction between the adsorbed extract molecules and aluminum surface is a physical process. The (AS) extract protects aluminum against pitting corrosion. The level of protection increases with increase extract concentrations. The extract inhibited both cathodic and anodic reactions and acted as mixed-type inhibitor.

The corrosion inhibition of carbon steel in 5 per cent HCl by Momordica charantia extract

2014 ◽  
Vol 61 (4) ◽  
pp. 255-260 ◽  
Author(s):  
Xie Xuejun* ◽  
Xiao Peng* ◽  
He Jie ◽  
Xiao Wen ◽  
Fu Qiang ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Xps Analysis ◽  
Content Type ◽  
Isotherm Equation ◽  
Inhibition Effect ◽  
Langmuir Isotherm Equation ◽  
Ir Analysis ◽  
Mixed Type Inhibitor

Purpose – To study the inhibition effect and mechanism of the Momordica charantia extract (BM) to 20 A carbon steel in 5 per cent HCl. Design/methodology/approach – The weight loss, polarization curve, infrared spectrum (IR) analysis and X-ray photoelectron spectrum (XPS) analysis were carefully investigated to indicate the inhibition effect and mechanism of the BM to 20 A carbon steel in 5 per cent HCl. Findings – BM was composed of C, N and O. Functional groups such as N–H and C=O were found in BM. The inhibition efficiency increased with the increasing concentration of BM. BM behaved as a mixed-type inhibitor, and the inhibition of BM to 20 A carbon steel might be its adsorption through the coordinate covalent bonding among the lone pair electrons of N and O and the empty 3d orbits of Fe, and the adsorption on the surface of 20 A carbon steel obeyed the Langmuir isotherm equation. Research limitations/implications – The inhibition of the BM to 20 A carbon steel in 5 per cent HCl. Practical implications – BM could be used in 5 per cent HCl to prevent 20 A carbon steel from corrosion. Social implications – BM could be used in the chemical cleaning of the boilers to prevent the thermal equipments from corrosion. Originality/value – The inhibition effect and mechanism of the BM to 20 A carbon steel were studied by the weight loss, polarization curve, IR analysis and XPS analysis. BM was composed of C, N and O. Functional groups such as N–H and C=O were found in BM. BM behaved as a mixed-type inhibitor. The inhibition efficiency increased with the increasing concentration of BM, and the adsorption on the surface of 20 A carbon steel obeyed the Langmuir isotherm equation.

Corrosion Inhibition of 2-Mercaptobenzothiazole for Carbon Steel in Sulfuric Acid Solution

2012 ◽  
Vol 557-559 ◽  
pp. 92-95 ◽  
Author(s):  
Xiao Feng Liang ◽  
Xue Yang
Keyword(s):  
Sulfuric Acid ◽  
Carbon Steel ◽  
Acid Solution ◽  
Sulfuric Acid Solution ◽  
Mixed Type ◽  
Sulfuric Acid Concentration ◽  
Weight Loss Measurement ◽  
Inhibition Effect ◽  
Effects Of Temperature ◽  
Mixed Type Inhibitor

The inhibition effect of 2-Mercaptobenzothiazole (2-MB) against the corrosion of carbon steel in sulfuric acid solution was studied by weight loss measurement and electrochemical measurements(potentiodynamic polarization techniques). The results show that 2-MB acts as a good corrosion inhibitor in sulfuric acid solution. Adsorption of 2-MB is found to obey Langmuir isotherm. Polarization curves indicate 2-MB is a mixed-type inhibitor. The effects of temperature and sulfuric acid concentration were also studied.

Inhibition Effect of N-Octyl-2-Pyrrolidonium Chloride on the Corrosion of Mild Steel in Acidic Medium

2013 ◽  
Vol 634-638 ◽  
pp. 651-654
Author(s):  
Zi Chong Zhuang ◽  
Bao Hua Huang ◽  
Jun Liu ◽  
Yu Jing Lu ◽  
Zhan Chang Pan ◽  
...  
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Acidic Medium ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Electrochemical Techniques ◽  
Inhibition Mechanism ◽  
Inhibition Effect ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

A new ionic liquid, N-octyl-2-pyrrolidonium chloride (NOPC), were synthesized and evaluated as inhibitors for mild steel (Q235) corrosion in 1 mol/L HCl. The adsorption behavior and corrosion inhibition mechanism of NOPC for mild steel in HCl solution were investigated by using weight loss measurements, electrochemical techniques, and SEM. The inhibition efficiency increases with the increasing concentration of NOPC in 1 mol/L HCl and decreases as the temperature increases. The results indicate that NOPC is able to function as a mixed type inhibitor.

scholarly journals Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Sarra Aourabi ◽  
Majid Driouch ◽  
Mariya Kadiri ◽  
Noura Achnine ◽  
Mouhcine Sfaira ◽  
...  
Keyword(s):  
Mild Steel ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Synergetic Effect ◽  
Equivalent Circuit Model ◽  
Mild Steel Surface ◽  
Ammi Visnaga ◽  
Edx Analyses ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

The synergetic effects between hydroethanolic extracts of A. visnaga HE (AV) and Z. mays hairs HE (ZM) on corrosion of mild steel in 1 M HCl solution was investigated at 298 K by two techniques: potentiodynamic polarization (PP) methods (Tafel and Stern & Geary) and electrochemical impedance spectroscopy (EIS). The mixture of HE (AV)/HE (ZM) acted as an efficient corrosion inhibitor and its inhibition efficiency increased with concentration up to 96.55% at 0.01 gL−1 HE (AV)/0.2 gL−1 HE (ZM). The polarization curves revealed that the mixture acted as a mixed-type inhibitor, with anodic predominant action. The EIS studies were fitted by the (Rs + CPEdl)/(Rct + CPEf/Rf) equivalent circuit model. The kinetic parameters were in favor of a physisorption character of adsorption of HE (AV)/HE (ZM) components onto the mild steel surface. The influence of exposure time on the efficiency of mixture extract was investigated. Scanning electron microscopy (SEM/EDX) analyses confirmed the formation of a protective adsorbed film upon the mild steel surface.

scholarly journals Aizoon Extract As a Novel Eco-friendly Corrosion Inhibitor For Stainless Steel430 in HCl Solution

2021 ◽  
Author(s):  
Ahmed F. Molouk ◽  
Mohamed F. Atia ◽  
Abd El-Aziz S. Fouda
Keyword(s):  
Mixed Type ◽  
Electrochemical Impedance ◽  
Theoretical Data ◽  
Cathodic Reaction ◽  
Mass Reduction ◽  
Adsorption Model ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

Abstract Aizoon extract used as anti-corrosion for stainless steel430 (SS430) in 2M hydrochloric acid solution. The mass reduction, electrochemical impedance, and potentiodynamic polarization were carried out to demonstrate the performance of Aizoon extract as corrosion resistance for SS430. Polarization revealed that the Aizoon extract is mixed type inhibitor with superiority to inhibiting the cathodic reaction. The inhibition percentage reaches 93% at 300 ppm extract. Adsorption of the extract on SS430 surface is regular with Langmuir adsorption model. Thermodynamic factors for adsorption and activation processes for SS430 dissolution were estimated and discussed. Furthermore, the SS430 surface is characterized using different techniques. The surface morphology of SS430 was tested utilizing several techniques. The experimental data were supported by the theoretical data.

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